Patents by Inventor Karl Hintermeier
Karl Hintermeier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4877540Abstract: Methylolated and optionally etherified urethanes containing fluoroalkyl ligans with formaldehyde, with or witout subsequent etherification, and are in the form of their solutions or aqueous dispersions suitable for the treatment of textiles and leather.Type: GrantFiled: August 8, 1988Date of Patent: October 31, 1989Assignee: Cassella AktiengesellschaftInventors: Fritz Engelhardt, Karl Hintermeier, Manfred Muller, Norbert Munch, Hans Wagener
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Patent number: 4775488Abstract: An agent effective for oleophobizing and hydrophobizing textiles is an aqueous anionic dispersion which comprises water and(A) 5 to 25% by weight of a reaction product which contains at least one bis-(2-fluoroalkyl-ethoxy-carbonylamino)-toluene of the formula ##STR1## wherein n is a number from 5 to 15 and Y is --H or --F, and wherein said reaction product is prepared by reacting 2-perfluoroalkylethanol of the formulaYCF.sub.2 --(CF.sub.2).sub.n --CH.sub.2 CH.sub.2 OHwith tolylene diisocyanate in a molar ratio of (1.8 to 2):1 in the presence of 2 to 5% by weight of N-methylpyrrolidone, relative to the perfluoroalkylethanol,(B) 1 to 14% by weight of at least one emulsifier of the formulaYCF.sub.2 (CF.sub.2).sub.p --CH.sub.2 CH.sub.2 O--CO--NH--CH.sub.2 CH.sub.2 --SSO.sub.3 Xwherein p is a number from 5 to 15, Y is --H or --F, and X is a monovalent cation,(C) 1 to 14% by weight of at least one nonionic emulsifier of the formulaYCF.sub.2 --(CF.sub.2).sub.q --CH.sub.2 CH.sub.2 --(OCH.sub.2 CH.sub.2).sub.Type: GrantFiled: April 11, 1986Date of Patent: October 4, 1988Assignee: Cassella AktiengesellschaftInventors: Karl Hintermeier, Heinrich Bathelt, Frank Wehowsky, Hans Wagener, Manfred Seidel, Manfred Muller, Klaus Kaschub
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Patent number: 4736014Abstract: Polycoester of the formula IE--CO--R--CO--O--R.sup.1 --O--CO--R--CO).sub.n E.sup.1 (I)in whichR is 60 to 85 mol % 1,3-phenylene radicals, 5 to 20 mol % tetramethylene radicals and 10 to 20 mol % for example radicals of the formula IIa ##STR1## R.sup.1 is 60 to 95 mol % ethylene radicals (--CH.sub.2 CH.sub.2 --), 0 to 28 mol % 2,2-dimethyl-1,3-propylene radicals and 5 to 12 mol % polyoxyethylene radicals having an average molecular weight up to 600 andR.sup.2 denotes for example SO.sub.3 H andE, E.sup.1 denote for example --OH andn is a sufficiently large number that the polycoester has an average molecular weight between 15,000 and 40,000, are used in the form of their aqueous solutions as sizing agents.Type: GrantFiled: January 13, 1987Date of Patent: April 5, 1988Assignee: Cassella AktiengesellschaftInventors: Friedrich Engelhardt, Karl Hintermeier, Rolf Kleber, Peter Klein
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Patent number: 4709074Abstract: The novel urethanes correspond to the formula I below ##STR1## in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water.The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.Type: GrantFiled: August 28, 1986Date of Patent: November 24, 1987Assignee: Hoechst AktiengesellschaftInventors: Heinrich Bathelt, Winfried Ehrl, Frank Wehowsky, Rolf Kleber, Werner Lotz, Wolfgang Glenz, Hubert Herdt, Lothar Jackel, Jan-Hilbert Mast, Karl Hintermeier, Manfred Muller
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Patent number: 4535031Abstract: Modified aminoplast resin comprising:(a) 60 to 99.5% by weight of an aminoplast precondensate which has been etherified with a lower alkanol to an extent not exceeding 10% and(b) 0.5 to 40% by weight of a modifying agent which comprises a mixture of (i) a water-soluble polyester prepared from carboxylic acids with at least one carboxyl and dihydric or polyhydric alcohols, and (ii) sufficient free diol or polyol whereby the mixture has a ratio of the sum of free and esterified hydroxyls of 0.8 to 4.5 moles for each mole of the sum of free and esterified carboxyls which resins are useful in impregnating webs for producing laminates and panels of wood-based materials.Type: GrantFiled: March 5, 1984Date of Patent: August 13, 1985Assignee: Cassella AktiengesellschaftInventors: Peter Dorries, Thomas Gotze, Steffen Piesch, Manfred Schon, Gunther Wulff, Karl Hintermeier
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Patent number: 4463165Abstract: Hydrophobic textile materials exhibit reduced tendency to static charge buildup, significantly improved absorbency and reduced soiling tendency when treated with a water-dispersible polyester having structural units of the formula ##STR1## wherein A is, on statistical average, 80 to 100 mol percent of p-phenylene and 0 to 20 mol percent of divalent moieties of the formula ##STR2## and wherein G is, on statistical average, 30 to 90 mol percent of linear or branched divalent alkane moieties having 3 to 6 carbon atoms which may be interrupted by 1 or 2 oxygen atoms, 10 to 30 mol percent of divalent polyether moieties having an average molecular weight of 1,000 to 3,000, and up to 50 mol percent of ethylene moieties, and R is a straight-chain or branched alkyl or alkenyl having 6 to 8 carbon atoms.Type: GrantFiled: November 8, 1983Date of Patent: July 31, 1984Assignee: Cassella AktiengesellschaftInventors: Friedrich Engelhardt, Karl Hintermeier, Otto Smerz, Hans Wagener
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Patent number: 4314052Abstract: Improved polyesters soluble or dispersible in water having an apparent average molecular weight of 800 to 5,000 and containing phosphonic ester moieties are useful as levelling auxiliaries for uniform dyeing and are produced by esterifying dibasic acids and dihydric alcohols, either or both of which contain phosphonic acid moieties, phosphonic acid ester moieties or both.Type: GrantFiled: January 7, 1980Date of Patent: February 2, 1982Assignee: Cassella AktiengesellschaftInventors: Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Walter Dursch, Walter Rupp
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Patent number: 4304569Abstract: The formulation for brightening synthetic fibers or mixtures of synthetic fibers and natural fibers, which is an aqueous dispersion comprising at least one finely divided optical brightener and a dispersing agent, wherein the improvement comprises the dispersing agent being a water-soluble or water-dispersible polyester containing at least one phosphonic acid ester moiety.Type: GrantFiled: November 26, 1980Date of Patent: December 8, 1981Assignee: Cassella AG.Inventors: Friedrich Engelhardt, Karl Hintermeier, Herbert Friedrich, Thomas Martini
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Patent number: 4252532Abstract: Process for dyeing evenly synthetic fiber materials and mixtures thereof with natural fibers, with water-insoluble disperse dyestuffs according to the exhaust method, which comprises adding water-soluble or dispersible linear polyesters that have been obtained by polycondensation of dicarboxylic acids with diols, including sulfo-groups-containing chain links, with an average molecular weight of 800 to 5,000, combined with surface-active oxethylation products, at a blend ratio of 1:0.25 to 1:1.5, as dispersing system with levelling action to the aqueous dyeliquors, besides said dyestuffs and pH-controlling substances.Type: GrantFiled: November 18, 1977Date of Patent: February 24, 1981Assignee: Hoechst AktiengesellschaftInventors: Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Ralf Zimmermann
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Patent number: 4250296Abstract: Disclosed is a polycondensate of (a) water soluble or dispersible polyester having a molecular weight of 600-5000 prepared by reacting a carboxylic acid and a diol or polyol wherein 5-40 moles percent of the acid or hydroxy compounds contain sulfo substituents and (b) a compound of the formulaR--O--(CH.sub.2 CH.sub.2 O).sub.m --CH.sub.2 CH.sub.2 OHwherein m is a number from 5 to 50 and R is selected from the group consisting of alkyl of 6-22 carbon atoms, alkenyl of 6-22 carbon atoms, alkanoyl of 6-22 carbon atoms, aryl of 6-22 carbon atoms, aralkyl of 6-22 carbon atoms, castor oil radical and ##STR1## wherein R' is alkyl or alkenyl each having 6-22 carbon atoms. The polycondensate is useful as a modifier for aminoplast resins and as a leveller in dyeing.Type: GrantFiled: August 15, 1978Date of Patent: February 10, 1981Assignee: Cassella AktiengesellschaftInventors: Gerhard Weckler, Hans J. Hauss, Karl Hintermeier, Friedrich Engelhardt
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Patent number: 4247456Abstract: Water-insoluble monoazo dyes of the formula ##STR1## produced by reacting a diazotized amine of the benzene, naphthalene, diphenyl, diphenylmethane or heterocyclic series which is free from water solubilizing groups with the appropriate 6-hydroxy-2-pyridone and the utility thereof for the dyeing and printing of synthetic fabric materials to yellow to red shades having excellent fastness to light and sublimation.Type: GrantFiled: November 19, 1976Date of Patent: January 27, 1981Assignee: Cassella AktiengesellschaftInventors: Hanswilli von Brachel, Ernst Heinrich, Otto Grawinger, Karl Hintermeier, Horst Kindler
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Patent number: 4168145Abstract: Dyeing with disperse dyes is made more uniform when there is used as a levelling agent a branched polyester which has an apparent average molecular weight of from about 600 to about 5,000, disperses itself in water, and is essentially an ester-linked combination of hydrocarbyloxy groups and carboxyl-derived acyl groups, the groups being linked together as a branched chain by the ester linkages and relative to the carboxy-derived acyl groups the polyester contains from about 5 to about 50 mol.% of COOH or COOM groups and less than 5 mol.% of SO.sub.3 M groups, wherein M denotes the cation of an alkali metal, the ammonium ion or the cationic radical of an organic amine, the number of branches on an interesterified group being not over three and at least 50 mol.% of the hydrocarbyloxy groups are in diethylene glycol or triethylene glycol groups.Type: GrantFiled: September 30, 1977Date of Patent: September 18, 1979Assignee: Cassella AktiengesellschaftInventors: Karl Hintermeier, Fritz Engelhardt, Joachim Ribka, Helmut Beutler
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Patent number: 4167395Abstract: Water-soluble polyester having an apparent molecular weight between about 600 and about 5,000 and a SO.sub.3 M group content between about 5 to about 40 mol percent based on the number of mols of dicarboxylic and/or polycarboxylic acids esterified in the polyester, and an at least trifunctional alcohol and/or an at least trifunctional carboxylic acid content between about 1 to about 40 mol percent based on the number of mols of dicarboxylic and/or polycarboxylic acids esterified in the polyester so that the polyester is correspondingly branched and M denotes a cation of an alkali metal, the ammonium ion or the cationic radical of an organic amine. The improved polyester is particularly suited as a levelling agent in the disperse dyeing of polyester fibers or the like.Type: GrantFiled: May 12, 1977Date of Patent: September 11, 1979Assignee: Cassella AktiengesellschaftInventors: Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Helmut Beutler
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Patent number: 4150216Abstract: Hair-treatment agents having a content of branched copolyesters dispersible or soluble in water and an apparent molecular weight of 600 to 5000, and having a content of SO.sub.3 M groups, wherein M represents an alkali metal ion or ammonium ion or the cationic radical of an organic amine.Type: GrantFiled: July 19, 1977Date of Patent: April 17, 1979Assignee: Hoechst AktiengesellschaftInventors: Jochen M. Quack, Alwin Reng, Friedrich Engelhardt, Karl Hintermeier
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Patent number: 4101274Abstract: Process for the even dyeing of synthetic fiber materials and mixtures thereof with natural fibers with water-insoluble disperse dyes according to the exhaustion method, which comprises adding to the dyebath as levelling agents linear water-soluble, or dispersible polyesters containing sulfo groups.Type: GrantFiled: February 24, 1976Date of Patent: July 18, 1978Assignee: Hoechst AktiengesellschaftInventors: Helmut Beutler, Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka
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Patent number: 3957749Abstract: Water-insoluble monoazo dyes of the formula ##SPC1##Produced by reacting a diazotized amine of the benzene, naphthalene, diphenyl, diphenylmethane or heterocyclic series which is free from water solubilizing groups with the appropriate 6-hydroxy-2-pyridone and the utility thereof for the dyeing and printing of synthetic fabric materials to yellow to red shades having excellent fastness to light and sublimation.Type: GrantFiled: June 5, 1972Date of Patent: May 18, 1976Assignee: Cassella Farbwerke Mainkur AktiengesellschaftInventors: Hanswilli von Brachel, Ernst Heinrich, Otto Grawinger, Karl Hintermeier, Horst Kindler