Patents by Inventor Karl William Koch
Karl William Koch has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11981598Abstract: An article is described herein that includes: a glass-based substrate comprising opposing major surfaces; a crack mitigating composite over one of the major surfaces, the composite comprising an inorganic element and a polymeric element; and a hard film disposed on the crack mitigating composite comprising an elastic modulus greater than or equal to the elastic modulus of the glass-based substrate. The crack mitigating composite is characterized by an elastic modulus of greater than 30 GPa. Further, the hard film comprises at least one of a metal-containing oxide, a metal-containing oxynitride, a metal-containing nitride, a metal-containing carbide, a silicon-containing polymer, a carbon, a semiconductor, and combinations thereof.Type: GrantFiled: July 7, 2022Date of Patent: May 14, 2024Assignee: Corning IncorporatedInventors: Robert Alan Bellman, Shandon Dee Hart, Jenny Kim, Karl William Koch, III, James Joseph Price, Hannah Shenouda
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Patent number: 11977206Abstract: A display article is described herein that includes: a substrate comprising a thickness and primary surface; a diffractive surface region defined by the primary surface; and an antireflective coating disposed on the diffractive surface region. The diffractive surface region comprises structural features that comprise different heights in a multimodal distribution. The substrate exhibits a sparkle of <4%, and a transmittance haze of <20%, each from an incident angle of 0°. The antireflection coating comprises a plurality of alternating high refractive index and low refractive index layers. Further, each of the low index layers comprises a refractive index of ?about 1.8, and each of the high index layers comprises a refractive index of >1.8. The article exhibits a first-surface average visible specular reflectance of less than 0.2% at an incident angle of 20°, and a maximum hardness of ?8 GPa in a Berkovich Indenter Hardness Test.Type: GrantFiled: July 8, 2021Date of Patent: May 7, 2024Assignee: CORNING INCORPORATEDInventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Wageesha Senaratne, William Allen Wood
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Publication number: 20240142668Abstract: An article that includes: an inorganic oxide substrate having opposing major surfaces; and an optical film structure disposed on a first major surface of the substrate, the optical film structure comprising one or more of a silicon-containing oxide, a silicon-containing nitride and a silicon-containing oxynitride and a physical thickness from about 50 nm to less than 500 nm. The article exhibits a hardness of 8 GPa or greater measured at an indentation depth of about 100 nm or a maximum hardness of 9 GPa or greater measured over an indentation depth range from about 100 nm to about 500 nm, the hardness and the maximum hardness measured by a Berkovich Indenter Hardness Test. Further, the article exhibits a single-side photopic average reflectance that is less than 1%.Type: ApplicationFiled: January 10, 2024Publication date: May 2, 2024Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Alexandre Michel Mayolet, James Joseph Price
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Patent number: 11971519Abstract: A display article is described herein that includes: a substrate comprising a thickness and a primary surface; a textured surface region; and an antireflective coating disposed on the textured surface region. The textured surface region comprises structural features and an average texture height (Rtext) from 50 nm to 300 nm. The substrate exhibits a sparkle of less than 5%, as measured by PPD140, and a transmittance haze of less than 40%, at a 0° incident angle. The antireflective coating comprises alternating high refractive index and low refractive index layers. Each of the low index layers comprises a refractive index of less than or equal to 1.8, and each of the high index layers comprises a refractive index of greater than 1.8. The article also exhibits a first-surface average photopic specular reflectance (% R) of less than 0.3% at any incident angle from about 5° to 20° from normal at visible wavelengths.Type: GrantFiled: July 8, 2021Date of Patent: April 30, 2024Assignee: CORNING INCORPORATEDInventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Cameron Robert Nelson, James Joseph Price, Jayantha Senawiratne, Florence Christine Monique Verrier, David Lee Weidman
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Publication number: 20240116801Abstract: A colored glass article includes greater than or equal to 50 mol % and less than or equal to 80 mol % SiO2; greater than or equal to 7 mol % and less than or equal to 25 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 15 mol % B2O3; greater than or equal to 5 mol % and less than or equal to 20 mol % Li2O; greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; and greater than or equal to 1×10?6 mol % and less than or equal to 1 mol % Au. R2O—Al2O3 is greater than or equal to ?5 mol % and less than or equal to 7 mol %, R2O being the sum of Li2O, Na2O, and K2O.Type: ApplicationFiled: December 13, 2023Publication date: April 11, 2024Inventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Jian Luo, Liping Xiong Smith, Nicole Taylor Wiles
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Patent number: 11948792Abstract: Embodiments of a glass wafer for semiconductor fabrication processes are described herein. In some embodiments, a glass wafer includes: a glass substrate comprising: a top surface, a bottom surface opposing the top surface, and an edge surface between the top surface and the bottom surface; a first coating disposed atop the glass substrate, wherein the first coating is a doped crystalline silicon coating having a sheet-resistance of 100 to 1,000,000 ohm per square; and a second coating having one or more layers disposed atop the glass substrate, wherein the second coating comprises a silicon containing coating, wherein the glass wafer has an average transmittance (T) of less than 50% over an entire wavelength range of 400 nm to 1000 nm.Type: GrantFiled: November 25, 2020Date of Patent: April 2, 2024Assignee: CORNING INCORPORATEDInventors: Ya-Huei Chang, Karl William Koch, III, Jen-Chieh Lin, Jian-Zhi Jay Zhang
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Patent number: 11940593Abstract: A display article is described herein that includes: a substrate comprising a thickness and a primary surface; and the primary surface having defined thereon a diffractive surface region. The diffractive surface region comprises a plurality of structural features that comprises a plurality of different heights in a multimodal distribution. Further, the substrate exhibits a sparkle of less than 4%, as measured by pixel power deviation (PPD140) at an incident angle of 0° from normal, a distinctness of image (DOI) of less than 80% at an incident angle of 20° from normal, and a transmittance haze of less than 20% from an incident angle of 0° from normal.Type: GrantFiled: July 8, 2021Date of Patent: March 26, 2024Assignee: CORNING INCORPORATEDInventors: Jiangwei Feng, Shandon Dee Hart, Karl William Koch, III, Cameron Robert Nelson, Wageesha Senaratne, William Allen Wood
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Patent number: 11927722Abstract: A transparent article is described herein that includes: a glass-ceramic substrate comprising first and second primary surfaces opposing one another and a crystallinity of at least 40% by weight; and an optical film structure disposed on the first primary surface. The optical film structure comprises a plurality of alternating high refractive index (RI) and low RI layers and a scratch-resistant layer. The article also exhibits an average photopic transmittance of greater than 80% and a maximum hardness of greater than 10 GPa, as measured by a Berkovich Hardness Test over an indentation depth range from about 100 nm to about 500 nm. The glass-ceramic substrate comprises an elastic modulus of greater than 85 GPa and a fracture toughness of greater than 0.8 MPa·?m. Further, the optical film structure exhibits a residual compressive stress of ?700 MPa and an elastic modulus of ?140 GPa.Type: GrantFiled: March 13, 2023Date of Patent: March 12, 2024Assignee: Corning IncorporatedInventors: Jaymin Amin, Jason Thomas Harris, Shandon Dee Hart, Chang-gyu Kim, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Dong-gun Moon, Jeonghong Oh, James Joseph Price, Charlene Marie Smith, Ananthanarayanan Subramanian, Ljerka Ukrainczyk, Tingge Xu
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Publication number: 20240069246Abstract: An article is described herein that includes an optical coating on both a first portion and a second portion of a first major surface of a substrate. The first portion and the second portion face in different directions. The optical coating forms an anti-reflective surface, has a total thickness of less than 1000 nm, and is thicker over the first portion than over the second portion. The optical coating exhibits a first surface reflected color characterized by International Commission on Illumination (“CIE”) L*a*b* color space values of: (i) a*, from ?6.0 to +4.5, and (ii) b*, from ?11.0 to +6.0 at all viewing angles within a range of from 0 degrees to 10 degrees relative to a normal of the first major surface at both (i) the first portion and (ii) the second portion where the total thickness of the optical coating is 75% to 90% of the maximum value of the total thickness.Type: ApplicationFiled: August 24, 2023Publication date: February 29, 2024Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin
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Publication number: 20240059604Abstract: A glass composition includes greater than or equal to 50 mol % and less than or equal to 70 mol % SiO2; greater than or equal to 10 mol % and less than or equal to 20 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 10 mol % B2O3; greater than or equal to 7 mol % and less than or equal to 14 mol % Li2O; greater than 0 mol % and less than or equal to 8 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; greater than or equal to 0 mol % and less than or equal to 7 mol % CaO; greater than or equal to 0 mol % and less than or equal to 8 mol % MgO; and greater than or equal to 0 mol % and less than or equal to 8 mol % ZnO. R2O+R?O is less than or equal to 25 mol %, wherein R2O is the sum of Li2O, Na2O, and K2O and R?O is the sum of CaO, MgO, and ZnO. The glass composition includes at least one of NiO+Co3O4+Cr2O3+CuO is greater than or equal to 0.001 mol %, CeO2 is greater than or equal to 0.1 mol %, and TiO2 is greater than or equal to 0.1 mol %.Type: ApplicationFiled: November 3, 2023Publication date: February 22, 2024Inventors: Xiaoju Guo, Karl William Koch, III, Liping Xiong Smith, Nicole Taylor Wiles
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Patent number: 11906699Abstract: An article that includes: an inorganic oxide substrate having opposing major surfaces; and an optical film structure disposed on a first major surface of the substrate, the optical film structure comprising one or more of a silicon-containing oxide, a silicon-containing nitride and a silicon-containing oxynitride and a physical thickness from about 50 nm to less than 500 nm. The article exhibits a hardness of 8 GPa or greater measured at an indentation depth of about 100 nm or a maximum hardness of 9 GPa or greater measured over an indentation depth range from about 100 nm to about 500 nm, the hardness and the maximum hardness measured by a Berkovich Indenter Hardness Test. Further, the article exhibits a single-side photopic average reflectance that is less than 1%.Type: GrantFiled: January 10, 2022Date of Patent: February 20, 2024Assignee: Corning IncorporatedInventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Alexandre Michel Mayolet, James Joseph Price
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Publication number: 20240045106Abstract: An article is described herein that includes: a translucent substrate having a major surface; and an anti-reflective coating disposed on the major surface and forming an anti-reflective surface. The article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.35%. Further, the article exhibits a single side color shift (?C) of less than 6 over an incident angle range from 0 degrees to 60 degrees incidence at the anti-reflective surface, wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 500 nm. In addition, the anti-reflective coating comprises a plurality of layers that comprises at least one low refractive index layer and at least one high refractive index layer. Further, each high refractive index layer has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7.Type: ApplicationFiled: October 10, 2023Publication date: February 8, 2024Inventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, James Joseph Price, Nicholas Michael Walker
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Patent number: 11891332Abstract: A colored glass article includes greater than or equal to 50 mol % and less than or equal to 80 mol % SiO2; greater than or equal to 7 mol % and less than or equal to 25 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 15 mol % B2O3; greater than or equal to 5 mol % and less than or equal to 20 mol % Li2O; greater than or equal to 0.5 mol % and less than or equal to 15 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; and greater than or equal to 1×10?6 mol % and less than or equal to 1 mol % Au. R2O—Al2O3 is greater than or equal to ?5 mol % and less than or equal to 7 mol %, R2O being the sum of Li2O, Na2O, and K2O.Type: GrantFiled: January 5, 2023Date of Patent: February 6, 2024Assignee: Corning IncorporatedInventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Jian Luo, Liping Xiong Smith, Nicole Taylor Wiles
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Publication number: 20240036236Abstract: A cover glass article is described herein that includes: a substrate comprising an outer primary surface with an outer optical film structure disposed thereon and an inner primary surface with an inner optical film structure disposed thereon. The outer film structure comprises a first plurality of alternating high index and low index layers with an outermost low index layer. The inner film structure comprises a second plurality of alternating high index and low index layers with a low or high index layer disposed on the inner primary surface, and an innermost low or high index layer. Each high index layer of the first and the second plurality comprises a nitride or an oxynitride, and an oxide or a nitride, respectively. Further, the cover glass article exhibits an average photopic transmittance of greater than 95% and a maximum hardness of greater than 10 GPa.Type: ApplicationFiled: December 10, 2021Publication date: February 1, 2024Inventors: Albert Joseph Fahey, Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Alexandre Michel Mayolet, Xu Ouyang, Charles Andrew Paulson, James Joseph Price
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Patent number: 11834370Abstract: A glass composition includes greater than or equal to 50 mol % and less than or equal to 70 mol % SiO2; greater than or equal to 10 mol % and less than or equal to 20 mol % Al2O3; greater than or equal to 1 mol % and less than or equal to 10 mol % B2O3; greater than or equal to 7 mol % and less than or equal to 14 mol % Li2O; greater than 0 mol % and less than or equal to 8 mol % Na2O; greater than 0 mol % and less than or equal to 1 mol % K2O; greater than or equal to 0 mol % and less than or equal to 7 mol % CaO; greater than or equal to 0 mol % and less than or equal to 8 mol % MgO; and greater than or equal to 0 mol % and less than or equal to 8 mol % ZnO. R2O+R?O is less than or equal to 25 mol %, wherein R2O is the sum of Li2O, Na2O, and K2O and R?O is the sum of CaO, MgO, and ZnO. The glass composition includes at least one of NiO+Co3O4+Cr2O3+CuO is greater than or equal to 0.001 mol %, CeO2 is greater than or equal to 0.1 mol %, and TiO2 is greater than or equal to 0.1 mol %.Type: GrantFiled: January 4, 2023Date of Patent: December 5, 2023Assignee: Corning IncorporatedInventors: Xiaoju Guo, Karl William Koch, III, Liping Xiong Smith, Nicole Taylor Wiles
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Publication number: 20230373846Abstract: A colored glass article may include 50-80 mol % SiO2; 7-20 mol % Al2O3; 1-35 mol % R2O, wherein R2O comprises at least one of Li2O, Na2O, and K2O; 1×10?6-10 mol % of a colorant, wherein the colorant comprises at least one of Cr2O3, Au, Ag, CuO, NiO, Co3O4, TiO2, CeO2; and 12-24 mol % of Al2O3+MgO+CaO+ZnO. The colored glass article may have a transmittance color coordinate in the CIELAB color space with an L* value of 55 to 96.5. The colored glass article may have a compressive stress profile with a depth of compression ?0.15t a thickness t from 0.4 mm-5 mm, a compressive stress ?200 MPa, and a central tension ?60 MPa. The colored glass article may have a dielectric constant from 5.6 to 6.4 over the frequency range from 10 GHz to 60 GHz.Type: ApplicationFiled: August 1, 2023Publication date: November 23, 2023Inventors: Xiaoju Guo, Jill Marie Hall, Karl William Koch, III, Jesse Kohl, Liping Xiong Smith, Nicole Taylor Wiles
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Patent number: 11815657Abstract: An article is described herein that includes: a translucent substrate having a major surface; and an anti-reflective coating disposed on the major surface and forming an anti-reflective surface. The article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.35%. Further, the article exhibits a single side color shift (?C) of less than 6 over an incident angle range from 0 degrees to 60 degrees incidence at the anti-reflective surface, wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 500 nm. In addition, the anti-reflective coating comprises a plurality of layers that comprises at least one low refractive index layer and at least one high refractive index layer. Further, each high refractive index layer has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7.Type: GrantFiled: July 31, 2020Date of Patent: November 14, 2023Assignee: Corning IncorporatedInventors: Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, James Joseph Price, Nicholas M Walker
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Publication number: 20230359074Abstract: A transparent article is described herein that includes: a substrate comprising an opposing first and second primary surface; and an optical film structure disposed on the first primary surface. The optical film structure comprises a scratch-resistant layer, a plurality of alternating high refractive index (RI) and low RI layers, and an outer and inner structure, the scratch-resistant layer disposed between the outer and inner structures. The outer structure can comprise at least one medium RI layer in contact with one of the high RI layers and the scratch-resistant layer. The medium RI layer comprises an RI from 1.55 to 1.80, each of the high RI layers comprises an RI of >1.80, and each of the low RI layers comprises an RI<1.55. A sum of the physical thicknesses of all of the low RI layers in the outer structure can be <200 nm.Type: ApplicationFiled: May 2, 2023Publication date: November 9, 2023Inventors: Jaymin Amin, Jason Thomas Harris, Shandon Dee Hart, Karl William Koch, III, Carlo Anthony Kosik Williams, Lin Lin, Alexandre Michel Mayolet, Dong-gun Moon, Jeonghong Oh, Naveen Prakash, James Joseph Price, Charlene Marie Smith, Ananthanarayanan Subramanian, Ljerka Ukrainczyk, Florence Christine Monique Verrier, Tingge Xu, Binwei Zhang, Wenlei Zhang
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Publication number: 20230324583Abstract: Embodiments of this disclosure pertain to articles that exhibit scratch-resistance and improved optical properties. In some examples, the article exhibits a color shift of about 2 or less, when viewed at an incident illumination angle in the range from about 0 degrees to about 60 degrees from normal under an illuminant. In one or more embodiments, the articles include a substrate, and an optical film disposed on the substrate. The optical film includes a scratch-resistant layer and an optical interference layer. The optical interference layer may include one or more sub-layers that exhibit different refractive indices. In one example, the optical interference layer includes a first low refractive index sub-layer and a second a second high refractive index sub-layer. In some instances, the optical interference layer may include a third sub-layer.Type: ApplicationFiled: June 13, 2023Publication date: October 12, 2023Inventors: Robert Alan Bellman, Shandon Dee Hart, Karl William Koch, III, Charles Andrew Paulson, James Joseph Price
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Publication number: 20230303432Abstract: One or more aspects of the disclosure pertain to an article including an optical film structure disposed on an inorganic oxide substrate, which may include a strengthened or non-strengthened substrate that may be amorphous or crystalline, such that the article exhibits scratch resistance and retains the same or improved optical properties as the inorganic oxide substrate, without the optical film structure disposed thereon. In one or more embodiments, the article exhibits an average transmittance of 85% or more, over the visible spectrum (e.g., 380 nm - 780 nm). Embodiments of the optical film structure include aluminum-containing oxides, aluminum-containing oxy-nitrides, aluminum-containing nitrides (e.g., A1N) and combinations thereof. The optical film structures disclosed herein also include a transparent dielectric including oxides such as silicon oxide, germanium oxide, aluminum oxide and a combination thereof. Methods of forming such articles are also provided.Type: ApplicationFiled: April 18, 2023Publication date: September 28, 2023Inventors: Karl William Koch, III, Charles Andrew Paulson, James Joseph Price