Abstract: A surface treating composition is shown and described herein. A surface treating composition comprises (i) a hybrid siloxane oligomer comprises organosilicon units wherein the oligomer comprises organosilicon units with fluoro-functional groups, and organosilicon units with other reactive functionality, and (ii) a perfluoro(poly)ether group containing silane compound. The surface treating composition can be employed to provide a hydrophobic and/or oleophobic surface coating on a surface of a substrate, which may impart other beneficial properties to the article.

Abstract: A hybrid siloxane oligomer is shown and described herein. A hybrid siloxane oligomer comprises organosilicon units wherein the oligomer comprises organosilicon units with fluoro-functional groups, and organosilicon units with other reactive functionality. The oligomers can be employed to form a coating on a surface of an article to provide a hydrophobic and/or oleophobic surface coating, which may impart other beneficial properties to the article.

Abstract: A silicone polyether for use in forming a solid polymer electrolyte film, the silicone polyether comprising a heterocyclic moiety. The silicone polyether comprising the heterocyclic moiety may be used to provide an electrolyte composition suitable for use in an electrochemical device. The silicone polyether comprising a heterocyclic moiety may also be used to form a solid polymer electrolyte that may be used to form a solid polymer electrolyte film, which may be suitable for use in electrochemical devices.

Abstract: A functionalized siloxane network. The functionalized network comprises a ligand attached to the network. The ligand includes a pyridine-containing compound, and in one embodiment, the ligand includes a terpyridine compound. The functionalized siloxane network can be siloxane particles. The functionalized siloxane network can coordinate metal ions and can be used in luminescent articles.

Abstract: A functionalized siloxane includes a ligand capable of coordinating a metal. The functionalized siloxane includes a pyridine-containing ligand attached to a siloxane polymer. The functionalized siloxanes can be employed to provide complexes including a metal that may impart a desired property to the polymer. In one embodiment, the polymer can complex lanthanide metals that are capable of phosphorescing upon exposure to UV irradiation. Such polymers can be employed to provide functional materials such as, for example, luminescent films, coatings, etc.

Abstract: A silicone polyether for use in forming a solid polymer electrolyte film, the silicone polyether comprising a heterocyclic moiety. The silicone polyether comprising the heterocyclic moiety may be used to provide an electrolyte composition suitable for use in an electrochemical device. The silicone polyether comprising a heterocyclic moiety may also be used to form a solid polymer electrolyte that may be used to form a solid polymer electrolyte film, which may be suitable for use in electrochemical devices.

Abstract: The present technology provides a coating system including a curable silicone polymer and a catalyst, wherein the catalyst is selected from a super base, a salt of a super base, or a combination of two or more thereof.

Abstract: The present invention relates to silicone epoxy compositions, methods for making same and uses therefore. In one embodiment, the silicone epoxy ether compositions of the present invention are silane epoxy polyethers that contain at least one epoxy functionality. In another embodiment, the silicone epoxy ether compositions of the present invention are siloxane epoxy polyethers that contain at least one epoxy functionality. In still another embodiment, the present invention relates to silicone epoxy polyether compositions that are suitable for use as an electrolyte solvent in a lithium-based battery, an electrochemical super-capacitors or any other electrochemical device.

Abstract: There is provided herein a composition which contains hydride-functionalized siloxane or silane, a hydroxyl-containing compound that does not contain silicon, and a catalytically-effective amount of super acid or super base catalyst selected from the group consisting of a triaza-containing compound which contains only carbon, nitrogen and hydrogen atoms, an atrane compound, a linear or branched compound containing a sulfonyl group and a fluoro group, and combinations thereof. There is also provided a process of making such a composition.

Abstract: A functionalized siloxane network. The functionalized network comprises a ligand attached to the network. The ligand includes a pyridine-containing compound, and in one embodiment, the ligand includes a terpyridine compound. The functionalized siloxane network can be siloxane particles. The functionalized siloxane network can coordinate metal ions and can be used in luminescent articles.

Abstract: The present technology provides a coating system including a luminophoric material. The luminophoric material is a pyridine-containing ligand chosen from a substituted or unsubstituted bidentate pyridine compound, a substituted or unsubstituted tridentate pyridine compound, or a combination of two or more thereof. Alternatively, the luminophoric material may be a fluorescent dye. The coating system may include a topcoat material, a primer material, or a combination thereof.

Abstract: A functionalized siloxane includes a ligand capable of coordinating a metal. The functionalized siloxane includes a pyridine-containing ligand attached to a siloxane polymer. The functionalized siloxanes can be employed to provide complexes including a metal that may impart a desired property to the polymer. In one embodiment, the polymer can complex lanthanide metals that are capable of phosphorescing upon exposure to UV irradiation. Such polymers can be employed to provide functional materials such as, for example, luminescent films, coatings, etc.

Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a N-trialkylsilyl-bis(perfluoroalkylsulfonyl)imide compound.

Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a bicyclic guanidine compound. The guanidine-containing compounds useful in the ring opening reaction include a fused ring structure comprising a guanidine functional group as part of the fused ring.

Abstract: Compositions and methods for the production of siloxane materials using an azaphosphatrane as a catalyst. In one embodiment, there is provided a process for the ring opening polymerization of a cyclosiloxane in the presence of an azaphosphatrane. In another embodiment, there is provided a composition and method for condensation curing of a moisture curable composition using an azaphosphatrane.

Abstract: There is provided herein a composition which contains hydride-functionalized siloxane or silane, a hydroxyl-containing compound that does not contain silicon, and a catalytically-effective amount of super acid or super base catalyst selected from the group consisting of a triaza-containing compound which contains only carbon, nitrogen and hydrogen atoms, an atrane compound, a linear or branched compound containing a sulfonyl group and a fluoro group, and combinations thereof. There is also provided a process of making such a composition.

Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a N-trialkylsilyl-bis(perfluoroalkylsulfonyl)imide compound.

Abstract: Compositions and methods for the production of siloxane materials using an azaphosphatrane as a catalyst. In one embodiment, there is provided a process for the ring opening polymerization of a cyclosiloxane in the presence of an azaphosphatrane. In another embodiment, there is provided a composition and method for condensation curing of a moisture curable composition using an azaphosphatrane.

Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a bicyclic guanidine compound. The guanidine-containing compounds useful in the ring opening reaction include a fused ring structure comprising a guanidine functional group as part of the fused ring.

Abstract: The present invention relates to silicone epoxy compositions, methods for making same and uses therefore. In one embodiment, the silicone epoxy ether compositions of the present invention are silane epoxy polyethers that contain at least one epoxy functionality. In another embodiment, the silicone epoxy ether compositions of the present invention are siloxane epoxy polyethers that contain at least one epoxy functionality. In still another embodiment, the present invention relates to silicone epoxy polyether compositions that are suitable for use as an electrolyte solvent in a lithium-based battery, an electrochemical super-capacitors or any other electrochemical device.