Patents by Inventor Kazuhito Hashimoto

Kazuhito Hashimoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20020125457
    Abstract: A molecule mixed magnetic material having at least a kind of a magnetic ion unit of a molecular magnetic material showing a ferromagnetism and at least 1 kind of a magnetic ion unit of a molecular magnetic material showing a ferrimagnetism for controlling the magnetic characteristics of the molecular magnetic materials, wherein the magnetic characteristics are changeable by controlling the existing ratio of both the magnetic ion units, or the magnetic characteristics are changeable by the change of temperature or by the irradiation of light.
    Type: Application
    Filed: March 7, 2002
    Publication date: September 12, 2002
    Inventors: Shinichi Ohkoshi, Akira Fujishima, Kazuhito Hashimoto, Tomokazu Iyoda
  • Publication number: 20020107144
    Abstract: A titanium dioxide film (2) having at least photocatalytic activity, whose light linear transmittance corresponding to light having a wavelength of 550 nm is not less than 50% and whose thickness is 0.1 to 5 &mgr;m or so, is formed on a transparent substrate (1) constituted by a glass plate or the like. Preferably, a precoat film (3), which has optical transmissivity and is constituted by a SiO2 film having a thickness of 0.02 to 0.2 &mgr;m or so, is provided between the transparent substrate (1) and the titanium dioxide film (2). Thereby, excellent photocatalytic action and optical transmissivity can be obtained. Moreover, members composing various structures such as a glass window, which are especially required to have optical transparency, can be further provided with photocatalytic activities.
    Type: Application
    Filed: March 22, 2002
    Publication date: August 8, 2002
    Inventors: Akira Fujishima, Kazuhito Hashimoto, Tomokazu Iyoda, Shigemichi Fukayama, Tetsuo Yoshimoto, Tokuyoshi Saitoh
  • Patent number: 6387844
    Abstract: A titanium dioxide film having at least photocatalytic activity, whose light linear transmittance corresponding to light having a wavelength of 550 nm is not less than 50 % and whose thickness is 0.1 to 5 &mgr;m or so, is formed on a transparent substrate constituted by a glass plate or the like. Preferably, a precoat film, which has optical transmissivity and is constituted by a SiO2 film having a thickness of 0.02 to 0.2 &mgr;m or so, is provided between the transparent substrate and the titanium dioxide film. Thereby, excellent photocatalytic action and optical transmissivity can be obtained. Moreover, members composing various structures such as a glass window, which are especially required to have optical transparency, can be further provided with photocatalytic activities.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: May 14, 2002
    Inventors: Akira Fujishima, Kazuhito Hashimoto, Tomokazu Iyoda, Shigemichi Fukayama, Tetsuo Yoshimoto, Tokuyoshi Saitoh
  • Publication number: 20020016250
    Abstract: The surface of a substrate is coated with an abrasion-resistant photocatalytic coating comprised of a semiconductor photocatalyst. Upon irradiation by a light having a wavelength of an energy higher than the bandgap energy of the photocatalyst, water is chemisorbed onto the surface in the form of hydroxyl groups (OH−) whereby the surface of the photocatalytic coating is rendered highly hydrophilic. In certain embodiments, the surface of a mirror, lens, or windowpane is coated with the photocatalytic coating to exhibit a high degree of antifogging function. In another embodiment, an article or product coated with the photocatalytic coating is disposed outdoors and the highly hydrophilic surface thereof is self-cleaned as it is subjected to rainfall. In a still another embodiment, an article is coated with the photocatalytic coating and, when the article is soaked in, rinsed by or wetted with water, fatty dirt and contaminants are readily released without resort to a detergent.
    Type: Application
    Filed: August 14, 2001
    Publication date: February 7, 2002
    Inventors: Makoto Hayakawa, Eiichi Kojima, Keiichiro Norimoto, Mitsuyoshi Machida, Atsushi Kitamura, Toshiya Watanabe, Makoto Chikuni, Akira Fujishima, Kazuhito Hashimoto
  • Publication number: 20010046937
    Abstract: A photocatalyst composite is provided which comprise a substrate having particles of a photocatalyst such as titanium oxide, adhered thereon via a less degradative adhesive such as a fluorinated polymer comprising a copolymer of a vinyl ester and/or vinyl ether and a fluoroolefin, or a silicon based polymer or cement. Furthermore, a process for producing the photocatalyst composite and a coating composition containing the photocatalyst composite are provided.
    Type: Application
    Filed: June 27, 2001
    Publication date: November 29, 2001
    Inventors: Sadao Murasawa, Hajime Murakami, Yasuro Fukui, Mitsuru Watanabe, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 6277346
    Abstract: A photocatalyst composite is provided which comprise a substrate having particles of a photocatalyst such as titanium oxide, adhered thereon via a less degradative adhesive such as a fluorinated polymer comprising a copolymer of a vinyl ester and/or vinyl ether and a fluoroolefin, or a silicon based polymer or cement. Furthermore, a process for producing the photocatalyst composite and a coating composition containing the photocatalyst composite are provided.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: August 21, 2001
    Assignees: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Sadao Murasawa, Hajime Murakami, Yasuro Fukui, Mitsuru Watanabe, Akira Fujishima, Kazuhito Hashimoto
  • Publication number: 20010001288
    Abstract: There is provided a method of manufacturing a color display including a color filter and a black matrix, characterized in that it comprises the steps of: forming a film of zinc oxide on a transparent substrate; forming the the color filter on the said film of zinc oxide; and thereafter, applying a deposit of electroless copper plating on an area of the said film of zinc oxide on which the said color filter is not formed, the said deposit having a thickness which is substantially equal to a thickness of the said color filter and constituting an element of said black matrix. Thus, a color display may be provided with a black matrix that is of high optical density and a low reflectivity. The black matrix can also be commensurate with film thickness with the color matrix. No photo lithographic process is required in preparing the color filter and black matrix. Various modified forms of embodiments of the method of manufacturing a color display are also disclosed.
    Type: Application
    Filed: December 20, 2000
    Publication date: May 17, 2001
    Inventors: Makoto Tomoyori, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 6208404
    Abstract: There is provided a method of manufacturing a color display including a color filter and a black matrix, characterized in that it comprises the steps of: forming a film of zinc oxide on a transparent substrate; forming the the color filter on the said film of zinc oxide; and thereafter, applying a deposit of electroless copper plating on an area of the said film of zinc oxide on which the said color filter is not formed, the said deposit having a thickness which is substantially equal to a thickness of the said color filter and constituting an element of said black matrix. Thus, a color display may be provided with a black matrix that is of high optical density and a low reflectivity. The black matrix can also be commensurate with film thickness with the color matrix. No photo lithographic process is required in preparing the color filter and black matrix. Various modified forms of embodiments of the method of manufacturing a color display are also disclosed.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: March 27, 2001
    Assignee: Tryonics Corporation
    Inventors: Makoto Tomoyori, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 6139803
    Abstract: A process for photocatalytically treating a hospital room contaminated by bacteria or an interior environment bearing airborne malodorous substances. A thin film of photocatalyst made of a semiconductor such as titanium dioxide is disposed on the inner wall of the hospital room or living space. The photocatalytic thin film is irradiated by a light source suitable for general lighting applications, such as a fluorescent lamp, and is photoexcited by the small amount of ultraviolet radiation included in the light of the fluorescent lamp. The wattage of the fluorescent lamp as well as the distance between the photocatalytic thin film and the lamp are selected such that the intensity of those UV wavelengths which have a higher energy than the band gap energy of the photo-catalyst is 0.001-1 mW/cm.sup.2, preferably, 0.01-0.1 mW/cm.sup.2. The bacteria and chemical compounds deposited on the photoexcited thin film are photodecomposed.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: October 31, 2000
    Assignee: Toto Co., Ltd.
    Inventors: Toshiya Watanabe, Atushi Kitamura, Eiichi Kojima, Kazuhito Hashimoto, Akira Fujishima
  • Patent number: 6117568
    Abstract: The invention provides a novel cyanochromium-complex-based magnetic material formed on an electrode, which is excellent in magnetic properties and of which magnetic properties are reversibly controllable, by impressing a reduction potential which electrochemically reduces Cr.sup.3+ into Cr.sup.2+ in a solution containing at least [Cr(CN).sub.6 ].sup.3- and Cr.sup.3+.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: September 12, 2000
    Assignee: Kanagawa Academy of Science and Technology
    Inventors: Kazuhito Hashimoto, Akira Fujishima, Osamu Sato, Tomokazu Iyoda
  • Patent number: 6106955
    Abstract: A metal material having a photocatalytic activity which comprises an anodized layer and a thin layer containing titanium oxide powder which are heat treated are sequentially laminated on the surface of a substrate comprising metal material including titanium. By anodically oxidizing the metal material including titanium, an anodized layer is formed on the surface thereof. A thin layer containing titanium oxide powder is further coated on this surface, and heat treatment is carried out before and/or after forming this thin layer containing titanium oxide powder.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: August 22, 2000
    Assignees: Takenaka Corporation, Kobe Steel Ltd.
    Inventors: Takatoshi Ogawa, Toshio Saito, Sadatoshi Ohno, Atsumichi Kushibe, Fumio Kamikubo, Tatsuya Yasunaga, Takashi Kato, Yoshimasa Ito, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 6106692
    Abstract: There is provided a concentration sensor for measurement of concentrations of one or plural target substances in a system, with a detection electrode of conductive diamond. The measuring method with the concentration sensor involves measuring the reaction potentials of plural target substances in a sample containing and determining the concentrations of the plural substances by use of the difference between the resulting reaction potentials of the respective substances. The measuring method can also determine the concentration of a single substance in a sample containing one kind of target substance.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: August 22, 2000
    Assignees: Imra Japan Kabushikikaisha, Akira Fujishima, Kazuhito Hashimoto, Kohei Uosaki
    Inventors: Keiji Kunimatsu, Toshihide Nakata, Toshiya Saito, Mayumi Kazuta, Akira Fujishima, Kazuhito Hashimoto, Kohei Uosaki
  • Patent number: 6099695
    Abstract: A ZnO--Pd composite catalyst wherein Pd is dispersed and fixed on the surface of ZnO is produced by ion adsorption process having the steps of soaking ZnO in an acid solution of Pd to adsorb Pd ions (Pd.sup.2+) onto the surface of ZnO; and reducing the adsorbed Pd ions to metallic Pd particles so that the metallic Pd particles are substantially evenly deposited on the surface of ZnO. The ZnO--Pd composite catalyst provides a stable and continuing CO oxidizing capability, without light irradiation, even when the air to be treated contains sulfur compounds such as H.sub.2 S and SOx.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: August 8, 2000
    Assignees: Akira Fujishima, Kazuhito Hashimoto, Kabushikikaisha Equos Research, Aisin AW Co., Ltd.
    Inventors: Akira Fujishima, Kazuhito Hashimoto, Shuzo Moroto, Masao Ando, Masako Sakai
  • Patent number: 6090489
    Abstract: A method for hydrophilifying the surface of a substrate by taking advantage of photocatalytic action. The substrate has a photocatalytic titania coating (10). The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy in the solid/gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH group (12), bonded to a titanium atom, and a bridge OH group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: July 18, 2000
    Assignee: Toto, Ltd.
    Inventors: Makoto Hayakawa, Eiichi Kojima, Keiichiro Norimoto, Mitsuyoshi Machida, Atsushi Kitamura, Toshiya Watanabe, Makoto Chikuni, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 6013372
    Abstract: The surface of a substrate is coated with an abrasion-resistant photocatalytic coating comprised of a semiconductor photocatalyst. Upon irradiation by a light having a wavelength of an energy higher than the bandgap energy of the photocatalyst, water is chemisorbed onto the surface in the form of hydroxyl groups (OH.sup.--) whereby the surface of the photocatalytic coating is rendered highly hydrophilic. In certain embodiments, the surface of a mirror, lens, or windowpane is coated with the photocatalytic coating to exhibit a high degree of antifogging function. In another embodiment, an article or product coated with the photocatalytic coating is disposed outdoors and the highly hydrophilic surface thereof is self-cleaned as it is subjected to rainfall. In a still another embodiment, an article is coated with the photocatalytic coating and, when the article is soaked in, rinsed by or wetted with water, fatty dirt and contaminants are readily released without resort to a detergent.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: January 11, 2000
    Assignee: Toto, Ltd.
    Inventors: Makoto Hayakawa, Eiichi Kojima, Keiichiro Norimoto, Mitsuyoshi Machida, Atsushi Kitamura, Toshiya Watanabe, Makoto Chikuni, Akira Fujishima, Kazuhito Hashimoto
  • Patent number: 5948355
    Abstract: An air-purifying filter includes a carrier base and a TiO.sub.2 -Pd composite catalyst supported on the carrier base. CO in air treated by the filter is adsorbed onto the Pd surface and thus decomposed by oxidization to CO.sub.2, whereas sulfur compounds in the air are adsorbed onto the Pd surface and then transferred to the TiO.sub.2 surface where they are decomposed by oxidization to SO.sub.4.sup.-2 when the TiO.sub.2 is subjected to irradiation. Preferably, Pd exists in a relatively small quantity at a first side of the carrier base in the vicinity of a light source and in a greater quantity at a second side opposite the first side. The first side is preferably located upstream relative to flow of air treated by the filter. An air-purifier utilizing this filter is mounted in an automobile, preferably on a rear shelf or in a trunk compartment.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: September 7, 1999
    Assignees: Akira Fujishima, Kazuhito Hashimoto, KabushikiKaisha Equos Research, Aisin Aw Co., Ltd.
    Inventors: Akira Fujishima, Kazuhito Hashimoto, Shuzo Moroto, Masao Ando, Masako Sakai
  • Patent number: 5939194
    Abstract: A method for highly hydrophilifying the surface of an article by photoexcitation of a semiconductor photocatalyst and maintaining the hydrophilicity is disclosed. A layer containing a photocatalyst is formed on a substrate. Onto the surface of the layer are fixed a hydroxyl group upon photoexcitation of the photocatalyst and a physically adsorbed water molecule in the vicinity of the hydroxyl group upon photoexcitation of the photocatalyst. Thus, the surface is highly hydrophilified. Further, this surface, simultaneously with the hydrophilification, exhibits higher hydrophobicity.
    Type: Grant
    Filed: December 9, 1997
    Date of Patent: August 17, 1999
    Assignee: Toto Ltd.
    Inventors: Kazuhito Hashimoto, Akira Fujishima, Toshiya Watanabe, Mitsuhide Shimohigoshi, Makoto Hayakawa
  • Patent number: 5874701
    Abstract: A process for photocatalytically treating a hospital room contaminated by bacteria or an interior environment bearing airborne malodorous substances. A thin film of photocatalyst made of a semiconductor such as titanium dioxide is disposed on the inner wall of the hospital room or living space. The photocatalytic thin film is irradiated by a light source suitable for general lighting applications, such as a fluorescent lamp, and is photoexcited by the small amount of ultraviolet radiation included in the light of fluorescent lamp. The wattage of the fluorescent lamp as well as the distance between the photocatalytic thin film and the lamp are selected such that the intensity of those UV wavelengths which have a higher energy than the band gap energy of the photo-catalyst is 0.001-1 mW/cm.sup.2, preferably, 0.01-0.1 mW/cm.sup.2. The bacteria and chemical compounds deposited on the photoexcited thin film are photodecomposed.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: February 23, 1999
    Assignee: Toto Co., Ltd.
    Inventors: Toshiya Watanabe, Atushi Kitamura, Eiichi Kojima, Kazuhito Hashimoto, Akira Fujishima
  • Patent number: 5855595
    Abstract: A tumor treatment apparatus is provided including a light source which emits a bundle of light including ultraviolet radiation, visible radiation and infrared radiation. Also provided are an infrared radiation filter which filters infrared radiation, a visible radiation filter which filters visible radiation, and an optical fiber which transmits a bundle of light transmitted through the infrared radiation filter and the visible radiation filter toward an affected part of a patient to be treated.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: January 5, 1999
    Assignees: Asahi Kogaku Kogyo Kabushiki Kaisha, Akira Fujishima, Kazuhito Hashimoto, Yoshinobu Kubota
    Inventors: Akira Fujishima, Kazuhito Hashimoto, Yoshinobu Kubota, Rensuke Adachi, Teruyuki Kakeda
  • Patent number: 5668076
    Abstract: A photocatalyst comprises, on the surface, a zinc oxide film which comprises zinc oxide fine particles formed by anodic oxidation of zinc and having a particle size of not more than 0.2 .mu.m and a method for preparing a photocatalyst comprises the step of anodically oxidizing the surface of a zinc metal substance or a substance mainly comprising zinc metal to form, on the surface, a zinc oxide film which comprises zinc oxide fine particles having a particle size of not more than 0.2 .mu.m. The photocatalyst permits quite efficient decomposition or destruction of gases or bacterial cells to be treated, can easily be adhered to faces to which the photocatalytic function is to be imparted to thus impart sterilization and/or deodorization functions thereto and can easily be fitted to various apparatuses to which a film has conventionally been applied with great difficulty.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: September 16, 1997
    Assignee: Mitsui Mining Smelting Co., Ltd. et al.
    Inventors: Yasuhide Yamagushi, Masatoshi Yamazaki, Akira Fujishima, Kazuhito Hashimoto