Abstract: The lithium ion conductive material includes, in mole percent on an oxide basis, 36.6 to 37.3% of a P2O5 component, 43.0 to 48.1% of a TiO2 component, 0.6 to 3.2% of an Al2O3 component and 13.9 to 17.5% of a Li2O component, wherein a mole percent of the Al2O3 component is 0.3 to 3.0% by mole smaller than a mole percent of an Al2O3 component calculated by the composition formula Li1+xAlxTi2-xP3O12 (x=0.05 to 0.4) derived from the composition of Ti and Li, and a mole percent of the P2O5 component is 0.2 to 2.0% by mole smaller than a mole percent of a P2O5 component calculated by the above composition formula, and wherein the lithium ion conductive material further includes a crystal phase with a rhombohedral NASICON structure or a Li1+xAlxTi2-xP3O12 (x?0) crystal phase.

Abstract: An electrochemical cell includes an all-solid-state electrode body in which a positive electrode layer and a negative electrode layer are laminated together through a solid electrolyte and an exterior body having a cavity in which the electrode body is stored. The exterior body has a first case and a second case which sandwich the electrode body and a sealing member that defines the cavity together with the first case and the second case by joining the first case and the second. The thermal expansion coefficients of the electrode body, the first case, the second case, and the sealing member are all 10×10?6/° C. or lower.

Abstract: The present invention provides an electrochemical cell including: an electrode body; an exterior packaging body in which a plurality of substrates including a first substrate formed from a ceramic material are stacked in the first direction, and a cavity in which the electrode body is accommodated is formed; a first electrode connection wiring that is formed in the exterior packaging body and connects a first electrode layer and an external substrate to each other; and a second electrode connection wiring that is forming in the exterior packaging body and connects a second electrode layer and the external substrate to each other. At least the first electrode connection wiring is formed in the first substrate, and an attachment portion, to which a fastening member configured to mount at least the first electrode connection wiring to the external substrate is attached, is formed in the first substrate.

Abstract: An all-solid secondary battery has first electrode layers, and second electrode layers laminated on both sides of the first electrode layer with solid electrolyte layers placed in between, wherein at least one first opening is provided which penetrates the first electrode layer and the solid electrolyte layers adjacent to the first electrode layer, and the second electrode layers present on both sides of the first electrode layer are in contact with each other on the inside of the first opening.

Abstract: The present invention is an all-solid-state electrode body including: a positive electrode via that is formed in a negative electrode connection layer, and connects a plurality of a positive electrode connection layers adjacent to each other in a first direction; a negative electrode via that is formed in the positive electrode connection layer, and connects a plurality of the negative electrode connection layers adjacent to each other in the first direction; a positive electrode current collector layer which is exposed on a first surface that faces one side of the first direction in a stacked body, and is connected to the positive electrode connection layer via the positive electrode via; and a negative electrode current collector layer which is exposed on the first surface in the stacked body, and is connected to the negative electrode connection layer via the negative electrode via.

Abstract: The present invention provides an electrochemical cell including: an electrode body; an exterior packaging body in which a plurality of substrates including a first substrate formed from a ceramic material are stacked in the first direction, and a cavity in which the electrode body is accommodated is formed; a first electrode connection wiring that is formed in the exterior packaging body and connects a first electrode layer and an external substrate to each other; and a second electrode connection wiring that is forming in the exterior packaging body and connects a second electrode layer and the external substrate to each other. At least the first electrode connection wiring is formed in the first substrate, and an attachment portion, to which a fastening member configured to mount at least the first electrode connection wiring to the external substrate is attached, is formed in the first substrate.

Abstract: The present invention is an all-solid-state electrode body including: a positive electrode via that is formed in a negative electrode connection layer, and connects a plurality of a positive electrode connection layers adjacent to each other in a first direction; a negative electrode via that is formed in the positive electrode connection layer, and connects a plurality of the negative electrode connection layers adjacent to each other in the first direction; a positive electrode current collector layer which is exposed on a first surface that faces one side of the first direction in a stacked body, and is connected to the positive electrode connection layer via the positive electrode via; and a negative electrode current collector layer which is exposed on the first surface in the stacked body, and is connected to the negative electrode connection layer via the negative electrode via.

Abstract: An electrochemical cell includes an all-solid-state electrode body in which a positive electrode layer and a negative electrode layer are laminated together through a solid electrolyte and an exterior body having a cavity in which the electrode body is stored. The exterior body has a first case and a second case which sandwich the electrode body and a sealing member that defines the cavity together with the first case and the second case by joining the first case and the second. The thermal expansion coefficients of the electrode body, the first case, the second case, and the sealing member are all 10×10?6/° C. or lower.

Abstract: To provide an all-solid lithium ion secondary battery having a high voltage, a small internal resistance, and a discharge capacity close to a theoretical capacity and being able to be produced at low cost, and therefore, even in the case of collective sintering, generation of an inactive material due to interface reaction at the interface between an electrode active material and a solid electrolyte is reduced. An all-solid lithium ion secondary battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer disposed between the positive electrode layer and the negative electrode layer, wherein an electrode active material included in the positive electrode layer is a phosphate having an olivine structure; and a solid electrolyte crystal included in the solid electrolyte layer includes polyphosphoric acid and the content of Li2O is 16 mol % to 25 mol % in terms of mol % on an oxide basis.

Abstract: An all solid state battery having high output performance and a manufacturing method thereof are provided. The all solid state battery of the present invention comprises a negative electrode layer, a positive electrode layer, and a solid electrolyte layer having a lithium ion conductivity. At least one layer of the solid electrolyte, the positive electrode layer, and the negative electrode layer includes a lithium ion conductive crystal and AxByOz (A is one or more selected from the group consisting of Al, Ti, Li, Ge, and Si. B is one or more selected from the group consisting of P, N, and C, wherein 1?X?4, 1?Y?5, and 1?Z?7). The solid electrolyte material to which a preferable sintering additive is added in a predetermined ratio is densified by firing at relatively low temperature in the manufacturing process. The ion conductivity thereof is also high.

Abstract: The all-solid battery has two electrode layers of a positive electrode and a negative electrode interposing a solid electrolyte layer therebetween, in which at least one of the electrode layers is composed of a sintered body of a mixed material including at least one or more types of electrode active material particles comprising electrode active material and solid electrolyte particles comprising solid electrolyte, and a portion of at least 30% by area of a grain boundary surrounding the electrode active material particles has a coating layer with a thickness of 1 to 200 nm.

Abstract: To provide a lithium ion conductive inorganic substance that makes it possible to further enhance the charge-discharge voltage of batteries and to further improve the charge-discharge properties of batteries. The lithium ion conductive inorganic substance includes a ZrO2 component from 2.6% to 52.0% by mass on an oxide basis. The lithium ion conductive inorganic substance is preferably used for lithium ion secondary batteries that have a positive electrode layer, a negative electrode layer, and a solid electrolyte layer intervening between the positive electrode layer and the negative electrode layer.

Abstract: In the all-solid secondary battery of the present invention, a positive electrode layer and a negative electrode layer are disposed on both sides of a solid electrolyte layer, a first inorganic solid electrolyte and a second inorganic solid electrolyte are included into at least one of the positive electrode layer, the negative electrode layer, and the solid electrolyte layer, the content of transition metal in the first inorganic solid electrolyte is less than 15% by mass on oxide basis, and the content of transition metal in the second inorganic solid electrolyte is 15% by mass or more on oxide basis.

Abstract: To provide an all-solid lithium ion secondary battery having a high voltage, a small internal resistance, and a discharge capacity close to a theoretical capacity and being able to be produced at low cost, and therefore, even in the case of collective sintering, generation of an inactive material due to interface reaction at the interface between an electrode active material and a solid electrolyte is reduced. An all-solid lithium ion secondary battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer disposed between the positive electrode layer and the negative electrode layer, wherein an electrode active material included in the positive electrode layer is a phosphate having an olivine structure; and a solid electrolyte crystal included in the solid electrolyte layer includes polyphosphoric acid and the content of Li2O is 16 mol % to 25 mol % in terms of mol % on an oxide basis.

Abstract: An all-solid secondary battery has first electrode layers, and second electrode layers laminated on both sides of the first electrode layer with solid electrolyte layers placed in between, wherein at least one first opening is provided which penetrates the first electrode layer and the solid electrolyte layers adjacent to the first electrode layer, and the second electrode layers present on both sides of the first electrode layer are in contact with each other on the inside of the first opening.

Abstract: To provide a lithium ion conductive inorganic substance that makes it possible to further enhance the charge-discharge voltage of batteries and to further improve the charge-discharge properties of batteries. The lithium ion conductive inorganic substance includes a ZrO2 component from 2.6% to 52.0% by mass on an oxide basis. The lithium ion conductive inorganic substance is preferably used for lithium ion secondary batteries that have a positive electrode layer, a negative electrode layer, and a solid electrolyte layer intervening between the positive electrode layer and the negative electrode layer.

Abstract: In the all-solid secondary battery of the present invention, a positive electrode layer and a negative electrode layer are disposed on both sides of a solid electrolyte layer, a first inorganic solid electrolyte and a second inorganic solid electrolyte are included into at least one of the positive electrode layer, the negative electrode layer, and the solid electrolyte layer, the content of transition metal in the first inorganic solid electrolyte is less than 15% by mass on oxide basis, and the content of transition metal in the second inorganic solid electrolyte is 15% by mass or more on oxide basis.

Abstract: An all solid state battery having high output performance and a manufacturing method thereof are provided. The all solid state battery of the present invention comprises a negative electrode layer, a positive electrode layer, and a solid electrolyte layer having a lithium ion conductivity. At least one layer of the solid electrolyte, the positive electrode layer, and the negative electrode layer includes a lithium ion conductive crystal and AxByOz (A is one or more selected from the group consisting of Al, Ti, Li, Ge, and Si. B is one or more selected from the group consisting of P, N, and C, wherein 1?X?4, 1?Y?5, and 1?Z?7). The solid electrolyte material to which a preferable sintering additive is added in a predetermined ratio is densified by firing at relatively low temperature in the manufacturing process. The ion conductivity thereof is also high.

Abstract: The all-solid battery has two electrode layers of a positive electrode and a negative electrode interposing a solid electrolyte layer therebetween, in which at least one of the electrode layers is composed of a sintered body of a mixed material including at least one or more types of electrode active material particles comprising electrode active material and solid electrolyte particles comprising solid electrolyte, and a portion of at least 30% by area of a grain boundary surrounding the electrode active material particles has a coating layer with a thickness of 1 to 200 nm.