Patents by Inventor Kazumi Tsubaki

Kazumi Tsubaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4666637
    Abstract: A process for producing chlorobenzene sulfochloride comprises adding a reaction mixture of chlorobenzene and chlorosulfonic acid to water or diluted sulfuric acid to decompose excess chlorosulfonic acid; driving off hydrogen chloride thereby generated, from the system; bringing the sulfuric acid concentration in the sulfuric acid layer upon completion of the decomposition to be from 60 to 90%; and then separating chlorobenzene sulfochloride. The process is characterized in that the excess chlorosulfonic acid is decomposed at a temperature of from 40.degree. to 85.degree. C. and the chlorobenzene sulfochloride is separated in a liquid state at a temperature of from 60.degree. to 80.degree. C.
    Type: Grant
    Filed: October 17, 1985
    Date of Patent: May 19, 1987
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kazumi Tsubaki, Noriaki Koto, Kouichi Maeda
  • Patent number: 4448948
    Abstract: An epoxy resin substantially represented by the general formula ##STR1## where Ar.sup.1 is a residual group of a dihydric phenol derived from a compound having one or two benzene nuclei, Ar.sup.2 is residual group of a halogen-substituted benzenoid compound having two halogen atoms on its nuclei and represented by the formula --Ar.sup.3 --Y--Ar.sup.4 -- where each of Ar.sup.3 and Ar.sup.4 is a hydrocarbon group having a divalent benzene nucleus and Y is a sulfone group or a carbonyl group, and n is an integer of from 1 to 50.
    Type: Grant
    Filed: January 14, 1983
    Date of Patent: May 15, 1984
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kazumi Tsubaki, Hiroshi Morinaga, Joei Yukawa
  • Patent number: 4424321
    Abstract: A copolymer of ethylene and a C.sub.4 -C.sub.10 .alpha.-olefin at a content of 0.5 to 10 mol % is produced by forming a polymerization catalyst system by reacting a Grignard reagent with a chain or cyclic hydropolysiloxane having the unitR.sup.1.sub.a H.sub.b SiO.sub.(4-a-b/2)(R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3), to form a reaction product (a); reacting the reaction product (a) with at least one compound having the formulaR.sup.2.sub.n M.sup.(z) X.sub.z-n(R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1 . . . (z-1) in the presence of an aromatic hydrocarbon solvent at lower than 85.degree. C.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: January 3, 1984
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kazumi Tsubaki, Noriaki Koto, Toyohiko Abe
  • Patent number: 4398006
    Abstract: Butene-1 is polymerized in the presence of a catalytic system comprising a solid catalytic component (A), a trialkylaluminum compound (B), an organic acid ester (C), and an organoaluminum compound (D) at a molar ratio of (D) to (B) ranging 0.1 to 10 wherein said solid catalytic component (A) is obtained by reacting a reaction product (a) of a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3) with at least one compound having the formulaR.sub.n.sup.2 M(.sup.(z) X.sub.z-n(R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1-(z-1) to obtain a reaction product (b) and further reacting said reaction product (b) with at least one titanium halide in the presence of an organic acid ester.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: August 9, 1983
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Kazumi Tsubaki, Noriaki Koto, Toyohiko Abe
  • Patent number: 4357448
    Abstract: Ethylene or a mixture of ethylene and a small amount of another .alpha.-olefin or diene is polymerized in two successive steps under different hydrogen partial pressures by polymerizing 30 to 70 wt. % of the ethylene or ethylene mixture to be polymerized in the presence of hydrogen at a molar ratio of ethylene or ethylene mixture to hydrogen of 1:1-8 in the first step and polymerizing the residual ethylene or the ethylene mixture at a molar ratio of ethylene to hydrogen of 1:0-0.3 in the second step, in the presence of the specific catalyst system comprising an organoaluminum compound (C) and a specific solid catalytic component (B) obtained by reacting a titanium or vanadium halogen-containing compound with a reaction product (A) obtained by reacting a Grignard reagent with a hydropoly-siloxane having the formula ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy, or aryloxy group as a monovalent organic group; a is 0,1 or 2; b is 1, 2 or 3; and a+b.ltoreq.
    Type: Grant
    Filed: May 20, 1980
    Date of Patent: November 2, 1982
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Kazumi Tsubaki, Hiroshi Morinaga, Yoshiho Matsuo, Takeshi Iwabuchi
  • Patent number: 4258167
    Abstract: A powdery isotactic polyolefin having high isotactic characteristic and high bulk density and a narrow size distribution is produced by forming a polymerization catalyst system by reacting a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3) to form a reaction product (a); reacting the reaction product (a) with at least one compound having the formulaR.sup.2.sub.n M.sup.(z) X.sub.z-n(R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1 . . . (z-1)) in the presence of an aromatic hydrocarbon solvent at lower than 85.degree. C.
    Type: Grant
    Filed: January 25, 1979
    Date of Patent: March 24, 1981
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Kazumi Tsubaki, Noriaki Koto, Kouichi Maeda
  • Patent number: 4229552
    Abstract: A fire-retardant polyester composition comprising a fiber-forming linear polyester having an intrinsic viscosity of at least 0.1 and a fire retardant containing phosphorus and bromine, wherein at least 70 mole % of the polyester consists of a recurring unit of the formula ##STR1## wherein n represents an integer of 2 to 6, and the fire retardant is a copolyphosphonate composed of 1 mole of a recurring unit of the formula ##STR2## wherein Y represents an isopropylidene or sulfonyl group, and R represents a phenyl or benzyl group,and 0.25 to 10 moles of a recurring unit of the formula ##STR3## wherein R represents a phenyl or benzyl group, the proportion of the fire retardant being 1 to 20 parts by weight per 100 parts by weight of the polyester.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: October 21, 1980
    Assignees: Teijin Limited, Nissan Chemical Industries Ltd.
    Inventors: Masahiro Shiozaki, Kiyoshi Nawata, Kiyokazu Tsunawaki, Kazumi Tsubaki, Akira Yanagimoto, Shunichi Kumazawa
  • Patent number: 4223118
    Abstract: A polyethylene is produced by polymerizing ethylene with or without a comonomer in the presence of a catalyst consisting of an organometallic compound and a solid catalytic component (B) obtained by reacting a titanium or vanadium halide with a reaction product (A) in the presence of one or more aluminum alkoxide having the formulaAl(OR.sup.2).sub.n X.sub.3-nwherein R.sup.2 represents a C.sub.1 -C.sub.12 alkyl group and X represents a halogen atom and 0<n.ltoreq.3, or a reaction product of said aluminum alkoxide and water. The reaction product (A) is obtained by reacting a Grignard reagent with an organosilicon compound selected from the group consisting of hydropolysiloxanes having the structural units ofR.sup.1.sub.a H.sub.b SiO.sub.(4-a-b/2) (I)wherein R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3; and a+b.ltoreq.3, and organosilicon compounds having the formulaR.sup.3.sub.n Si(OH).sub.4-n (II)wherein R.sup.3 represents a C.sub.1 -C.sub.
    Type: Grant
    Filed: September 12, 1978
    Date of Patent: September 16, 1980
    Assignee: Nissan Chemical Industries, Limited
    Inventors: Kazumi Tsubaki, Hiroshi Morinaga, Takeshi Iwabuchi, Masao Kawahara