Abstract: An electrochemical gas sensor having an electrode with a catalyst distributed on a porous surface is described. The porous surface can be a polytetrafluoroethylene tape. Alternate embodiments include layered or stacked electrodes.

Abstract: Systems and methods of fast power up for electrochemical sensors are provided. A system can include an electrochemical sensor, and a potentiostat circuit, wherein, upon startup, the potentiostat circuit drives the electrochemical sensor to the electrochemical sensor's normal operating condition at a rate that is not limited by voltage and/or current supply. A method can include a potentiostat circuit driving an electrochemical sensor to the electrochemical sensor's normal operating condition at a rate that is not limited by voltage and/or current supply.

Abstract: A method of operating an electrochemical gas sensor includes: a) exposing, for a first predetermined duration, the electrochemical gas sensor to an atmosphere containing a target gas while the gas reaction capability of the electrode assembly is substantially reduced from a working level, such that target gas is collected within the housing; b) increasing the gas reaction capability of the electrode assembly to a level at which it consumes collected target gas and thereby outputs a signal to the sensing circuit, including an initial transient decay signal; c) monitoring the transient decay signal; and d) analysing the rate of decay of the transient decay signal to determine whether the performance of at least one component of the electrochemical gas sensor is within acceptable limits. An apparatus for operating an electrochemical gas sensor, adapted for connection to an electrochemical gas sensor via a sensing circuit for control thereof, can carry out the disclosed method(s).

Abstract: A docking station for use with gas sensors includes limited test and diagnostic circuitry directed to specific characteristics of selected detectors. Where a family of detectors is to be evaluated, a universal interface for that family can be included. A single port can be used for multiple different detectors irrespective of specific detector characteristics.

Abstract: An electrochemical gas detector includes a superhydrophobic, nanostructured gas porous electrode. The electrode exhibits a physically disrupted porous region. In an embodiment, electrode material can be deposited around a templating material which is removed before use. Such electrodes exhibit repeatable and reproducible characteristics.

Abstract: A method of improving performance of electrochemical gas sensors includes cycling potentials applied to one or more of the electrodes of the respective sensor(s) to improve performance of a different electrode. In a process for treating a reference electrode, potentials can be applied to working and, or counter electrodes so as to modify the environment in the vicinity of the reference electrode. An apparatus can carry out the method automatically.

Abstract: A method of operating an electrochemical gas sensor includes: a) exposing, for a first predetermined duration, the electrochemical gas sensor to an atmosphere containing a target gas whilst the gas reaction capability of the electrode assembly is substantially reduced from a working level, such that target gas is collected within the housing; b) increasing the gas reaction capability of the electrode assembly to a level at which it consumes collected target gas and thereby outputs a signal to the sensing circuit, including an initial transient decay signal; c) monitoring the transient decay signal; and d) analysing the rate of decay of the transient decay signal to determine whether the performance of at least one component of the electrochemical gas sensor is within acceptable limits. An apparatus for operating an electrochemical gas sensor, adapted for connection to an electrochemical gas sensor via a sensing circuit for control thereof, can carry out the disclosed method(s).

Abstract: A liquid electrolyte composition obtainable by combining a first component comprising bistrifluoromethanesulfonimide and/or an analogue thereof with a second component comprising a dialkyl sulfone, diaryl sulfone, alkyl aryl sulfone, alkyl acyl sulfone, boric acid, alkyl boronic acid, aryl boronic acid, dialkyl phosphite, trialkyl phosphite, dialkyl phosphate, trialkyl phosphate, alkylene carbonate, alkanoic lactone, preferably alkanoic ?-lactone an analogue of any of these, or mixtures thereof, wherein any of the alkyl, aryl of alkenyl groups may be substituted or unsubstituted. The liquid electrolyte is used in an electrochemical gas sensor.

Abstract: A docking station for use with gas sensors includes limited test and diagnostic circuitry directed to specific characteristics of selected detectors. Where a family of detectors is to be evaluated, a universal interface for that family can be included. A single port can be used for multiple different detectors irrespective of specific detector characteristics.

Abstract: A sensor system having an analyte modulator, detector and a pump. The concentration of an analyte sample may be modulated at one time constant. The detector may have an output with a drift at another time constant. The one time constant may be shorter than the latter time constant. The latter time constant may be substantially removed from the detector output with a discriminator. A reservoir may receive high concentrations of analyte from the modulator, before analyte is forwarded to the detector and pump via analyte conveyance lines and valving. The modulation or pre-concentration of analyte in the sensor system may entail shorter times and smaller volumes than those needed by the detector. Such mismatches may be alleviated via accumulation of analyte in the reservoir prior to being forwarded to the detector.

Abstract: An electrochemical gas detector includes a superhydrophobic, nanostructured gas porous electrode. The electrode exhibits a physically disrupted porous region. In an embodiment, electrode material can be deposited around a templating material which is removed before use. Such electrodes exhibit repeatable and reproducible characteristics.

Abstract: A sensor system having an analyte modulator, detector and a pump. The concentration of an analyte sample may be modulated at one time constant. The detector may have an output with a drift at another time constant. The one time constant may be shorter than the latter time constant. The latter time constant may be substantially removed from the detector output with a discriminator. A reservoir may receive high concentrations of analyte from the modulator, before analyte is forwarded to the detector and pump via analyte conveyance lines and valving. The modulation or pre-concentration of analyte in the sensor system may entail shorter times and smaller volumes than those needed by the detector. Such mismatches may be alleviated via accumulation of analyte in the reservoir prior to being forwarded to the detector.

Abstract: A method of detecting a predetermined alarm condition in a combustion emission gas. The method comprises exposing to the gas a semiconductor gas sensor having a p-type mixed metal oxide semiconducting material of the first, second and/or third order transition metal series, the semiconducting material being responsive both to a change in concentration of a reducing gas in the surrounding atmosphere and to a change in concentration of oxygen in the surrounding atmosphere to exhibit a change in its electrical resistance. The resistance is monitored and an alarm signal is output if the resistance exceeds a predetermined value corresponding to the alarm condition.

Abstract: Semiconductor gas-sensitive materials of the formula Cr2-xTixO3 where 0.05>x?0.0001, and gas sensors formed therefrom.

Abstract: Semiconductor gas-sensitive materials of the formula Cr2−xTixO3 where 0.05>x≧0.0001, and gas sensors formed therefrom.