Abstract: Kelvin (4-wire) connecting cables are routinely used when performing dynamic measurements (i.e., measurements with time-varying signals) on electrochemical cells and batteries. Current-carrying and voltage-sensing conductor pairs within such cables comprise distributed-parameter two-wire transmission lines which may extend several meters in length. As with all such transmission lines, internally reflected waves can oscillate back and forth at high frequency (hf) whenever the lines are not terminated in their characteristic impedances. Such hf reflected waves, by interacting with measuring circuitry, can seriously degrade low-frequency measurement accuracy. Apparatus is disclosed herein that suppresses hf reflected waves oscillating on Kelvin connecting cables during dynamic measurements of cells and batteries.

Abstract: A testing device contains measuring circuitry adapted to apply time-varying electrical excitation to a cell or battery, to sense a time-varying electrical response, and to thus determine components of complex immittance at n+m discrete frequencies, where n is an integer equal to or greater than two and m is an integer equal to or greater than one. Computation circuitry utilizes measured complex immittance components at the n discrete frequencies to evaluate the elements of a 2n-element equivalent circuit model. It then calculates the complex immittance of this model at the m discrete frequencies and mathematically compares components of the calculated immittances with components of the measured immittances at the m discrete frequencies. The results of this comparison establish the degree of cell deterioration without regard to the battery's manufacturer, group size, or its electrical ratings.

Abstract: Kelvin (4-wire) connecting cables are routinely used when performing dynamic measurements (i.e., measurements with time-varying signals) on electrochemical cells and batteries. Current-carrying and voltage-sensing conductor pairs within such cables comprise distributed-parameter two-wire transmission lines which may extend several meters in length. As with all such transmission lines, internally reflected waves can oscillate back and forth at high frequency (hf) whenever the lines are not terminated in their characteristic impedances. Such hf reflected waves, by interacting with measuring circuitry, can seriously degrade low-frequency measurement accuracy. Apparatus is disclosed herein that suppresses hf reflected waves oscillating on Kelvin connecting cables during dynamic measurements of cells and batteries.

Abstract: A testing device detects and quantifies cell deterioration of an electrochemical cell or battery. The device contains measuring circuitry adapted to apply time-varying electrical excitation to said cell or battery, to sense time-varying electrical response to said excitation, and to utilize said excitation and response to determine components of complex immittance (i.e., either impedance or admittance) at n+m discrete frequencies, where n is an integer equal to or greater than two and m is an integer equal to or greater than one. Computation circuitry utilizes measured complex immittance components at the n discrete frequencies to evaluate the elements of a 2n-element equivalent circuit model. It then calculates the complex immittance of this model at the m discrete frequencies and mathematically compares components of the calculated immittances with components of the measured immittances at the m discrete frequencies. The results of this comparison are related to the degree of cell deterioration.

Abstract: A broad-band technique for reducing the distributed inductance of a four-conductor Kelvin cable is disclosed. A special inductance-canceling cable section is connected in tandem with the cable section contacting the cell/battery. Connections between the two cable sections are transposed such that conductors in each conductor pair of the canceling section connect to current-carrying and voltage-sensing conductors from different conductor pairs in the contacting section. The canceling section thereby exhibits a distributed negative mutual inductance between its current-carrying and voltage-sensing conductors that can effectively cancel the distributed positive mutual inductance introduced by the contacting section. In one embodiment, conductor pairs comprise pairs of insulated wires which may be twisted together. In other disclosed embodiments, conductor pairs comprise shielded coaxial cables.

Abstract: A broad-band technique for reducing the distributed inductance of a four-conductor Kelvin cable is disclosed. A special inductance-canceling cable section is connected in tandem with the cable section contacting the cell/battery. Connections between the two cable sections are transposed such that conductors in each conductor pair of the canceling section connect to current-carrying and voltage-sensing conductors from different conductor pairs in the contacting section. The canceling section thereby exhibits a distributed negative mutual inductance between its current-carrying and voltage-sensing conductors that can effectively cancel the distributed positive mutual inductance introduced by the contacting section. In one embodiment, conductor pairs comprise pairs of insulated wires which may be twisted together. In other disclosed embodiments, conductor pairs comprise shielded coaxial cables.

Abstract: A “three-point” measurement technique effectively removes system effects to determine impedance, admittance, resistance, or conductance of an individual cell, battery, or interconnecting conductor embedded in a series or series-parallel electrochemical battery or fuel cell system. Three electrical contact points are defined. Two of these points bound the subject element. The third point is separated from the other two by a conducting path that may include one or more cells or batteries. By measuring dynamic parameters between alternate pairs of contact points, three dynamic parameter measurements are acquired. A mathematical computation combines the measurements and determines the dynamic parameter of a subject element as if it were alone—thus effectively “de-embedding” the subject element from the remainder of the system. A “four-point” extension of this technique permits measuring a dynamic parameter of a cell/battery disposed in a multiple-unit string of parallel-connected cells/batteries.

Abstract: Testing apparatus senses the time-varying electrical response of an electrochemical cell/battery to time-varying electrical excitation. The cell/battery may, or may not, be in service. Computation circuitry responsive to the time-varying electrical response evaluates elements of a unique circuit model representation of the cell/battery. Performance parameters and physical parameters are computed from these element values. Computed performance parameters include, but are not limited to, “total storage capacity”, “absolute stored charge”, “state-of-charge”, “absolute cranking current”, “fully charged cranking current”, and “state-of-health”.

Abstract: An exciter of periodic square-wave current for measurement of complex ac impedance or admittance is described. A microcontroller/processor outputs two digital words that define upper and lower current levels. These words are latched and converted to analog voltages by D/A converter circuitry. A timing signal at the measurement frequency, also outputted by the microprocessor/controller, controls a multiplexer arranged to select either analog voltage. The multiplexer output thus toggles between the two programmed analog voltages at the measurement frequency. By virtue of negative feedback, the toggled multiplexer output voltage equals the voltage developed across a resistance in series with the cell/battery.

Abstract: An exciter of periodic square-wave current for measurement of complex ac impedance or admittance is described. A microcontroller/processor outputs two digital words that define upper and lower current levels. These words are latched and converted to analog voltages by D/A converter circuitry. A timing signal at the measurement frequency, also outputted by the microprocessor/controller, controls a multiplexer arranged to select either analog voltage. The multiplexer output thus toggles between the two programmed analog voltages at the measurement frequency.

Abstract: A testing device applies time-varying electrical excitation to a cell or battery and senses the resulting time-varying electrical response. Computation circuitry within the device uses voltage and current signals derived from the excitation and response signals as inputs and computes values of elements of an equivalent circuit representation of the cell or battery. The relative charge (SOC) of the cell or battery is calculated from the value of the conductance component G of a particular parallel G-C subcircuit of the equivalent circuit. The absolute charge (Ah) contained in the cell or battery is calculated from the value of the capacitance component C of a different parallel G-C subcircuit. Relative or absolute charge values are then either displayed to the user or are used to control an external process such as charging of the battery.

Abstract: A “three-point” measurement technique effectively removes system effects to determine impedance, admittance, resistance, or conductance of an individual cell, battery, or interconnecting conductor embedded in a series or series-parallel electrochemical battery or fuel cell system. Three electrical contact points are defined. Two of these points bound the subject element. The third point is separated from the other two by a conducting path that may include one or more cells or batteries. By measuring dynamic parameters between alternate pairs of contact points, three dynamic parameter measurements are acquired. A mathematical computation combines the measurements and determines the dynamic parameter of a subject element as if it were alone—thus effectively “de-embedding” the subject element from the remainder of the system.

Abstract: An exciter of periodic square-wave current for measurement of complex ac impedance or admittance is described. A microcontroller/processor outputs two digital words that define upper and lower current levels. These words are latched and converted to analog voltages by D/A converter circuitry. A timing signal at the measurement frequency, also outputted by the microprocessor/controller, controls a multiplexer arranged to select either analog voltage. The multiplexer output thus toggles between the two programmed analog voltages at the measurement frequency. By virtue of negative feedback, the toggled multiplexer output voltage equals the voltage developed across a resistance in series with the cell/battery.

Abstract: Testing apparatus senses the time-varying electrical response of an electrochemical cell/battery to time-varying electrical excitation. The cell/battery may, or may not, be in service. Computation circuitry responsive to the time-varying electrical response evaluates elements of a unique circuit model representation of the cell/battery. Performance parameters and physical parameters are computed from these element values. Computed performance parameters include, but are not limited to, “total storage capacity”, “absolute stored charge”, “state-of-charge”, “absolute cranking current”, “fully charged cranking current”, and “state-of-health”.

Abstract: The disclosed invention relates to measuring an ac dynamic parameter (e.g., impedance, admittance, resistance, reactance, conductance, susceptance) of an electrochemical cell/battery or other electrical element under conditions of possible interference from potential sources such as ac magnetic fields and/or ac currents at the powerline frequency and its harmonics. More generally, it relates to evaluating a signal component at a known frequency f1 under conditions of possible hum, noise, or other spurious interference at one or more other known frequencies. A microprocessor or microcontroller commands A/D circuitry to sample a band-limited signal at M evenly spaced times per period 1/f1 distributed over an integer number N of such periods and calculates time-averaged Fourier coefficients from these samples. The frequency response of the calculated Fourier coefficients displays perfect nulls at evenly spaced frequencies either side of frequency f1.

Abstract: A testing device applies time-varying electrical excitation to a cell or battery and senses the resulting time-varying electrical response. Computation circuitry within the device uses voltage and current signals derived from the excitation and response signals as inputs and computes values of elements of an equivalent circuit representation of the cell or battery. The relative charge SOC) of the cell or battery is calculated from the value of the conductance component G of a particular parallel G-C subcircuit of the equivalent circuit. The absolute charge (Ah) contained in the cell or battery is calculated from the value of the capacitance component C of a different parallel G-C subcircuit. Relative or absolute charge values are then either displayed to the user or are used to control an external process such as charging of the battery.

Abstract: A “three-point” measurement technique precisely determines dynamic electrical parameters of individual cells/batteries and/or interconnecting conductors embedded in a larger series, parallel, or series-parallel battery/electrical system. Three measuring points are defined. Two of these points comprise terminals of the subject cell/battery or interconnecting conductor. The third measuring point is an adjacent point that is separated from one of the other two measuring points by a single conducting path that may include one or more cells or batteries. By measuring dynamic parameters between alternate pairs of these three measuring points, three dynamic parameter measurements are acquired. A mathematical computation combines the three measurements and uniquely determines the desired dynamic parameters of one or two subject elements—thus effectively “de-embedding” the subject elements from the remainder of the system.

Abstract: A testing device applies time-varying electrical excitation to a cell or battery and senses the resulting time-varying electrical response. Computation circuitry within the device uses voltage and current signals derived from the excitation and response signals as inputs and computes values of elements of an equivalent circuit representation of the cell or battery. The relative charge SOC) of the cell or battery is calculated from the value of the conductance component G of a particular parallel G-C subcircuit of the equivalent circuit. The absolute charge (Ah) contained in the cell or battery is calculated from the value of the capacitance component C of a different parallel G-C subcircuit. Relative or absolute charge values are then either displayed to the user or are used to control an external process such as charging of the battery.

Abstract: A testing device applies time-varying electrical excitation to a cell or battery and senses the resulting time-varying electrical response. Computation circuitry within the device uses voltage and current signals derived from the excitation and response signals as inputs and computes values of elements of an equivalent circuit representation of the cell or battery. The internal temperature of the cell or battery is calculated from the value of the time constant of a particular parallel G-C subcircuit of the equivalent circuit. The battery's internal temperature is then either displayed to the user, used to apply appropriate temperature corrections to other computed quantities, used to detect thermal runaway, and/or used to control an external process such as charging of the battery.

Abstract: A device measures complex self-immittance of a general element at a discrete frequency by implementing “sine/cosine correlation” in software. An active source excites the element with a periodic voltage or current having fundamental period equal to the reciprocal of the desired measurement frequency. Linear circuitry senses two signals; one proportional to the periodic voltage or current excitation, the other proportional to the periodic current or voltage response. Identical low-pass or band-pass filter-response functions process each signal to remove higher-order harmonics. The resulting band-limited signals are each sampled in synchronism with the excitation, digitized, and inputted to a microprocessor or microcontroller which performs the appropriate calculations.