Patents by Inventor Kenichi Kawase

Kenichi Kawase has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160072126
    Abstract: A battery capable of improving cycle characteristics is provided. An anode includes: an anode current collector, and an anode active material layer arranged on the anode current collector, in which the anode active material layer includes an anode active material including silicon (Si), and including a pore group with a diameter ranging from 3 nm to 50 nm both inclusive, and the volumetric capacity per unit weight of silicon of the pore group with a diameter ranging from 3 nm to 50 nm both inclusive is 0.2 cm3/g or less, the volumetric capacity being measured by mercury porosimetry using a mercury porosimeter.
    Type: Application
    Filed: November 17, 2015
    Publication date: March 10, 2016
    Inventors: Takakazu Hirose, Kenichi Kawase, Isamu Konishiike, Shunsuke Kurasawa, Masayuki Iwama, Koichi Matsumoto
  • Patent number: 9266444
    Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.
    Type: Grant
    Filed: December 22, 2011
    Date of Patent: February 23, 2016
    Assignee: SONY CORPORATION
    Inventors: Akira Takamuku, Kazuaki Endoh, Masaharu Senoue, Guohua Li, Yosuke Hosoya, Kenichi Kawase
  • Patent number: 9246160
    Abstract: An anode, an anode current collector, an anode active material and a battery using the anode are provided. The anode includes the anode current collector and the anode active material. The anode current collector has a projection. The anode active material layer is formed via at least one of a vapor deposition method, a liquid-phase deposition method, a sintering method and the like.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: January 26, 2016
    Assignee: Sony Corporation
    Inventors: Kenichi Kawase, Tomoo Takada, Yukio Miyaki
  • Patent number: 9225014
    Abstract: A battery is provided including a positive electrode; a negative electrode including a first negative electrode active material; and an electrolytic solution, wherein the first negative electrode active material includes a core portion having a core portion surface, wherein the core portion has a median diameter of 0.3 ?m to 20 ?m, and a covering portion that covers at least part of the core portion surface, wherein the covering portion comprises at least Si, O and at least of one element M1 selected from Li, carbon (C), Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K.
    Type: Grant
    Filed: June 1, 2015
    Date of Patent: December 29, 2015
    Assignee: Sony Corporation
    Inventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Isao Koizumi, Toshio Nishi
  • Patent number: 9214667
    Abstract: A lithium-ion secondary battery allowed to improve cycle characteristics and initial charge-discharge characteristics is provided. The lithium-ion secondary battery includes: a cathode; an anode including an anode active material layer; and an electrolytic solution. The anode active material layer includes an anode active material and an inorganic compound, and the inorganic compound includes one or both of an alkoxysilane compound and a hydrolysate thereof.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: December 15, 2015
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Motoki Endo, Kenichi Kawase
  • Publication number: 20150349340
    Abstract: An anode capable of preventing expansion of an anode active material layer and a battery using it are provided. The anode includes an anode current collector, and an anode active material layer containing silicon (Si) as an element, wherein the anode active material layer therein contains at least one selected from the group consisting of a fluoride of an alkali metal and a fluoride of an alkali earth metal.
    Type: Application
    Filed: August 14, 2015
    Publication date: December 3, 2015
    Inventors: Takakazu Hirose, Kenichi Kawase, Isamu Konishiike, Masayuki Iwama
  • Patent number: 9203079
    Abstract: An anode for a secondary battery capable of improving cycle characteristics, a secondary battery using the anode, and a method of manufacturing an anode for secondary battery. An anode active material layer is formed by vapor phase deposition method, and contains Si as an element. In the anode active material layer, there are a plurality of primary particles grown in the thickness direction. The primary particles aggregate and form a plurality of secondary particles. At least some of the primary particles have shape curved in the identical direction to an anode current collector on the cross section in the thickness direction. Thereby, stress due to expansion and shrinkage due to charge and discharge can be relaxed.
    Type: Grant
    Filed: February 10, 2014
    Date of Patent: December 1, 2015
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Isamu Konishiike, Kenichi Kawase
  • Patent number: 9166221
    Abstract: An anode in which an anode active material layer is arranged on an anode current collector. The anode active material layer includes anode active material particles made of an anode active material including at least one of silicon and tin as an element. An oxide-containing film including an oxide of at least one kind selected from the group consisting of silicon, germanium and tin is formed in a region in contact with an electrolytic solution of the surface of each anode active material particle by a liquid-phase method such as a liquid-phase deposition method. The region in contact with the electrolytic solution of the surface of each anode active material particle is covered with the oxide-containing film, to thereby improve the chemical stability of the anode and the charge-discharge efficiency. The thickness of the oxide-containing film is preferably within a range from 0.1 nm to 500 nm both inclusive.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: October 20, 2015
    Assignee: SONY CORPORATION
    Inventors: Hiroyuki Yamaguchi, Hiroshi Horiuchi, Kenichi Kawase, Tadahiko Kubota, Hideki Nakai, Takakazu Hirose
  • Publication number: 20150263344
    Abstract: A battery is provided including a positive electrode; a negative electrode including a first negative electrode active material; and an electrolytic solution, wherein the first negative electrode active material includes a core portion having a core portion surface, wherein the core portion has a median diameter of 0.3 ?m to 20 ?m, and a covering portion that covers at least part of the core portion surface, wherein the covering portion comprises at least Si, O and at least of one element M1 selected from Li, carbon (C), Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K.
    Type: Application
    Filed: June 1, 2015
    Publication date: September 17, 2015
    Inventors: Takakazu HIROSE, Kenichi KAWASE, Takashi FUJINAGA, Isao KOIZUMI, Toshio NISHI
  • Publication number: 20150243977
    Abstract: A secondary battery includes: a cathode; an anode including an active material; and an electrolytic solution, wherein the active material includes a central section and a covering section provided on a surface of the central section, the central section includes silicon (Si) as a constituent element, the covering section includes carbon (C) and hydrogen (H) as constituent elements, and one or more of positive ions represented by CxHy (x and y satisfy 2?x?6 and 3?x?9) are detected by positive ion analysis of the covering section with the use of time-of-flight secondary ion mass spectrometry.
    Type: Application
    Filed: February 27, 2014
    Publication date: August 27, 2015
    Applicant: Sony Corporation
    Inventors: Takakazu HIROSE, Kenichi KAWASE, Toshio NISHI, Isao KOIZUMI
  • Patent number: 9112238
    Abstract: An anode capable of preventing expansion of an anode active material layer and a battery using it are provided. The anode includes an anode current collector, and an anode active material layer containing silicon (Si) as an element, wherein the anode active material layer therein contains at least one selected from the group consisting of a fluoride of an alkali metal and a fluoride of an alkali earth metal.
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: August 18, 2015
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Isamu Konishiike, Masayuki Iwama
  • Patent number: 9083054
    Abstract: A lithium ion secondary battery is provided with a positive electrode, a negative electrode containing an active material, and an electrolytic solution, wherein the active material includes a core portion capable of occluding and releasing lithium ions, an amorphous or low-crystalline coating portion disposed on at least a part of the surface of the core portion, and a fibrous carbon portion disposed on at least a part of the surface of the coating portion, and the coating portion contains Si and O as constituent elements, while the atomic ratio y (O/Si) of O relative to Si satisfies 0.5?y?1.8.
    Type: Grant
    Filed: June 19, 2012
    Date of Patent: July 14, 2015
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Takashi Fujinaga, Isao Koizumi, Norihiro Shimoi, Kenichi Kawase
  • Patent number: 9077036
    Abstract: A lithium ion secondary battery including a positive electrode; a negative electrode; and an electrolytic solution, wherein the positive electrode includes a first lithium composite oxide and a second lithium composite oxide expressed by following formula (1) as a positive electrode active material, and wherein the second lithium composite oxide has a charge capacity greater than the first lithium composite oxide Li1+a(NibM1cM21?b?c)1.5?0.5aO2??(1) wherein, M1 represents at least one selected from among elements of group 13 to group 15 in an extended periodic table of elements excluding boron B, or carbon C, or nitrogen N, M2 represents at least one selected from among elements of group 3 to group 12, and a, b, and c satisfy relationships of 0.95?a?1.05, 0<b?0.99, and 0<c?0.15.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: July 7, 2015
    Assignee: SONY CORPORATION
    Inventors: Masaharu Senoue, Kenichi Kawase, Takakazu Hirose, Masayuki Ihara
  • Patent number: 9059452
    Abstract: There is provided an anode for a lithium ion secondary battery capable of improving the cycle characteristics, a lithium ion secondary battery using the same, an electric power tool using the lithium ion secondary battery, an electrical vehicle using the lithium ion secondary battery, and an electric power storage system using the lithium ion secondary battery. The anode for a lithium ion secondary battery includes an anode active material layer in which a first layer and a second layer respectively containing silicon and a metal element as an anode active material are alternately layered on an anode current collector, and 1.02?A/B?50 is satisfied. A represents a silicon content ratio in the anode active material in the first layer, and B represents a silicon content ratio in the anode active material in the second layer.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: June 16, 2015
    Assignee: SONY CORPORATION
    Inventors: Shunsuke Kurasawa, Takashi Fujinaga, Momoe Adachi, Kenichi Kawase
  • Patent number: 9048485
    Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5?y?1.8.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: June 2, 2015
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Isao Koizumi, Toshio Nishi
  • Patent number: 9048504
    Abstract: A secondary battery electrode includes an active material layer configured to be provided on a current collector and be obtained by stacking a plurality of active material sub-layers composed of an active material. Pores of which pore diameter along a thickness direction of the active material layer is 3 to 300 nm are formed along a boundary between the active material sub-layers, and at least a part of the pores is filled with an electrolyte and/or a product arising from reduction of the electrolyte upon assembling of a secondary battery.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: June 2, 2015
    Assignee: SONY CORPORATION
    Inventors: Momoe Adachi, Isamu Konishiike, Kenichi Kawase
  • Patent number: 9012066
    Abstract: A secondary battery capable of improving the cycle characteristics and the swollenness characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode includes an anode active material layer having a plurality of fine pores on an anode current collector. The anode active material layer contains an anode active material and an anode binder. A change rate of a mercury intrusion into the plurality of fine pores measured by mercury penetration technique is distributed to show a peak in the pore diameter range from 30 nm to 10000 nm, both inclusive.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: April 21, 2015
    Assignee: Sony Corporation
    Inventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii
  • Patent number: 8999583
    Abstract: A lithium-ion secondary battery allowed to improve cycle characteristics and initial charge-discharge characteristics is provided. The lithium-ion secondary battery includes a cathode; an anode; and an electrolytic solution. The anode includes an anode active material layer including a plurality of anode active material particles. The anode active material particles each include a core section and a coating section applied to a part or a whole of a surface of the core section, and the core section includes a silicon-based material (SiOx: 0?x<0.5) and the coating section includes an amorphous or low-crystalline silicon-based material (SiOy: 0.5?y?1.8).
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: April 7, 2015
    Assignee: Sony Corporation
    Inventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Masaharu Senoue, Motoki Endo, Masayuki Iwama
  • Publication number: 20150093642
    Abstract: Anode active materials, anodes, and batteries are provided. In one embodiment, an anode active material includes particles consisting essentially of a material selected from the group consisting of silicon and an alloy of silicon. An average degree of circularity of the particles is 90% or less.
    Type: Application
    Filed: December 11, 2014
    Publication date: April 2, 2015
    Inventors: Kenichi Kawase, Tomoo Takada, Kensuke Yamamoto
  • Publication number: 20150086879
    Abstract: An anode in which an anode active material layer is arranged on an anode current collector. The anode active material layer includes anode active material particles made of an anode active material including at least one of silicon and tin as an element. An oxide-containing film including an oxide of at least one kind selected from the group consisting of silicon, germanium and tin is formed in a region in contact with an electrolytic solution of the surface of each anode active material particle by a liquid-phase method such as a liquid-phase deposition method. The region in contact with the electrolytic solution of the surface of each anode active material particle is covered with the oxide-containing film, to thereby improve the chemical stability of the anode and the charge-discharge efficiency. The thickness of the oxide-containing film is preferably within a range from 0.1 nm to 500 nm both inclusive.
    Type: Application
    Filed: December 2, 2014
    Publication date: March 26, 2015
    Inventors: Hiroyuki Yamaguchi, Hiroshi Horiuchi, Kenichi Kawase, Tadahiko Kubota, Hideki Nakai, Takakazu Hirose