Abstract: A process for the purification and isolation of a chemical compound, by extractive solution crystallization. The process comprises combining in any order a first solvent, a second solvent, and a mixture comprising a chemical compound with at least one impurity. The second solvent phase extracts impurities out of the first solvent, and keeps the impurities dissolved to avoid their co-crystallization with the phenyl ester salt. Once the chemical compound has crystallized out of solution, it is collected, washed and/or dried. The second solvent may be added after the mixture containing at least one chemical compound is dissolved in a first solvent, as long as the second solvent phase is added prior to the end of crystallization. Advantageously, this invention combines the previously distinct steps of extraction and crystallization in one unit operation.

Abstract: The invention relates to a process for isolating a phenyl ester salt from a mixture comprising sulfolane (tetrahydrothiophene-1,1-dioxide). The invention includes adjusting the temperature of a mixture comprising a phenyl ester salt and sulfolane to a temperature of about 100-150° C. This step leads to the formation of a mixture comprising a solid phenyl ester salt and sulfolane. Next, the solid phenyl ester salt is separated, while maintaining the temperature of the mixture at about 100-150° C. The invention also relates to a process that includes adding a sufficient amount of a solvent to a mixture comprising a phenyl ester salt and sulfolane to decrease the viscosity or the density of the mixture. The solvent added has a density less than about 1.20 g/cm3 at 100° C. or a viscosity of less than about 2.56 centipoise at 100° C. The embodiments of the invention may be used alone or in combination.

Abstract: The invention relates to a process for isolating a phenyl ester salt from a mixture comprising sulfolane (tetrahydrothiophene-1,1-dioxide). The invention includes adjusting the temperature of a mixture comprising a phenyl ester salt and sulfolane to a temperature of about 100-150° C. This step leads to the formation of a mixture comprising a solid phenyl ester salt and sulfolane. Next, the solid phenyl ester salt is separated, while maintaining the temperature of the mixture at about 100-150° C. The invention also relates to a process that includes adding a sufficient amount of a solvent to a mixture comprising a phenyl ester salt and sulfolane to decrease the viscosity or the density of the mixture. The solvent added has a density less than about 1.20 g/cm3 at 100° C. or a viscosity of less than about 2.56 centipoise at 100° C. The embodiments of the invention may be used alone or in combination.

Abstract: A process for the purification and isolation of a chemical compound, by extractive solution crystallization. The process comprises combining in any order a first solvent, a second solvent, and a mixture comprising a chemical compound with at least one impurity. The second solvent phase extracts impurities out of the first solvent, and keeps the impurities dissolved to avoid their co-crystallization with the phenyl ester salt. Once the chemical compound has crystallized out of solution, it is collected, washed and/or dried. The second solvent may be added after the mixture containing at least one chemical compound is dissolved in a first solvent, as long as the second solvent phase is added prior to the end of crystallization. Advantageously, this invention combines the previously distinct steps of extraction and crystallization in one unit operation.

Abstract: An essentially stable monomer miniemulsion characterized by small monomer droplet size is prepared and is then polymerized to a polymer latex under free radical polymerization conditions. The monomer miniemulsions herein include, in addition to water, a surfactant, and a monomer or mixture thereof, one or more polymers which function as a polymeric co-surfactant. The monomer miniemulsions are characterized by average monomer droplet size of 10 to 500 nanometers, preferably 80 to 150 nanometers. The amount of polymer added as a co-surfactant is about 0.5 to about 5 percent by weight based on monomer weight. The monomer emulsion may contain either a single monomer or a monomer mixture. The monomer emulsion is polymerized under conventional emulsion polymerization conditions yielding a polymer latex having an average polymer particle size of 10 to 500 nanometers, preferably 80 to 150 nanometers, and a narrow particle size distribution, i.e., a polydispersity index of about 1.05 to about 1.40.

Abstract: An in-use rolling element bearing monitoring system which uses a piezoelectric film transducer on either a bearing, bearing support structure, or on a separate washer in close proximity to a bearing for monitoring bearing performance. One embodiment provides a bearing monitoring system for detecting and predicting bearing failure. Another embodiment provides a system configured for detecting rotational speed of a rolling element bearing. Each embodiment of the invention entails maintaining a piezoelectric film transducer in contiguous pressure wave responsive communication with a bearing for detecting bearing performance, and provides the system in a compact configuration for in-use operation on a variety of machinery and vehicle components heretofore previously not compatible.

Abstract: A bearing assembly incorporating a speed and/or temperature sensor particularly adapted for motor vehicle wheel applications. The sensor incorporates a magnetized tone ring defining a radial or cylindrical face which interacts with an annular transducer. The transducer has a plurality of teeth facing the magnetized tone ring with separate first and second rows of teeth extending from the transducer frame. The first set of teeth engage one area of the tone ring defining one magnetic pole whereas the second series of teeth interact with regions of the tone ring defining the opposite magnetic pole. Relative rotation between the transducer and tone ring induces an alternating magnetic field through the transducer case which induces an alternating voltage in the winding coil. The transducer is efficiently packaged within the enclosed cavity of a bearing assembly. This invention further contemplates a means to allow transducer temperature to be evaluated by monitoring the DC resistance of the transducer winding.

Abstract: A bearing assembly incorporating a speed and/or temperature sensor particularly adapted for motor vehicle wheel applications. The sensor incorporates a magnetized tone ring defining a radial or cylindrical face which interacts with an annular transducer. The transducer has a plurality of teeth facing the magnetized tone ring with separate first and second rows of teeth extending from the transducer frame. The first set of teeth engage one area of the tone ring defining one magnetic pole whereas the second series of teeth interact with regions of the tone ring defining the opposite magnetic pole. Relative rotation between the transducer and tone ring induces an alternating magnetic field through the transducer case which induces an alternating voltage in the winding coil. The transducer is efficiently packaged within the enclosed cavity of a bearing assembly. This invention further contemplates a means to allow transducer temperature to be evaluated by monitoring the DC resistance of the transducer winding.