Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer with a nickel-based catalyst system, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, where the temperature of the polymerization mixture is maintained below 34° C. during said step of polymerizing, and where the conversion of the conjugated diene monomer is maintained below 30%.

Abstract: A process for preparing a polydiene, the process comprising the steps of (i) providing conjugated diene monomer; (ii) charging a nickel-based catalyst system to the conjugated diene monomer; and (iii) charging a modulating Lewis base to the conjugated diene monomer, to thereby polymerize the conjugated diene monomer in the presence of the modulating Lewis base, where said step of charging a modulating Lewis base is separate from said step of charging a nickel-based catalyst, and where said steps of providing conjugated diene monomer, charging a nickel-based catalyst system and charging a Lewis base form a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of (a) polymerizing monomer in the presence of a coordination catalyst to form a polymer, (b) inhibiting said step of polymerizing with a Lewis base, and (c) reacting the polymer with a functionalizing agent.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.

Abstract: A method for preparing a polymeric composition, the method comprising providing a polymer cement including a polymer and a solvent; introducing a cold-flow inhibitor with the polymer cement, where the cold-flow inhibitor is selected from the group consisting of vicinal diamides, vicinal diureas and vicinal amide-ureas; and isolating at least a portion of the polymer and the cold-flow inhibitor from the solvent to provide a polymeric composition including the polymer and the cold-flow inhibitor.

Abstract: A method for reducing the cold flow of a polymeric composition of matter by introducing polymer with the combination or reaction product of (i) an acetal or ketal of an alditol and (ii) (a) a hydrocarbylated boric acid, (b) an organoaluminum compound, or (c) both a hydrocarbylated boric acid and an organoaluminum compound.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.

Abstract: A method for quenching an active polymerization mixture, the method comprising introducing a polyhydroxy compound to an active polymerization mixture.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.

Abstract: A method for reducing the cold flow of a polymeric composition of matter by introducing polymer with the combination or reaction product of (i) an acetal or ketal of an alditol and (ii) (a) a hydrocarbylated boric acid, (b) an organoaluminum compound, or (c) both a hydrocarbylated boric acid and an organoaluminum compound.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.

Abstract: There is disclosed a process for producing a conjugated diene-containing polymer wherein a stream comprising conjugated diene monomer and a specified catalyst, that includes a lanthanide compound and an aluminoxane, is passed through an orifice into the reaction zone of a polymerization vessel, maintained under specific pressure conditions to form a cement having a viscosity that allows the cement to be conveyed through a devolatilization zone, where desired.

Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.

Abstract: A method for quenching an active polymerization mixture, the method comprising introducing a polyhydroxy compound to an active polymerization mixture.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of (a) polymerizing monomer in the presence of a coordination catalyst to form a polymer, (b) inhibiting said step of polymerizing with a Lewis base, and (c) reacting the polymer with a functionalizing agent.

Abstract: There is disclosed a process for producing a conjugated diene-containing polymer wherein a stream comprising conjugated diene monomer and a specified catalyst, that includes a lanthanide compound and an aluminoxane, is passed through an orifice into the reaction zone of a polymerization vessel, maintained under specific pressure conditions to form a cement having a viscosity that allows the cement to be conveyed through a devolatilization zone, where desired.