Patents by Inventor Kiyoshi Nakazyo
Kiyoshi Nakazyo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4735893Abstract: A silver halide color photographic light-sensitive material containing a combination of a pyrazolo-azole magenta coupler and a specific dye image stabilizing agent is disclosed. The stabilizing agent is effective to improve fastness of a dye image formed by the coupler to light, heat and moisture.Type: GrantFiled: June 10, 1985Date of Patent: April 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Masakazu Morigaki, Toshio Kawagishi, Kiyoshi Nakazyo, Nobuo Seto, Sadao Kamei
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Patent number: 4681835Abstract: A method of processing a silver halide color photographic material, which comprises processing a photographic material containing at least one pyrazoloazole type magenta coupler represented by the general formula (I) in a final bath containing a soluble iron salt in an amount of at least 1.times.10.sup.-4 mol/l, whereby marked improvements in stabilization of color images, especially cyan dye images and prevention of yellow stain are achieved: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent, X represents a hydrogen atom or a group capable of being eliminated by the coupling reaction with an oxidation product of an aromatic primary amine developing agent, and Z.sub.a, Z.sub.b and Z.sub.c each represents methine group, a substituted methine group, .dbd.N-- or --NH--, provided that one of the Z.sub.a -Z.sub.b and Z.sub.b -Z.sub.c bonds is a double bond and the other is a single bond, in which when it represents a double bond the Z.sub.b -Z.sub.Type: GrantFiled: December 12, 1985Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Kiyoshi Nakazyo
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Patent number: 4659652Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein said material includes at least one magenta coupler of 1H-pyrazolo(1,5-b)(1,2,4)triazole type in which a substituted or unsubstituted aryloxy group is attached to the coupling active site to heighten coloring efficiency and speed, and further to ensure excellent light-fastness to the dye formed therefrom.Type: GrantFiled: August 23, 1985Date of Patent: April 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Kawagishi, Kiyoshi Nakazyo
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Patent number: 4639413Abstract: A silver halide color photographic material is described, comprising a support having formed thereon at least one silver halide emulsion layer having dispersed therein, in a coexisting state, at least one magenta coupler represented by formula (I) and at least one high-boiling point organic solvent represented by the formula (II) ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent and x represents a hydrogen atom or a group capable of being released by a coupling reaction with the oxidation product of an aromatic primary amine developing agent; andwherein R.sup.3, R.sup.4, and R.sup.5 each represents an alkyl group, a cycloalkyl group, or an alkenyl group, and the total number of carbon atom of the groups R.sup.3, R.sup.4 and R.sup.5 is from 12 to 60.Type: GrantFiled: August 14, 1985Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Kawagishi, Kiyoshi Nakazyo
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Patent number: 4564586Abstract: A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, wherein the silver halide color photographic light-sensitive material contains a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sub.2, R.sub.3, R.sub.4 and R.sub.Type: GrantFiled: January 30, 1985Date of Patent: January 14, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Aoki, Michio Ono, Kiyoshi Nakazyo
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Patent number: 4559297Abstract: A silver halide photographic light-sensitive material is described, the material comprising a support having thereon at least one photographic layer containing at least one compound represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, ##STR2## a substituted or unsubstituted silyl group, a substituted or unsubstituted phosphoric acid group, or a divalent group derived from the above-described groups which forms a ring together with the oxygen atom linking to --R and the carbon atom which is in the ortho-position to --O--R and to which ##STR3## is not bonded; R.sub.1, R.sub.2 and R.sub.Type: GrantFiled: February 7, 1985Date of Patent: December 17, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Seto, Nobuo Furutachi, Masakazu Morigaki, Kiyoshi Nakazyo
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Patent number: 4404274Abstract: A photographic light-sensitive element comprising a support and having thereon at least one silver halide emulsion layer containing an .alpha.-diacylamino substituted (aliphatic acyl) acetamide yellow dye forming coupler and a method for forming yellow dye images which comprises processing a silver halide photographic emulsion with an aromatic primary amino developing agent in the presence of an .alpha.-diacylamino substituted (aliphatic acyl) acetamide compound are disclosed. The coupler is an excellent two-equivalent coupler.Type: GrantFiled: April 6, 1981Date of Patent: September 13, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuaki Arai, Yasushi Oishi, Akio Okumura, Kiyoshi Nakazyo
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Patent number: 4269936Abstract: The process of forming a dye image by developing an image-exposed silver halide photographic emulsion layer by an aromatic primary amine color developing agent in the presence of the yellow dye forming coupler shown by the general formula ##STR1## wherein R.sup.1 represents an aromatic group, R.sup.2 represents an aromatic group or a heterocyclic group, and Z represents the non-metallic atom or atoms necessary for forming a 4-membered ring, a 5-membered ring or a 6-membered ring together with ##STR2## in the above formula. A photographic element containing such a yellow-forming coupler.Type: GrantFiled: December 29, 1972Date of Patent: May 26, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuaki Arai, Yasushi Oishi, Kiyoshi Nakazyo, Atsushi Sugizaki, Akio Okumura
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Patent number: 4120725Abstract: A color photographic light-sensitive material having at least one silver halide photographic emulsion layer containing a hydrophobic coupler, in which the color photographic material additionally contains both a polymer having a recurring unit represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group and R.sup.2 and R.sup.3 each represents a hydrogen atom, an aliphatic hydrocarbon group, an aromatic hydrocarbon group, an alkyl-substituted amino group or an aryl-substituted amino group, with the proviso that both of R.sup.2 and R.sup.3 are not simultaneously hydrogen atoms, the total number of carbon atoms in R.sup.2 and R.sup.3 is 4 to 12, R.sup.2 and R.sup.3 do not contain an acidic group, and R.sup.2 and R.sup.3 can combine to form a ring;And a polymer having a recurring unit represented by the following general formula (II); ##STR2## wherein R.sup.4 has the same meaning as R.sup.1 ; and Q represents (1) --(CH.sub.2).sub.Type: GrantFiled: February 24, 1977Date of Patent: October 17, 1978Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Nakazyo, Shinji Sakaguchi, Nobuo Tsuji
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Patent number: 4072525Abstract: A photographic color coupler in which a hydrogen atom at the coupling position capable of coupling with an oxidation product of an aromatic primary amine developing agent is substituted with a group represented by the following general formula: ##STR1## wherein R and R', which may be the same or different, each represents an alkyl group, an alkenyl group, an aryl group, an alkoxy group, an alkylthio group, an aryloxy group, a hydroxy group, or an amino group, and R and R' can combine each other to form a ring; and X represents an oxygen atom or a sulfur atom. These photographic color couplers are a novel class of two-equivalent color forming couplers which are suitable for use in color photography. A color photographic light-sensitive material containing the above described photographic color coupler and a method of forming a color image comprising developing an exposed photographic light-sensitive material in the presence of the above described photographic color coupler are also disclosed.Type: GrantFiled: August 4, 1976Date of Patent: February 7, 1978Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Inouye, Yukio Yokota, Kiyoshi Nakazyo
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Patent number: 4046573Abstract: A color photographic material comprising a support having photographic layers thereon, with at least one of the photographic layers containing a non-diffusible colored coupler which releases, on coupling reaction with the oxidation product of a primary aromatic amino developing agent at development, a diffusible dye capable of being removed from the photographic layer, the non-diffusible colored coupler being represented by general formula (I):a--o--so.sub.2 --r--b (i)wherein R represents an alkylene group having 1 to 10 carbon atoms; A represents an image forming coupler residue containing a phenol nucleus or a naphthol nucleus, and wherein the --O--SO.sub.2 --R--B group is bonded to the coupling position of the coupler residue and the group can be released upon oxidative coupling with an aromatic primary amine developing agent to form a dye; and B represents a residue containing a chromophore.Type: GrantFiled: March 24, 1976Date of Patent: September 6, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Inouye, Kotaro Nakamura, Yukio Yokota, Kiyoshi Nakazyo, Akio Okumura
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Patent number: 4029508Abstract: A yellow color forming photographic coupler represented by the following general formula (I): ##STR1## wherein Q represents an aliphatic group, an alicyclic group, an aromatic group or a heterocyclic group; Y represents a hydrogen atom, an aliphatic group, an alicyclic group, an aromatic group or a heterocyclic group; R represents a divalent aliphatic group, a divalent alicyclic group, a divalent aromatic group or a divalent heterocyclic group; and Z represents an oxygen atom, a sulfur atom or a nitrogen atom substituted with an electron attracting group.Type: GrantFiled: August 14, 1975Date of Patent: June 14, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsugu Tanaka, Atsuaki Arai, Kiyoshi Nakazyo, Keisuke Shiba
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Patent number: 4022620Abstract: A method of forming color photographic images which comprises developing image-exposed photographic silver halide emulsion layer with a primary aromatic amino color developing agent in the presence of a yellow color forming coupler represented by the following general formula (I) ##STR1## wherein X.sub.1 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group or an acyl group; X.sub.2 represents a hydrogen atom, an alkyl group or an aryl group; X.sub.3 represents a hydrogen atom, an alkyl group, an aryl group or an acyl group; Y represents an oxygen atom or a sulfur atom; and Q represents a residue of a yellow color forming coupler, e.g., a yellow coupler in which one hydrogen atom attached to the active methylene group of the coupler is eliminated. These yellow color forming couplers provide yellow color images having superior properties.Type: GrantFiled: April 3, 1975Date of Patent: May 10, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Akio Okumura, Atsushi Sugizaki, Seiji Ichijima, Keisuke Shiba, Kiyoshi Nakazyo
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Patent number: 4021248Abstract: A color photographic light-sensitive material comprising a silver halide photographic emulsion containing (1) at least one compound selected from the group consisting of (a) a compound represented by the following general formula (I);cp - Z (I)wherein Cp represents a monovalent residue of a magenta or yellow coupler residue in which one hydrogen atom of the active methylene group is replaced by a coupling off group Z eliminated upon coupling reaction with an oxidation product of an aromatic primary amine color developing agent, and Z represents a nitrogen-containing coupling-off group connected to Cp at a nitrogen atom thereof, and (b) a 4-position unsubstituted 3-arylamino-5-pyrazolone derivative, and (2) at least one compound represented by the following general formula (II);q - sh (ii)wherein Q represents a heterocyclic group, bonded directly or indirectly thereto and containing at least one of a --SO.sub.Type: GrantFiled: September 3, 1975Date of Patent: May 3, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Kiyoshi Nakazyo, Reiichi Ohi, Keiichi Adachi
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Patent number: 4012259Abstract: A photographic silver halide emulsion containing a yellow color forming coupler, in which one hydrogen atom of an active methylene group is replaced by a 2,5-dioxo-1-imidazolidinyl group, in which a nitrogen atom at 3-position and a carbon atom at 4-position are connected to form a ring through a divalent aliphatic radical, a photographic element containing the emulsion and a method for forming color photographic images which comprises developing the image-exposed photographic silver halide emulsion with a primary aromatic amino developing agent. These yellow color forming couplers have a high coupling reactivity as well as no adverse effect on the bleaching of developed silver and thus they are suitable for use in rapid processing type color photographic materials.Type: GrantFiled: May 14, 1974Date of Patent: March 15, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Akio Okumura, Akira Sato, Seiji Ichijima, Keisuke Shiba, Kiyoshi Nakazyo
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Patent number: 3990896Abstract: A method of forming color photographic images which comprises developing an image-exposed photographic silver halide emulsion layer with a primary aromatic amino color developing agent in the presence of a yellow color forming coupler, in which one hydrogen atom of an active methylene group is substituted with a 5-alkylidene-3-hydantoinyl group and a color photographic light-sensitive element which comprises a silver halide emulsion containing a yellow color forming coupler, in which one hydrogen atom of an active methylene group of the coupler is substituted with a 5-alkylidene-3-hydantoinyl group. These yellow color forming couplers have a high coupling reactivity and additionally provide a stable coupler dispersion.Type: GrantFiled: October 9, 1974Date of Patent: November 9, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuaki Arai, Akio Okumura, Seiji Ichijima, Keisuke Shiba, Kiyoshi Nakazyo
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Patent number: H122Abstract: A silver halide color photographic light-sensitive material which comprises a support having thereon at least one silver halide emulsion layer containing dispersed therein at least one magenta coupler represented by the following general formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a substituent, each represents a hydrogen atom or a substituent, X represents a hydrogen atom or a group capable of being eliminated upon coupling with an oxidation product of an aromatic primary amine developing agent, Z represents a nitrogen atom or --CR.sup.6 where R.sup.6 represents a hydrogen atom or a substituent and dimers or higher polymers thereof,together with at least one high boiling organic solvent represented by the following general formula (II): ##STR2## wherein R.sup.3, R.sup.4 and R.sup.Type: GrantFiled: July 19, 1985Date of Patent: September 2, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Kawagashi, Kiyoshi Nakazyo, Masakazu Morigaki
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Patent number: H131Abstract: Silver halide color photographic materials contain pyrazoloazole type magenta couplers having at least one hydroxyphenyl group bonded thereto. The silver halide color photographic materials are improved in color developability and color image light fastness. The pyrazoloazole type magenta couplers are 5-membered ring/5-membered ring condensed nitrogen heterocyclic type couplers.Type: GrantFiled: September 9, 1985Date of Patent: September 2, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Furutachi, Tadahisa Sato, Toshio Kawagishi, Kiyoshi Nakazyo