Patents by Inventor Klaus Lorenz

Klaus Lorenz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20210070916
    Abstract: A process for producing polyurethane foams by reaction of the components: A, B, C, and D. Component A comprises a polyol component, comprising A1 which is 40 to 100 parts by weight of polyether carbonate polyol and A2 which is 0 to 60 parts by weight of polyether polyol. Component B can comprise B1 a catalyst, and B2 optionally auxiliary and additive substances. Component C can comprise water and/or physical blowing agents. Component D can comprise di- and/or polyisocyanates. Production is carried out at an index of 90 to 120 and in the presence of a component K, wherein the component K comprises a reaction product of alkoxylated phosphoric acid with 1,3-dicarbonyl compound or carboxylic anhydride. A polyurethane foam and a method for producing articles are also disclosed.
    Type: Application
    Filed: April 4, 2019
    Publication date: March 11, 2021
    Inventors: Persefoni Hilken, Stefan Lindner, Joerg Hofmann, Klaus Lorenz
  • Patent number: 10787550
    Abstract: The present invention relates to the use of hydrophopic polyols for producing fiber composite components on the basis of a polyurethane/polyisocyanurate reaction mixture, to a method for producing composite components and to the composite components as such. The method according to the invention is particularly economical in terms of saving material and time costs and the composite components obtained are characterized by excellent visual and material properties.
    Type: Grant
    Filed: June 25, 2015
    Date of Patent: September 29, 2020
    Assignee: COVESTRO DEUTSCHLAND AG
    Inventors: Stefan Lindner, Klaus Lorenz, Marc Schütze, Florian Hupka, Dirk Passmann, Peter Nordmann
  • Patent number: 10457775
    Abstract: The invention relates to an efficient method for producing polyoxyalkylene polyols with equivalent molar masses between 9500 and 23000 g/mol from one or more H-functional starter compounds, and one or more alkylene oxides in the presence of a double metal cyanide catalyst, characterized in that the alkylene oxide metering rate is reduced once a calculated equivalent molar mass of between 8000 and 9500 g/mol is reached.
    Type: Grant
    Filed: August 23, 2016
    Date of Patent: October 29, 2019
    Assignee: Covestro Deutschland AG
    Inventors: Klaus Lorenz, Christian Steinlein, Horst Zwick, Markus Bodenmüller, Stephan Eckelmann, Friedhelm Baer
  • Publication number: 20190161577
    Abstract: The invention relates to a two-stage method for the preparation of polyoxyalkylene polyols having low equivalent molar masses, in which the method requires no reprocessing. The invention is characterized in that, in the first stage, a polyoxyalkylene polyol precursor is provided, which contains the salts of a strong Bronsted acid, and in that, in a second stage, the polyoxyalkylene polyol precursor is further reacted with alkylene oxides under DMC catalysis.
    Type: Application
    Filed: May 11, 2017
    Publication date: May 30, 2019
    Inventors: Klaus LORENZ, Ingo DANEK
  • Patent number: 10253134
    Abstract: The invention concerns a new polyol composition from isopropylidenediphenol-based polyethers, which are used in an advantageous manner for the production of polyurethane-polyisocyanurate (PUR-/PIR) rigid foams, as well as their production and use in PUR/PIR rigid foams.
    Type: Grant
    Filed: May 9, 2016
    Date of Patent: April 9, 2019
    Assignee: COVESTRO DEUTSCHLAND AG
    Inventors: Hartmut Nefzger, Stephan Schleiermacher, Klaus Lorenz
  • Publication number: 20180334530
    Abstract: The invention relates to a method for producing PUR/PIR rigid foam materials, having the steps of reacting at least one polyester polyol (a), which can be obtained by reacting a. I.) at least one cyclic carboxylic acid anhydride; a.2.) at least one low-molecular dial with a molecular mass of 62 to 450 Da; and a.3.) at least one alkylene oxide; by esterifying the components a.I.) and a.2.) and subsequently oxalkylating the resulting carboxylic acid half-ester using component a.3.); wherein at least the oxalkylation is carried out using a.4.) at least one amine catalyst in which (the) nitrogen atom(s) is/are part of an aromatic ring system, with (b) at least one polyisocyanate-containing component, (c) at least one propellant, (d) at least one or more catalysts, (e) optionally at one flameproofing agent and/or other auxiliary agents, and (f) optionally at least one additional compound with at least two groups which are reactive towards isocyanates and which differ from polyester polyol (a).
    Type: Application
    Filed: November 23, 2016
    Publication date: November 22, 2018
    Inventors: Hartmut Nefzger, Torsten Hagen, Klaus Lorenz, Rene Abels
  • Patent number: 10131743
    Abstract: This invention relates to a process for preparing polyols which contain oxyalkylene units. This process comprises neutralizing a crude polyol by addition of an acid, optionally removing water, and removing the salts formed by neutralization. The crude polyol is contacted with the acid for at least 5 minutes.
    Type: Grant
    Filed: December 16, 2014
    Date of Patent: November 20, 2018
    Assignee: Covestro Deutschland AG
    Inventors: Klaus Lorenz, Marco Antonio Marquez-Benitez
  • Publication number: 20180273674
    Abstract: The present invention relates to a method for producing polyurethane foams by reacting an isocyanate component with an isocyanate-reactive component comprising at least one polyethercarbonate polyol, the reaction taking place in the presence of a component K selected from one or more compounds from the group consisting of K1 esters of mono- or polybasic carboxylic acids whose (first) dissociation has a pKa of 0.5 to 4.0, K2 mono-, di- and polysulfonates of mono- and polyfunctional alcohols, and K3 one or more compounds from the group consisting of K 3.1 esters of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid, these esters each containing no P—OH group, K3.
    Type: Application
    Filed: December 6, 2016
    Publication date: September 27, 2018
    Inventors: Bert Klesczewski, Jörg Hofmann, Karsten Malsch, Nicole Welsch, Klaus Lorenz, Hartmut Nefzger, Kai Laemmerhold
  • Publication number: 20180244842
    Abstract: The invention relates to an efficient method for producing polyoxyalkylene polyols with equivalent molar masses between 9500 and 23000 g/mol from one or more H-functional starter compounds, and one or more alkylene oxides in the presence of a double metal cyanide catalyst, characterised in that the alkylene oxide metering rate is reduced once a calculated equivalent molar mass of between 8000 and 9500 g/mol is reached.
    Type: Application
    Filed: August 23, 2016
    Publication date: August 30, 2018
    Inventors: Klaus Lorenz, Christian Steinlein, Horst Zwick, Markus Bodenmüller, Stephan Eckelmann, Friedhelm Baer
  • Publication number: 20180171062
    Abstract: The invention concerns a new polyol composition from isopropylidenediphenol-based polyethers, which are used in an advantageous manner for the production of polyurethane-polyisocyanurate (PUR-/PIR) rigid foams, as well as their production and use in PUR/PIR rigid foams.
    Type: Application
    Filed: May 9, 2016
    Publication date: June 21, 2018
    Applicant: Covestro Deutschland AG
    Inventors: Hartmut Nefzger, Stephan Schleiermacher, Klaus Lorenz
  • Patent number: 9994672
    Abstract: The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride and at least one alkylene oxide compound to give a hydroxyl-group-carrying prepolymer, b) adding a primary amine and/or ammonia to the double bonds of the hydroxyl-group-carrying prepolymer obtained according to step a) to give the hydroxy-amino polymer, wherein the reaction of the H-functional starter compound with the unsaturated cyclic carboxylic acid anhydride and/or the addition of the alkylene oxide compound is carried out using a double metal cyanide catalyst (DMC catalyst). The invention relates additionally to a hydroxy-amino polymer obtainable by the above-mentioned process, wherein the ratio of the amount of alkylene oxide compound to the amount of carboxylic acid anhydride is at least 1.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: June 12, 2018
    Assignee: Covestro Deutschland AG
    Inventors: Klaus Lorenz, Jorg Hofmann, Hartmut Nefzger
  • Patent number: 9826734
    Abstract: The invention relates to etherified lactate esters of formula (I), in which R represents alkyl and RI an alkoxylated alkyl radical and to the use thereof for enhancing the effect of plant protecting agents.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: November 28, 2017
    Assignee: Clariant International Ltd.
    Inventors: Peter Baur, Klaus Lorenz, Jorg Hofmann
  • Patent number: 9757492
    Abstract: The present invention relates to a process for producing a hydroxy amino polymer comprising the steps: a) Reaction of an H functional starter compound bearing at least one Zerewitinoff active H atom with an unsaturated, cyclical carboxylic acid anhydride and at least one alkylene oxide compound for obtaining a prepolymer bearing hydroxyl groups, b) Addition of a primary amine and/or of ammonia to the double bond(s) of the prepolymer bearing hydroxyl groups obtained according to step a) for obtaining the hydroxy amino polymer, wherein the ratio of added amino groups to hydroxyl groups in a hydroxy amino polymer is at least 0.6. Furthermore, the invention relates to a hydroxy amino polymer, which can be achieved according to this process as well as a polyurea/polyurethane system, which contains such a hydroxy amino polymer.
    Type: Grant
    Filed: January 10, 2017
    Date of Patent: September 12, 2017
    Assignee: Adhesys Medical GmbH
    Inventors: Heike Heckroth, Christoph Eggert, Jörg Hofmann, Klaus Lorenz, Edward Browne, Hartmut Nefzger
  • Patent number: 9714216
    Abstract: The present invention relates to a process for preparing polyether polyols by addition of alkylene oxides onto H-functional starter substances, characterized in that at least one urethane alcohol of formula (II) where R1 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R2 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R is H, linear or branched C1 to C24-alkyl, C3 to C24-cycloalkyl, C4 to C24-aryl, C5 to C24-aralkyl, C2 to C24-alkenyl, C2 to C24-alkynyl, each of which may optionally be interrupted by heteroatoms such as O, S or N and/or each of which may be substituted by alkyl, aryl and/or hydroxyl, is used as H-functional starter compound.
    Type: Grant
    Filed: November 19, 2014
    Date of Patent: July 25, 2017
    Assignee: Covestro Deutschland AG
    Inventors: Jörg Hofmann, Kai Laemmerhold, Hartmut Nefzger, Monika Heinz, Bert Klesczewski, Klaus Lorenz
  • Publication number: 20170152354
    Abstract: The present invention relates to the use of hydrophopic polyols for producing fiber composite components on the basis of a polyurethane/polyisocyanurate reaction mixture, to a method for producing composite components and to the composite components as such. The method according to the invention is particularly economical in terms of saving material and time costs and the composite components obtained are characterized by excellent visual and material properties.
    Type: Application
    Filed: June 25, 2015
    Publication date: June 1, 2017
    Inventors: Stefan Lindner, Klaus Lorenz, Marc Schütze, Florian Hupka, Dirk Passmann, Peter Nordmann
  • Publication number: 20170119921
    Abstract: The present invention relates to a process for producing a hydroxy amino polymer comprising the steps: a) Reaction of an H functional starter compound bearing at least one Zerewitinoff active H atom with an unsaturated, cyclical carboxylic acid anhydride and at least one alkylene oxide compound for obtaining a prepolymer bearing hydroxyl groups, b) Addition of a primary amine and/or of ammonia to the double bond(s) of the prepolymer bearing hydroxyl groups obtained according to step a) for obtaining the hydroxy amino polymer, wherein the ratio of added amino groups to hydroxyl groups in a hydroxy amino polymer is at least 0.6. Furthermore, the invention relates to a hydroxy amino polymer, which can be achieved according to this process as well as a polyurea/polyurethane system, which contains such a hydroxy amino polymer.
    Type: Application
    Filed: January 10, 2017
    Publication date: May 4, 2017
    Inventors: Heike HECKROTH, Christoph EGGERT, Jörg HOFMANN, Klaus LORENZ, Edward BROWNE, Hartmut NEFZGER
  • Patent number: 9580540
    Abstract: The present invention relates to a process for producing a hydroxy amino polymer comprising the steps: a) Reaction of an H functional starter compound bearing at least one Zerewitinoff active H atom with an unsaturated, cyclical carboxylic acid anhydride and at least one alkylene oxide compound for obtaining a prepolymer bearing hydroxyl groups, b) Addition of a primary amine and/or of ammonia to the double bond(s) of the prepolymer bearing hydroxyl groups obtained according to step a) for obtaining the hydroxy amino polymer, wherein the ratio of added amino groups to hydroxyl groups in a hydroxy amino polymer is at least 0.6. Furthermore, the invention relates to a hydroxy amino polymer, which can be achieved according to this process as well as a polyurea/polyurethane system, which contains such a hydroxy amino polymer.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: February 28, 2017
    Assignee: Adhesys Medical GmbH
    Inventors: Heike Heckroth, Christoph Eggert, Jörg Hofmann, Klaus Lorenz, Edward Browne, Hartmut Nefzger
  • Publication number: 20160369051
    Abstract: This invention relates to a process for preparing polyols which contain oxyalkylene units. This process comprises neutralizing a crude polyol by addition of an acid, optionally removing water, and removing the salts formed by neutralization. The crude polyol is contacted with the acid for at least 5 minutes.
    Type: Application
    Filed: December 16, 2014
    Publication date: December 22, 2016
    Inventors: Klaus Lorenz, Marco Antonio Marquez-Benitez
  • Patent number: 9468701
    Abstract: The present invention relates to an isocyanate functional prepolymer that can be achieved through a) a reaction of an H functional starter compound having at least one Zerewitinoff active H atom with an alkylene oxide and a comonomer to a preliminary stage bearing hydroxyl groups, wherein said comonomer is selected from the group comprising lactides, glycolides, cyclical dicarboxylic acid anhydrides as well as combinations thereof and wherein said comonomer is integrated through statistical copolymerization into the polymer chain(s) of the preliminary stage bearing hydroxyl groups, and b) a reaction of the preliminary stage bearing hydroxyl groups from step a) with a polyfunctional isocyanate to an isocyanate functional prepolymer. The invention additionally relates to a process for producing this isocyanate functional prepolymer, a tissue adhesive system containing such an isocyanate functional prepolymer and a dispensing system having at least two chambers and this type of tissue adhesive system.
    Type: Grant
    Filed: May 16, 2016
    Date of Patent: October 18, 2016
    Assignee: Adhesys Medical GmbH
    Inventors: Heike Heckroth, Christoph Eggert, Jörg Hofmann, Klaus Lorenz
  • Publication number: 20160264519
    Abstract: The present invention relates to a process for preparing polyether polyols by addition of alkylene oxides onto H-functional starter substances, characterized in that at least one urethane alcohol of formula (H) where R1 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R2 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R3 is H, linear or branched C1 to C24-alkyl, C3 to C24-cycloalkyl, C4 to C24-aryl, C5 to C24-aralkyl. C2 to C24-alkenyl, C2 to C24-alkynyl, each of which may optionally be interrupted by heteroatoms such as O, S or N and/or each of which may be substituted by alkyl, aryl and/or hydroxyl, is used as H-functional starter compound.
    Type: Application
    Filed: November 19, 2014
    Publication date: September 15, 2016
    Inventors: Jörg HOFMANN, Kai LAEMMERHOLD, Hartmut NEFZGER, Monika HEINZ, Bert KLESCZEWSKI, Klaus LORENZ