Abstract: In a first aspect, a dicarbonyl halide includes an alicyclic group. In a second aspect, a polymer composition is derived from the dicarbonyl halide, a dianhydride and a diamine, wherein the polymer composition is a poly(amide-imide) or a poly(amide-ester-imide), wherein the poly(amide-ester-imide) is further derived from a polyol. In a third aspect, a polymer film includes the polymer composition. In a fourth aspect, an electronic device includes the polymer film. In a fifth aspect, a metal-clad laminate includes the polymer film.

Abstract: The present disclosure is related to an electrolyte composition comprising from 30 to 80% by weight of CH3CO2CH2CF2H, from 10 to 60% by weight of ethylene carbonate or propylene carbonate, from 0.1 to 1.0% by weight of lithium bis(oxalate) borate, from 0.2 to 2.0 moles/L of lithium hexafluorophosphate and from 0.1 to 2% by weight of fluoroethylene carbonate, where the amounts of compounds are based on the total weight of the electrolyte composition, and where when used as an electrolyte in a lithium-ion battery, the composition exhibits an 80% cycle life of at least 250 at a cycling rate is 240 mA/g.

Abstract: In a first aspect, a polymer composition includes a first polymer derived from a soluble polymer composition having an imide group and a Tg reducing compound having an amine group. The first polymer has a glass transition temperature that is lower than a second polymer derived from the same soluble polymer composition, but without a Tg reducing compound having an amine group. In a second aspect, a coating solution includes a soluble polymer having an imide group and a Tg reducing compound having an amine moiety that can be an amine or a first masked amine that can be converted to an amine, wherein the first masked amine can be chemically converted, thermally converted, photo-converted or dissociated.

Abstract: In a first aspect, a polyimide film includes a polyimide derived from a dianhydride and a diamine. The dianhydride, the diamine or both the dianhydride and the diamine include an alicyclic monomer, an aliphatic monomer or both an alicyclic monomer and an aliphatic monomer. The polyimide film has an L* of at least 90, a b* of 1.25 or less, a yellowness index of 2.25 or less and a haze of less than 1% for a film thickness of 50 ?m. In a second aspect, an electronic device includes the polyimide film of the first aspect.

Abstract: In a first aspect, a polyimide corn position has a glass transition temperature of less than 300° C. and includes a polyimide derived from a dianhydride, a fluorinated aromatic diamine and an aliphatic diamine. A polyimide film made from the polyimide composition has a b* of less than one for a film thickness of at least 30 microns.

Abstract: In a first aspect, a polyimide film includes a substantially chemically converted polyimide and at least 10 volume percent of an inorganic filler, based on a total volume of the polyimide film. A void ratio of the polyimide film is 0.75 or less. In a second aspect, a polyimide film includes a substantially chemically converted polyimide and at least 10 volume percent of an organic filler, based on a total volume of the polyimide film. A void ratio of the polyimide film is 1.0 or less.

Abstract: In a first aspect, an article includes a first polymer film layer and a second polymer film layer. The first polymer film layer includes a first polymer including a first imide group. The second polymer film layer includes a second polymer including a second imide group.

Abstract: In a first aspect, an article includes an inorganic substrate and a polymer film layer. The inorganic substrate includes a material including a ceramic, a glass, a glass-ceramic or a mixture thereof. The material includes a metal cation selected from the group consisting of silicon, aluminum, titanium, zirconium, tantalum, niobium and mixtures thereof and oxygen. The polymer film layer includes a polymer including an imide group. From an interface where the inorganic substrate contacts the polymer film layer, a line-profile of a CNO— signal from negative secondary ion mass spectroscopy decreases as it moves away from the interface and into the bulk of the polymer film layer.

Abstract: In a first aspect, a polyimide film includes a dianhydride and a diamine. The dianhydride, the diamine or both the dianhydride and the diamine include an alicyclic monomer, an aliphatic monomer or both an alicyclic monomer and an aliphatic monomer. The polyimide film has a b* of 1.25 or less and a yellowness index of 2.25 or less for a film thickness of 50 ?m. The polyimide film is formed by: (a) polymerizing the dianhydride and the diamine in the presence of a first solvent to obtain a polyamic acid solution; (b) imidizing the polyamic acid solution to form a substantially imidized solution; (c) casting the substantially imidized solution to form a film; and (d) drying the film.

Abstract: A cover window for a display includes a multilayer polymer film. The multilayer polymer film includes a first transparent, colorless polymer layer having a first elastic modulus and a second transparent, colorless polymer layer having a second elastic modulus. Each of the first and second transparent, colorless polymer layers include a polyimide, a polyamide imide, or a block copolymer of a polyimide. The polymers of both the first and second transparent, colorless polymer layers are cross-linked. The first elastic modulus is different from the second elastic modulus. The first and second transparent, colorless polymer layers are bonded by consolidation and cross-linking. The first transparent, colorless layer of the multilayer polymer film is the layer farthest from the display.

Abstract: Disclosed herein are electrolyte compositions comprising a fluorinated solvent, at least one silyl oxalate represented by the formulas RR?Si(C2O4), wherein R and R? are each the same or different from each other and independently selected from C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, or C6-C10 aryl radical, optionally comprising at least one substituent selected from halogen, hydroxyl, alkoxy, carbonyl, and carboxyl groups; and LiPF6. Also disclosed herein are electrolyte compositions comprising a fluorinated solvent and a lithium oxalato phosphate salt represented by the formula LiPF(6-2q)(C2O4)q, wherein q is 1, 2 or 3; wherein the oxalato phosphate salt comprises at least a portion that is derived from at least one silyl oxalate as defined herein. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: Disclosed herein are electrolyte compositions comprising: a) a first solvent comprising a cyclic carbonate; b) a second solvent comprising a non-fluorinated acyclic carbonate; c) at least one electrolyte component selected from: i) a fluorinated acyclic carboxylic acid ester; ii) a fluorinated acyclic carbonate; iii) a fluorinated acyclic ether; or iv) a mixture thereof; and d) an electrolyte salt; wherein the electrolyte component is present in the electrolyte composition in the range of from about 0.05 weight percent to about 10 weight percent, based on the total weight of the first and second solvents.

Abstract: In a first aspect, a coating solution includes a soluble polymer and a crosslinking precursor. The soluble polymer includes an imide group. The crosslinking precursor includes a first amine group that is either reactive or passivated towards crosslinking and one or more additional amine groups, wherein the one or more additional amine groups has been passivated towards crosslinking such that the crosslinking precursor can be chemically converted, thermally converted, photo-converted or dissociated to form at least two reactive amines. In a second aspect, a process for forming a polymer film includes: (a) casting a coating solution, (b) activating the crosslinking precursor using an external stimulus to form at least two reactive amines and crosslink the polymer, and (c) drying the polymer film. The coating solution includes a soluble polymer, including an imide group, and a crosslinking precursor.

Abstract: In a first aspect, a polyimide corn position has a glass transition temperature of less than 300° C. and includes a polyimide derived from a dianhydride, a fluorinated aromatic diamine and an aliphatic diamine. A polyimide film made from the polyimide composition has a b* of less than one for a film thickness of at least 30 microns.

Abstract: Disclosed herein are electrolyte compositions comprising a fluorinated solvent, a fluorinated sulfone, at least one component selected from a borate salt, and/or an oxalate salt, and/or a fluorinated cyclic carbonate, and at least one electrolyte salt. The fluorinated solvent may be a fluorinated acyclic carboxylic acid ester, a fluorinated acyclic carbonate, a fluorinated acyclic ether, or combinations thereof. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: In a first aspect, a polyimide film includes a dianhydride, a fluorinated aromatic diamine and an aliphatic diamine. The polyimide film has a b* of less than one for a film thickness of at least 30 microns and a glass transition temperature of less than 300° C. In a second aspect, an electronic device includes the polyimide film of the first aspect.

Abstract: In a first aspect, a consolidated polymer film includes a first polymer layer having a first elastic modulus, wherein the first polymer layer comprises a non-melt-processible polymer comprising a polyimide, a poly(amide-imide), a block copolymer of a polyimide or a poly(amide-imide) or a mixture thereof, and a second polymer layer having a second elastic modulus, wherein the second polymer layer comprises a polyimide, a poly(amide-imide), a block copolymer of a polyimide or a poly(amide-imide) or a mixture thereof. A minor surface of the first polymer layer is in contact with a minor surface of the second polymer layer. The first elastic modulus is different from the second elastic modulus. The first and second polymer layers are bonded by consolidation.

Abstract: Described herein are: An electrolyte composition comprising a) a fluorinated solvent for an electrolyte salt; b) an oxalate salt represented by the Formula LiPF(6-2q)(Ox)q, wherein Ox is an oxalate moiety and q is 1, 2 or 3; and c) optionally, at least one electrolyte salt. In some embodiments, the electrolyte composition comprises a mole ratio of Ox/P in the range of from 0.001 to 5. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: In a first aspect, a multilayer polymer film includes a first transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide and a second transparent, colorless polymer layer comprising a polyimide, a polyamide imide, or a block copolymer of a polyimide. An elastic modulus of the first transparent, colorless polymer layer is different than an elastic modulus of the second transparent, colorless polymer layer. The first and second transparent, colorless polymer layers are bonded by consolidation. In a second aspect, a cover window for a display includes the multilayer polymer film of the first aspect. The first transparent, colorless layer of the multilayer polymer film is the layer farthest from the display.

Abstract: A cover window for a display includes a multilayer polymer film. The multilayer polymer film includes a first transparent, colorless polymer layer having a first elastic modulus and a second transparent, colorless polymer layer having a second elastic modulus. Each of the first and second transparent, colorless polymer layers include a polyimide, a polyamide imide, or a block copolymer of a polyimide. The polymers of both the first and second transparent, colorless polymer layers are cross-linked. The first elastic modulus is different from the second elastic modulus. The first and second transparent, colorless polymer layers are bonded by consolidation and cross-linking. The first transparent, colorless layer of the multilayer polymer film is the layer farthest from the display.