Abstract: This invention discloses an improved process which employs mixed alpha-olefins as feed over activated metallocene catalyst systems to provide essentially random liquid polymers particularly useful in lubricant components or as functional fluids.

Abstract: A method to determine the model-of-composition of a vacuum resid in which the resid is separated into fractions including the DAO fraction which is then separated into chemical classes including saturates, aromatics, sulfides and polars by a combination of soft ionization methods. The results of the ionization analyses are reconciled with other analyses such as bulk analysis, then consolidated to generate the modeol-of composition.

Abstract: Systems and methods are provided for analysis and/or profiling of petroleum samples. The systems and methods allow for compositional analysis of samples using techniques that can be implemented outside of a laboratory setting, such as in a refinery or even at a petroleum or hydrocarbon source. The techniques are enabled by using desorption electrospray ionization as a method for generating ions for detection by mass spectroscopy. Desorption electrospray ionization can be used to generate ions for detection from a liquid or solid petroleum (or other hydrocarbon) sample with minimal sample preparation. For solid samples, the technique can also be used to identify changes in composition of a petroleum sample relative to a dimension of the solid sample.

Abstract: The present invention relates to a catalytic process for removing organonitrogen species from hydrocarbon mixtures such as refinery process feedstreams. More particularly, this invention relates to a new operating and catalyst loading strategies based on organonitrogen concentration, composition, and structure.

Abstract: A method to determine the model-of-composition of a vacuum resid wherein the resid is separated into eight fractions, saturates, aromatics, sulfides and polars by a combination of soft ionization methods.

Abstract: A method for the determination of the aromatic cores or building blocks of a vacuum resid by controlled fragmentation. Molecules can be generated from these building blocks.

Abstract: The present invention relates to a catalytic process for removing organonitrogen species from hydrocarbon mixtures such as refinery process feedstreams. More particularly, this invention relates to a new operating and catalyst loading strategies based on organonitrogen concentration, composition, and structure.

Abstract: This invention discloses an improved process which employs mixed alpha-olefins as feed over activated metallocene catalyst systems to provide essentially random liquid polymers particularly useful in lubricant components or as functional fluids.

Abstract: The present invention is a method to determine the TAN and TAN as a function of boiling point for a hydrocarbon feedstream using an electrospray ionization mass spectrometer (ESI-MS). The steps of the method include determining the signal as a function of mass from the ESI-MS while minimizing the formation of oligomers and fragmentation of the molecular species in the feedstream and then determining the TAN from the signals. The TAN is also determined as a function of boiling point.

Abstract: The present invention is a method to determine the composition of a hydrocarbon feedstream from a small sample of hydrocarbons including the steps analyzing the sample with a combination of chromatograph and mass spectrometer, and reconciling output from step a) with other analytical measurements to determine to determine the composition of the hydrocarbon feedstream.

Abstract: This invention is a data processing/visualization method which includes the software development and operation to apply to any multi-dimensional separation. The GC-MS analysis of diesel is an example to demonstrate this software development and operation. The steps of this method includes (1) displaying the total ion chromatogram obtained from a GC-MS experiment, (2) displaying each mass spectrum versus retention time, (3) selecting a normal paraffin family as the reference compound family for relative polarity display, (4) transforming every mass slice to line-up normal paraffin compound family in the same relative retention time (position), (5) rotating the axis to best display the two (multi) dimensional data.

Abstract: The present invention is a method to determine the composition of a hydrocarbon feedstream from a small sample of hydrocarbons including the steps analyzing the sample with a combination of chromatograph and mass spectrometer, and reconciling output from step a) with other analytical measurements to determine to determine the composition of the hydrocarbon feedstream.

Abstract: The present invention is a method to determine the TAN and TAN as a function of boiling point for a hydrocarbon feedstream using an electrospray ionization mass spectrometer (ESI-MS). The steps of the method include determining the signal as a function of mass from the ESI-MS while minimizing the formation of oligomers and fragmentation of the molecular species in the feedstream and then determining the TAN from the signals. The TAN is also determined as a function of boiling point.

Abstract: This invention is a data processing/visualization method which includes the software development and operation to apply to any multi-dimensional separation. The GC-MS analysis of diesel is an example to demonstrate this software development and operation. The steps of this method includes (1) displaying the total ion chromatogram obtained from a GC-MS experiment, (2) displaying each mass spectrum versus retention time, (3) selecting a normal paraffin family as the reference compound family for relative polarity display, (4) transforming every mass slice to line-up normal paraffin compound family in the same relative retention time (position), (5) rotating the axis to best display the two (multi) dimensional data.

Abstract: A method to quantify the conjugated dienes in a feedstream including the steps of dissolving 4-methyl-1,2,4-trazoline-3,5-dione (MTAD) in said feedstream, and determining the molar concentration of said conjugated dienes and/or the carbon number distribution of said conjugated dienes by GC/MS and GC/NCD (Nitrogen Chemiluminescence Detection).

Abstract: The invention relates to a method for improving yield in petroleum streams derived from coking processes. In a preferred embodiment, the invention relates to a method for regenerating filters employed to remove particulate matter from coker gas oil to improve coker gas oil yield and yield of upgraded coker gas oil products.

Abstract: A method to quantify the conjugated dienes in a feedstream including the steps of dissolving MTAD in said feedstream, and determining the molar concentration of said conjugated dienes and/or the carbon number distribution of said conjugated dienes.

Abstract: The invention relates to a method for improving yield in petroleum streams derived from coking processes. In a preferred embodiment, the invention relates to a method for regenerating filters employed to remove particulate matter from coker gas oil to improve coker gas oil yield and yield of upgraded coker gas oil products.