Patents by Inventor Laurent Germanaud

Laurent Germanaud has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5804619
    Abstract: A functionalized elastomer is provided which is of the type containing a substrate elastomer, having a weight-average molecular mass (Mw).sub.0 of between 10,000 and 600,000 daltons and a polydispersity index of less than 5, onto which are grafted, in an amount representing 0.1 to 10% by weight of the substrate, sequences carrying carboxyl or ester functional groups, wherein its weight-average molecular Mw is such that the ratio ##EQU1## is less than 20% and the sequences grafted onto the substrate correspond to the formula ##STR1## in which R.sub.1 denotes an (x+z+1)-valent C.sub.1 to C.sub.12 hydrocarbon radical, X represents H or a monovalent C.sub.1 to C.sub.12 hydrocarbon radical R, z is equal to zero or 1 and x is an integer having a value ranging from 1 to 3 with x+z .ltoreq.3. Bitumen/EF compositions useful for making surfacings may be produced by incorporating the EF into a bituminous component.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: September 8, 1998
    Assignee: Elf Exploaration Production
    Inventors: Pascal Nicol, Jean-Pascal Planche, Laurent Germanaud, Herve Nabet, Patrick Turello
  • Patent number: 5756565
    Abstract: Non-gellable, high temperature storage-stable bitumen/polymer compositions are provided and which are produced by stirring a sulphur-cross-linkable elastomer, an antigelling adjuvant and a sulphur-donating coupling agent into a bitumen or bitumen mixture at 100.degree.-230.degree. C. The antigelling adjuvant has the formula R--X wherein R is a C.sub.2-50 monovalent organic radical and X is a carboxylic acid, sulfonic acid or phosphoric acid group. The bitumen-polymer compositions may be used directly or in diluted form in a bitumen or bitumen mixture to form bitumen/polymer binders for producing road surfaces, coating materials or sealing materials.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: May 26, 1998
    Assignee: Elf Antar France
    Inventors: Laurent Germanaud, Jean-Pascal Planche, Trung Kiet Phung
  • Patent number: 5618862
    Abstract: Bitumen/polymer compositions with a broadened plasticity range are produced by stirring together a bitumen or bitumen mixture and a sulphur-cross-linkable elastomer as well as a sulphur-donating coupling agent at 100.degree.-230.degree. C. to give a cross-lined bitumen/polymer composition, stirring an acid or acid anhydride inorganic admixture into the composition at 100.degree.-230.degree. C., and maintaining the resulting reaction medium at 100.degree.-230.degree. C. while stirring for at least 20 minutes. Such bitumen/polymer compositions may be used directly or in dilute form to provide bituminous binders for road surfaces, coated materials and sealing coatings.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: April 8, 1997
    Assignee: Elf Antar France
    Inventors: Laurent Germanaud, Jean Pascal Planche, Patrick Turello
  • Patent number: 5605946
    Abstract: A process is provided for the preparation of a bitumen-polymer composition which comprises(a) producing at a temperature of between 100.degree. C. and 230.degree. C., a mixture of(i) a bitumen;(ii) a linear block copolymer of styrene and a conjugated diene, the block copolymer being used in a quantity of from 0.5% to 25% by weight of bitumen and having a weight-average molecular weight of between 170,00 and 250,000 and a structure of A-B with A denoting a polymer block consisting of a polystyrene block which may be extended on the B side by a random copolymer of styrene and of the conjugated. diene and B denoting a polymer block consisting of conjugated diene units, and(iii) a coupling agent containing at least one sulphur-donor compound and used in an amount to provide a quantity of sulphur representing, by weight, 0.1% to 10% of the weight of the liner block copolymer of styrene and conjugated diene; and(b) keeping the mixture thus produced at a temperature of between 100.degree. C. and 230.degree. C.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: February 25, 1997
    Assignee: Koch Materials Company
    Inventors: Jean-Pascal Planche, Laurent Germanaud, Pascal Nicol, Fran.cedilla.ois Travers
  • Patent number: 5269954
    Abstract: The present invention relates to the preparation of antioxidant additives to lubricants and to their use in lubricating compositions. The additives according to the invention have the formula:ArAr'(H)N--(R--X).sub.a --R'Ywhere--Ar and Ar' are identical or different aromatic radicals, R and R', which are identical or different, denote a C.sub.2 -C.sub.18 linear or branched alkylene radical, X denotes an oxygen or sulphur atom or an --NH group, a is an integer between 0 and 5 and Y is chosen from the group consisting of --NR.sub.1 R.sub.2, where R.sub.1 and R.sub.2, which are identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.12 alkyl, alkenyl, cycloalkyl or arylalkyl radical --N.dbd.CH--Ar.sub.1 where Ar.sub.1 is an aryl radical containing at least one phenolic group --NR.sub.1 --CO--Ar.sub.1 and ##STR1## where R.sub.3 denotes a saturated or unsaturated, linear or branched alkyl radical.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: December 14, 1993
    Assignee: Elf France
    Inventors: Laurent Germanaud, Patrick Azorin, Patrick Turello
  • Patent number: 5062977
    Abstract: This invention relates to additives to lubricants with antiwear and extreme-pressure effect consisting of asymmetric dihydrocarbyl polysulphides containing a hydrocarbyl polysulphide group R-S.sub.x - in a vicinal position of a secondary or tertiary alcohol, and to lubricating compositions containing these additives. The additives are prepared by reaction of a basic salt of a hydrocarbyl (poly)sulphide either with a compound containing at least one epoxy group or with an alpha-hydroxylated organic thiosulphate.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: November 5, 1991
    Assignee: Elf France
    Inventors: Laurent Germanaud, Patrick Azorin, Lhopital Michel
  • Patent number: 5055213
    Abstract: The invention relates to additives to lubricants resulting from the condensation of a primary or secondary amine and/or of an alkylene polyamine with a copolymer containing vicinal carboxylic groups.Derivatives of phenothiazine, or naphthylamine and of diphenylamine are employed in most cases as alkylene polyamine.These compounds can be employed as multifunctional additives to lubricants.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: October 8, 1991
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Laurent Germanaud, Nguyen Truong-Dinh, Gilbert Marie, Patrick Turello
  • Patent number: 5021175
    Abstract: Lubricating oil additives are provided which have extreme pressure, antiwear and antioxidant properties. The additives are dithiophosphorous disymmetric bisulphides of the formula: ##STR1## wherein X and Y represent an oxygen or sulphur atom or a methylene group and R.sub.1 and R.sub.2 and R.sub.3 represent a hydrocarbon radical, a polyether, a polythioether or a hydrogen atom.The invention also relates to a process for their preparation and to lubricating compositions containing the additives.
    Type: Grant
    Filed: October 4, 1990
    Date of Patent: June 4, 1991
    Assignee: Elf France
    Inventors: Laurent Germanaud, Robert Nouguier
  • Patent number: 4986924
    Abstract: The invention provides polymeric compounds resulting from the condensation of a primary amine having one phenolic group in its molecule with a copolymer of carboxylic acid functions.The copolymer is formed by copolymerization of an unsaturated monocarboxylic acid with at least one derivative of such a acid or by grafting of an unsaturated acid on a hydrocarbon polymer. These compounds can be especially used as multifunctional additives to lubricants.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: January 22, 1991
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Laurent Germanaud, Nguyen Truong Dinh, Gilbert Marie, Patrick Turello
  • Patent number: 4859357
    Abstract: The invention relates to new polyfluorinated compounds which are usable as anti-wear additives for lubricants.These compounds are of general formula: ##STR1## in which R.sub.F is a perfluorinated radical, X denotes a divalent linkage--(CH.sub.2 CF.sub.2).sub.a (CH.sub.2).sub.b --, --CF.dbd.CH--CH.sub.2 -- or --CFH--CH.sub.2 CH.sub.2 --, a is an integer ranging from 0 to 10, b is an integer ranging from 1 to 4 but equal to 2 if a is other than zero, R.sub.1 denotes a hydrogen atom or an alkyl radical, R.sub.2 denotes a hydrogen atom or a methyl radical and R.sub.3 denotes an alkyl radical. They are prepared by condensing an amino alcohol, R.sub.F --X--NH--CH.sub.2 CH(R.sub.1)OH, with an alkyl ester of an unsaturated carboxylic acid, CH.sub.2 .dbd.C(R.sub.2)--COOR.sub.3.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: August 22, 1989
    Assignee: Societe Atochem
    Inventors: Laurent Germanaud, Marc Hermant
  • Patent number: 4832859
    Abstract: In order to improve the wear resistance properties of lubricants, at least one compound of the following formula is incorporated therein: ##STR1## Rf is a perfluorinated radical, a=0 to 10,b=0 or 1 (if a=o and c=1),c=1 to 4 (2 if a.noteq.0),m=0 or 1,n=0 or 1,X is an aryl radical,Y is a 2-hydroxy-1-phenylethyl group,R.sub.1 and R'.sub.1 each represent a hydrogen atom or an alkyl, cycloalkyl or aryl radical,R.sub.2 and R'.sub.2 each represent a hydrogen atom or an acyl residue, at least one of the symbols R.sub.1 and R.sub.2 being other than H or CH.sub.3 if the sum a+m+n=0.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: May 23, 1989
    Assignee: Atochem
    Inventors: Dominique Basset, Jean-Claude Fayard, Marc Hermant, Pierre Durual, Laurent Germanaud
  • Patent number: 4704229
    Abstract: New surface-active compounds of the sulfobetaines group are manufactured. They comply with the general formula: ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is substantially a hydrocarbon radical, each of R.sub.4 and R.sub.5 is a hydrogen atom or substantially a hydrocarbon radical and R.sub.6 is a hydrogen atom or a hydrocarbon radical, R.sub.1 to R.sub.6 radicals containing together from 12 to 30 carbon atoms, n is an integer equal to 2 to 3, Z may be a CH.sub.3 radical or a hydroxy group, p may be 0 or 1 with, when Z is a hydroxy group and p is equal to 1, a value of 1 for m and for q; when Z is a methyl radical, with a value of 1 for p, a value of 2 for m and a value of 0 or 1 for q and, when p=0, a value of 2, 3 or 4 for the sum (m+q).These new surfactants are useful in enhanced oil recovery as micellar systems consisting of aqueous solutions and microemulsions.
    Type: Grant
    Filed: August 20, 1985
    Date of Patent: November 3, 1987
    Assignees: Institut Francais du Petrole, Centre National de la Recherche Scientifique
    Inventors: Sylvain Brunel, Laurent Germanaud, Pierre Le Perchec, Bernard Sillion