Abstract: In an elastomer composition, which preferably comprises an isoprene elastomer, use of an inorganic filler with a compound having the following formula (I), and which is optionally, in all or part, in a polymerized form: wherein R is R6 or OR8; wherein R1, R2, R3, R4, R5, and R6, independently from each other, are chosen from: hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, heterocycloalkyl, and alkenyl groups; and wherein R7 and R8, independently from each other, are chosen from: hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, alkenyl groups, and metals selected from the group consisting of Na, Li, and Ca.

Abstract: Elastomer isoprene rubber compositions contain an effective amount of a polyfunctional coupling system (A) as an inorganic-elastomer filler coupling agent, and (B) at least one elastomer of natural or synthetic rubber; (C) an inorganic filler as reinforcing filler; (D) other conventional constituents or additives comprising one or more vulcanizing agent(s), the polyfunctional coupling system being of the constituents (A1) and (A2): (A1) is at least one coupling agent selected from among the functionalized organosilicon compounds of formula (I): [(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a?(Z—CO—N?N—CO-A)SiO(3-a-a?)/2]q and (A2) is at least one coupling agent selected among polysulfurated “symmetric” silanes, or sulfurated “asymmetric” silanes.

Abstract: This invention relates to the modification of elastomers especially epoxidised rubber by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. In a process according to the present invention, the silane has the formula: R?—CH?CH—C(O)X—Y—SiRaR?(3-a)??(I) or R?—C?C—C(O)X—Y—SiRaR?(3-a)??(II) in which R, R?, a, Y, X and R? are as defined in the description.

Abstract: Elastomeric isoprene rubber compositions contain an effective amount of a coupling system (A) as an inorganic filler/elastomer coupling agent, and (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcing filler, (D) other conventional constituents or additives comprising (a) vulcanization agent(s), the coupling system (A) being a particular mixture of the following combination of constituents (A1) and (A2): (A1) is at least one coupling agent selected from among the following functionalized organosilicon compounds of formula (I):[(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a?(Z—CO—N?N—CO-A)SiO(3-a-a?)/2]g and (A2) is at least one coating agent for the reinforcing filler including one compound with the single function Y in the structure thereof which is capable of bonding physically and chemically to the inorganic filler and resulting in an increase in dispersion of the charge within the rubber matrix and a reduction in viscosity of the composition.

Abstract: Elastomeric isoprene rubber compositions contain an effective amount of a coupling agent (A) comprising an organosilicon compound with coupling agent functions for inorganic/elastomeric fillers and include (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcement filler, (D) other conventional constituents or additives comprising vulcanization agents; the coupling agent (A) being a functionalized organosilicon compound, including the following two compounds (i) and (2i), (i) being at least one functionalized siloxane corresponding to the formula (I): [(G0)3SiO1/2]m [(G0)2SiO2/2]n [G0SiO3/2]o [SiO4/2]p [(G2)a(G1)a?(Z—CO—N?N—CO-A)SiO(3-a-a?)/2]q and (2i) being a mixture of at least one functionalized siloxane (i) with (3i) at least one functionalized organosilane also corresponding to formula (I) where m=n=o=p=0 (zero), q=1, a=0, 1, 2 or 3 and the sum a+a?=3.

Abstract: The joint use in an elastomer composition of an isoprenic elastomer of a precipitated silica including aluminum as a reinforcing inorganic filler, in which the aluminum content of the precipitated silica is higher than 0.5 wt. %, and 3-acryloxy-propyltriethoxysilane as an inorganic filler, or an elastomer coupling agent is described. Also described, is an elastomer composition obtained therefrom and items produced from such a composition.

Abstract: A method for preparing precipitated silicas is described. A precipitation reaction between a silicate and an acidifying agent is also described, wherein a precipitated silica suspension is produced, and, subsequently, separation and drying of the suspension is conducted, in which, inter alia, one of the following three operations (a, b or c) is performed: (a) simultaneously adding a compound of aluminium and a basic agent, (b) simultaneously adding a silicate and a compound of aluminium, (c) simultaneously adding the acidifying agent, a silicate and a compound of aluminium.

Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.

Abstract: Precipitated silicas including clusters of large primary silica particles having at the surface thereof small primary silica particles, have a specific surface area CTAB (SCTAB) ranging from 60 to 400 m2/g; a cluster average size d50, as measured by XDC grading after ultrasound deagglomeration, such that d50 (nm)>(6214/SCTAB (m2/g)+23; a pore volume distribution such that V(d5-d50)/V(d5-d100)>0.906?(0.0013×SCATB (m2/g)); and a pore size distribution such that Mode (nm)>(4166/SCTAB (m2/g))?9.2; such silicas are useful reinforcing fillers for polymers.

Abstract: The invention relates to the use of an effective amount of a coupling system (A) as an inorganic filler/elastomer coupling agent in rubber compositions comprising: (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcing filler, (D) all or part of the other constituents or additives normally used particularly comprising (a) vulcanisation agent(s) the use being characterised in that: the coupling system (A) is a particular mixture of the following combination of ingredients (A1) and (A2): (A1) is at least one coupling agent selected from the following functionalised organosilicon compounds of formula (I): [(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a(Z-CO—N?N—CO-A)SiO(3-a-a?)/2]g where the symbols Z, A, G0, G1, G2, a, a?, m, n, o, p and q have the definitions given in claim 1, (A2) is at least one coating agent for the reinforcing filler comprising one compound with the single function Y in the structure thereof which is capable of bonding physically and chem

Abstract: Elastomer isoprene rubber compositions contain an effective amount of a polyfunctional coupling system (A) as an inorganic-elastomer filler coupling agent, and (B) at least one elastomer of natural or synthetic rubber; (C) an inorganic filler as reinforcing filler; (D) other conventional constituents or additives comprising one or more vulcanizing agent(s), the polyfunctional coupling system being of the constituents (A1) and (A2): (A1) is at least one coupling agent selected from among the functionalized organosilicon compounds of formula (I): [(G0)3SiO1/2]m [(G0)2SiO2/2]n [G0SiO3/2]o [SiO4/2]p [(G2)a(G1)a?(Z-CO—N?N—CO-A)SiO(3-a-a?)/2]q and (A2) is at least one coupling agent selected among polysulfurated “symmetric” silanes, or sulfurated “asymmetric” silanes.

Abstract: Elastomeric isoprene rubber compositions contain an effective amount of a coupling agent (A) comprising an organosilicon compound with coupling agent functions for inorganic/elastomeric fillers and include (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcement filler, (D) other conventional constituents or additives comprising vulcanization agents; the coupling agent (A) being a functionalized organosilicon compound, including the following two compounds (i) and (2i), (i) being at least one functionalized siloxane corresponding to the formula (I): [(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a?(Z-CO N?N—CO-A)SiO(3-a-a?)/2]q and (2i) being a mixture of at least one functionalized siloxane (i) with (3i) at least one functionalized organosilane also corresponding to formula (I) where m=n=o=p=0 (zero), q=1, a=0, 1, 2 or 3 and the sum a+a?=3.

Abstract: 1. Roll paper feed device (1) for a printing machine (2), comprising a cradle (3) provided with side cheeks (4), means (5, 7) at the bottom of the cradle for supporting a freely rotating paper roll (6) whenever the free end of the paper web (10) is subjected to a traction (9), braking means (13) for the rotating roll (6), which are joined to the cradle and have at least one elastic bearing member (14) against a side of the roll, which member comprises at least one elastically deformable arm (19) joined to the cradle and a protruding zone (16) situated at the free end of the arm and engaged through an opening (17) in the cheek and protruding relative to the inner face of the latter; the protruding zone is in the form of a protruding stub having a flat bearing surface (18) peripherally surrounded by an inclined surface (24, 25) suitable for sliding over the sides of the roll when this is introduced in the cradle.

Abstract: 1. Roll paper feed device (1) for a printing machine (2), comprising a cradle (3) provided with side cheeks (4), means (5, 7) at the bottom of the cradle for supporting a freely rotating paper roll (6) whenever the free end of the paper web (10) is subjected to a traction (9), braking means (13) for the rotating roll (6), which are joined to the cradle and have at least one elastic bearing member (14) against a side of the roll, which member comprises at least one elastically deformable arm (19) joined to the cradle and a protruding zone (16) situated at the free end of the arm and engaged through an opening (17) in the cheek and protruding relative to the inner face of the latter; the protruding zone is in the form of a protruding stub having a flat bearing surface (18) peripherally surrounded by an inclined surface (24, 25) suitable for sliding over the sides of the roll when this is introduced in the cradle.

Abstract: An atomic maser comprises a walled enclosure (76) defining a resonant cavity (4), and a storage bulb (8) for storing a medium capable of stimulated emission. The storage bulb is a sapphire cylinder (70) that is open at both ends and has two closure members (71,72) for closing the open ends. The closure members are made substantially of titanium and have a coating (73,74) of polyfluoroethene formed on their inner surfaces. At least one of the closure members (71,72) forms part of the walled enclosure.

Abstract: An atomic maser includes a circuit (25) for effecting a shift in the frequency of a signal injected into a resonant cavity (4) so as to generate alternately a first and a second signal portion having respectively a frequency greater than and less than the natural frequency of stimulated emission, the first and second signal portions having a periodicity corresponding to a predetermined interrogation period. Circuitry (31,32,33,51,52) is responsive to a signal detected in the cavity (4) to produce an error signal representing the difference between the amplitude of the detected signal in response to the injection of the first and second signal portions. Further circuitry (53,54) adjusts the resonant frequency of the cavity in response to the error signal. A pulse generator 26 and a mixer 28 periodically apply both the first and second signal portions for a limited duration only during the interrogation period.