Abstract: A method including forming a bilayer polymer film having an oriented polypropylene film and a metallocene-catalyzed polypropylene film wherein the metallocene-catalyzed polypropylene film has a seal initiation temperature of from 80° C. to 130° C. A laminate including a biaxially oriented polypropylene film, a metallocene-catalyzed polypropylene film, and a substrate, wherein the metallocene-catalyzed polypropylene film is disposed between the biaxially oriented polypropylene film and the substrate.

Abstract: A method including forming a bilayer polymer film having an oriented polypropylene film and a metallocene-catalyzed polypropylene film wherein the metallocene-catalyzed polypropylene film has a seal initiation temperature of from 80° C. to 130° C. A laminate including a biaxially oriented polypropylene film, a metallocene-catalyzed polypropylene film, and a substrate, wherein the metallocene-catalyzed polypropylene film is disposed between the biaxially oriented polypropylene film and the substrate.

Abstract: A method including forming a bilayer polymer film having an oriented polypropylene film and a metallocene-catalyzed polypropylene film wherein the metallocene-catalyzed polypropylene film has a seal initiation temperature of from 80° C. to 130° C. A laminate including a biaxially oriented polypropylene film, a metallocene-catalyzed polypropylene film, and a substrate, wherein the metallocene-catalyzed polypropylene film is disposed between the biaxially oriented polypropylene film and the substrate.

Abstract: A method including forming a bilayer polymer film having an oriented polypropylene film and a metallocene-catalyzed polypropylene film wherein the metallocene-catalyzed polypropylene film has a seal initiation temperature of from 80° C. to 130° C. A laminate including a biaxially oriented polypropylene film, a metallocene-catalyzed polypropylene film, and a substrate, wherein the metallocene-catalyzed polypropylene film is disposed between the biaxially oriented polypropylene film and the substrate.

Abstract: A method comprising reactively extruding a polyolefin, an acrylate containing compound, and an initiator to form a polyolefin/polyacrylate blend, and applying the blend in a melted form to one or more substrates. A method comprising extruding a metallocene ethylene-propylene random copolymer to form a melt, wherein the copolymer has a melt flow rate of from 0.5 g/10 min. to 2000 g/10 min., and applying the melt to one or more substrates. A method comprising reactively extruding a metallocene ethylene-propylene random copolymer, an acrylate containing compound, and a peroxide to form a polyolefin/polyacrylate blend, wherein the blend has a melt flow rate of greater than 100 g/10 min., and applying the blend in a melted form to one or more substrates.

Abstract: The invention relates generally to the production of polyethylene, and particularly to the production of polyethylene that is mixed with peroxides during extrusion to increase the level of long-chain branching. In an aspect, the polyethylene is used for large part blow molding (LPBM) applications. In an embodiment, the cross-linked polyethylene has a density of from about 0.945 g/cc to about 0.965 g/cc, a molecular weight distribution (MWD) of at least from 10 to 25, for example, and a high load melt index (HLMI) (ASTM D1238 21.6 kg) of from about 1 dg/min to about 30 dg/min. In an embodiment, the cross-linked polyethylene is comprised of at least one olefin having an ESCR of 100 hours to 1000 hours, and a flexural modulus of 120,000 psi to 250,000 psi.

Abstract: This invention relates polyethylene resins that are mixed with peroxides during extrusion to partially cross-link the polymer. The resins are then used to form an article and the article is then irradiated to cause further cross-linking of the polymer. Such resins are useful in blow molding applications, rotomolding, for foamed materials or articles, for extruded membranes, sheets and layers, and for applications where resins are wrapped around other materials or resins prior to irradiation. This cross-linking improves the properties of the resin for certain end-use applications. The polyethylene resins can be obtained from chromium catalyzed polymerizations, Ziegler-Natta catalyzed polymerizations, and metallocene polymerizations.

Abstract: A method of processing polyethylene for use as an extruded blow molding resin to improve the properties and processability thereof is accomplished by modifying a polyethylene resin having a molecular weight distribution (Mw/Mn) of less than about 10. The modification is carried out by the addition of a free radical initiator to the resin during extrusion of the resin to increase the rheological breadth of the polyethylene from about 10% to about 60% compared to unmodified polyethylene resin extruded under similar conditions. In another aspect of the invention, a polyethylene resin having higher melt index is processed to provide a desired final melt index by the addition of a free radical initiator where it would otherwise be necessary to utilize a resin having lower melt flow, and which is more difficult to process. Improvements in color can also be obtained.

Abstract: A method of processing polyethylene for use as an extruded blow molding resin to improve the properties and processability thereof is accomplished by modifying a polyethylene resin having a molecular weight distribution (Mw/Mn) of less than about 10. The modification is carried out by the addition of a free radical initiator to the resin during extrusion of the resin to increase the rheological breadth of the polyethylene from about 10% to about 60% compared to unmodified polyethylene resin extruded under similar conditions. In another aspect of the invention, a polyethylene resin having higher melt index is processed to provide a desired final melt index by the addition of a free radical initiator where it would otherwise be necessary to utilize a resin having lower melt flow, and which is more difficult to process. Improvements in color can also be obtained.