Abstract: The present disclosure provides for thick fins on the surface of coils or tubes in a steam cracking furnace. The fins have a thickness at their base from ¼ to ¾ of the radius of the furnace tube. The fins have grooves or protuberances on not less than about 10% of a major surface. The fins help increase the radiant heat taken up by the tube from the walls and combustion gases in the furnace.

Abstract: A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H2, CH4, CO and CO2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

Abstract: The dry oxygen content in the exhaust of an industrial furnace may be controlled to 1% or less by determining one or more of: the temperature of: each or a group of one or more burner (flame); one or more section of the radiant walls adjacent (e.g., within 5 feet of the burner); the temperature gradient across the process coils; the combustion products of one or more burners; the mass flow rate or the volume flow rate of air to each burner (e.g., the pressure drop across the variable forced air aperture ii) comparing the result to said target value; and iii) adjusting either a) the opening of the variable forced air aperture; or b) adjusting the mass flow rate or the volume flow rate of air from said one or more fans.

Abstract: A substantially linear ceramic or metallic radiant of ellipsoidal or polygonal cross section is placed proximate furnace tubes or coils in the radiant section of a fired heater to increase the radiant heat directed to the surface of the tubes or coils.

Abstract: The dry oxygen content in the exhaust of an industrial furnace may be controlled to 1% or less by determining one or more of: the temperature of: each or a group of one or more burner (flame); one or more section of the radiant walls adjacent (e.g., within 5 feet of the burner); the temperature gradient across the process coils; the combustion products of one or more burners; the mass flow rate or the volume flow rate of air to each burner (e.g., the pressure drop across the variable forced air aperture ii) comparing the result to said target value; and iii) adjusting either a) the opening of the variable forced air aperture; or b) adjusting the mass flow rate or the volume flow rate of air from said one or more fans.

Abstract: Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The present invention provides a transfer line exchanger which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The transfer line exchanger is designed by computer modeling a transfer line exchanger in which the cross section of flow path is substantially circular and modeling the operation of the transfer line under industrial conditions to validate the model design and its operation. Then iteratively the model design is deformed and the operation of the deformed part is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The present invention provides a transfer line exchanger which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The transfer line exchanger is designed by computer modeling a transfer line exchanger in which the cross section of flow path is substantially circular and modeling the operation of the transfer line under industrial conditions to validate the model design and its operation. Then iteratively the model design is deformed and the operation of the deformed part is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The present invention provides low profile, thick (“stuby”) longitudinal fins having a cross section which is a parallelogram, trapezoid or a triangle extending from 10% to 100% of a coil pass and comprising from 3 to 45 weight % of a coil in a radiant section of a furnace for thermally cracking one or more of paraffins and naphtha. The fins provide an additional surface through which heat may be transferred to the coil making the coil more efficient reducing greenhouse emissions.

Abstract: Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The present invention provides low profile, thick (“stubby”) longitudinal fins having a cross section which is a parallelogram, trapezoid or a triangle extending from 10% to 100% of a coil pass and comprising from 3 to 45 weight % of a coil in a radiant section of a furnace for thermally cracking one or more of paraffins and naphtha. The fins provide an additional surface through which heat may be transferred to the coil making the coil more efficient reducing greenhouse emissions.

Abstract: Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The efficiency of heat transfer to a furnace tube or coil in a furnace for cracking ethane, propane or naphtha feedstocks, or a mixture thereof may be improved by providing protuberances on the surface of the tube or coil having i) a maximum height from 3 to 15% of the coil outer diameter, ii) a contact surface with a coil, or a base, which area is 0.1%-10% of the coil external cross section area, and iii) a geometrical shape which has a relatively large external surface containing a relatively small volume.

Abstract: Some embodiments of the present invention provide components for a serpentine fluid reactor which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The components are designed by computer modeling the components individually and collectively in which the cross section of flow path is substantially circular under industrial conditions to validate the model design and its operation. Then iteratively the component designs are deformed and the operation of the deformed part(s) is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The present invention provides a transfer line exchanger which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The transfer line exchanger is designed by computer modeling a transfer line exchanger in which the cross section of flow path is substantially circular and modeling the operation of the transfer line under industrial conditions to validate the model design and its operation. Then iteratively the model design is deformed and the operation of the deformed part is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: The dry oxygen content in the exhaust of an industrial furnace may be controlled to 1% or less by determining one or more of: the temperature of: each or a group of one or more burner (flame); one or more section of the radiant walls adjacent (e.g., within 5 feet of the burner); the temperature gradient across the process coils; the combustion products of one or more burners; the mass flow rate or the volume flow rate of air to each burner (e.g., the pressure drop across the variable forced air aperture ii) comparing the result to said target value; and iii) adjusting either a) the opening of the variable forced air aperture; or b) adjusting the mass flow rate or the volume flow rate of air from said one or more fans.

Abstract: The efficiency of heat transfer to a furnace tube or coil in a furnace for cracking ethane, propane or naphtha feedstocks, or a mixture thereof may be improved by providing protuberances on the surface of the tube or coil having i) a maximum height from 3 to 15% of the coil outer diameter, ii) a contact surface with a coil, or a base, which area is 0.1%-10% of the coil external cross section area, and iii) a geometrical shape which has a relatively large external surface containing a relatively small volume.

Abstract: The present invention provides low profile, thick (“stubby”) longitudinal fins having a cross section which is a parallelogram, trapezoid or a triangle extending from 10% to 100% of a coil pass and comprising from 3 to 45 weight % of a coil in a radiant section of a furnace for thermally cracking one or more of paraffins and naphtha. The fins provide an additional surface through which heat may be transferred to the coil making the coil more efficient reducing greenhouse emissions.

Abstract: A stainless steel comprising at least 20 weight % of chromium and at least 1.0 weight % of manganese is adapted to support an overcoating having a thickness from 1 to 10 microns of a spinel of the formula MnxCr3?xO4 wherein x is from 0.5 to 2. Preferably the overcoating is on chromia and has stability against chemical reaction at temperatures at least 25° C. higher than the uncoated chromia.