Abstract: A method for calculating a terminal voltage of a lithium battery based on an electrochemical model, an apparatus, and a medium are provided. The method includes: constructing the electrochemical model of the lithium battery, and dividing the lithium-ion battery into three domains comprising an anode domain, a separator domain, and a cathode domain; numerically simulating the electrochemical model in the three domains respectively using the Chebyshev spectral method, and respectively obtaining distribution data of a liquid-phase potential, overpotential, and open-circuit voltage of the anode and the cathode; obtaining solid-phase potential distribution data of the anode and the cathode, based on discrete data of the liquid-phase potential, overpotential, and open-circuit voltage of the anode and the cathode; and obtaining the terminal voltage of the lithium battery based on the solid-phase potential distribution data of the anode and cathode.

Abstract: The invention provides a method and system for decoupling electric field of electrochemical model based on a parallel targeting method. The method includes selecting a negative or positive electrode region as a calculation region; selecting a solid or liquid phase current as an observed quantity, and a solid and liquid phase potential as a costate variable; inserting nodes between two endpoints of the calculation region, and determining a target value of the observed quantity of each node; constructing N calculation units; respectively performing a target shooting on the N calculation units; and determining whether a distance between the target shooting value of the observed quantity of the end point of each calculation unit and the target value of the observed quantity of the node corresponding to the end point of the calculation unit is within a preset range.