Abstract: A process and apparatus is provided for reduction of dissolved oxygen content in seawater from about 8 ppm in the feed seawater to about 10 ppb or less. Significant advantages are achieved by: use of a separator in horizontal alignment to provide high gas-liquid contacting area for separation and de-entrainment within the separator, thereby providing higher throughput; and heating seawater to at least 30° C. and up to 60° C., so as to enhance removal of oxygen from seawater; use of once-through fuel gas as stripping gas and its subsequent combustion for heating the seawater provides for high efficiency and reduction of fouling. The combination of these features allows the amount of residual oxygen in deoxygenated seawater to be reduced to below 10 ppb and as low as 2 ppb.

Abstract: A vapor distributor for use in atmospheric or vacuum columns includes a new design of vapor inlet device, or vapor horn, to provide superior mixing and distribution of a tangential first feed and a vertical second feed. New vapor inlet device has an inlet dividing the first feed into two portions, each flowing in respective housings in opposed circulation directions, and a plurality of vanes for redirection of vapor. Mixing and distribution of feeds by the vapor distributor is further enhanced by inclusion in vapor distributor of a mixer and vapor directing plates.

Abstract: A process and apparatus is provided for reduction of dissolved oxygen content in seawater from about 8 ppm in the feed seawater to about 10 ppb or less. Significant advantages are achieved by: use of a separator in horizontal alignment to provide high gas-liquid contacting area for separation and de-entrainment within the separator, thereby providing higher throughput; and heating seawater to at least 30° C. and up to 60° C., so as to enhance removal of oxygen from seawater; use of once-through fuel gas as stripping gas and its subsequent combustion for heating the seawater provides for high efficiency and reduction of fouling. The combination of these features allows the amount of residual oxygen in deoxygenated seawater to be reduced to below 10 ppb and as low as 2 ppb.

Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent, is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.

Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent, is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.

Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.

Abstract: A vapor distributor for use in atmospheric or vacuum columns includes a new design of vapor inlet device, or vapor horn, to provide superior mixing and distribution of a tangential first feed and a vertical second feed. New vapor inlet device has an inlet dividing the first feed into two portions, each flowing in respective housings in opposed circulation directions, and a plurality of vanes for redirection of vapor. Mixing and distribution of feeds by the vapor distributor is further enhanced by inclusion in vapor distributor of a mixer and vapor directing plates.

Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.