Abstract: Glasses having a low softening point and high toughness. The glasses are alkali aluminoborosilicate glasses having softening points of less than 900° C. and, in some embodiments, in a range from about 650° C. up to about 825° C., and an indenter damage threshold of at least 300 g for glasses that are not chemically strengthened. The glasses are free of alkaline earth metals, lead, arsenic, antimony, and, in some embodiments, lithium.

Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.

Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.

Abstract: A solid oxide fuel cell device includes layers of solid electrolyte, cathode plates, anode plates, a frame and a non-contaminating, electrochemically stable sealing material. The sealing material may have a CTE of about 95×10?7/° C. to about 115×10?7/° C. The sealing material may include from about 65 wt % to about 100 wt % of glass frit and from about 0 wt % to about 35 wt % of a filler material. The glass frit may include from about 0 mol % to about 43 mol % of a metal oxide expressed as RO wherein R comprises magnesium, calcium, strontium, barium, zinc and/or combinations thereof. The glass frit may also include from about 0 mol % to about 5 mol % Al2O3; from about 0 mol % to about 7 mol % TiO2; and from about 41 mol % to about 60 mol % SiO2.

Abstract: A glass article having improved edge strength. The glass article includes a glass substrate and an outer edge comprising a glass frit disposed on the edge of the substrate, wherein the glass frit is under compression. Methods of making the glass article and strengthening the edge of a glass article are also provided.

Abstract: Photovoltaic devices having light scattering articles having a smooth surface are described herein. Glass frits on glass superstrates can provide planar surfaces for subsequent layer deposition such as TCO layers and yet provide light scattering functions within, for example, silicon tandem photovoltaic devices. Methods of making the light scattering articles with a planar surface include depositing unfilled or filled glass frits on planar or surface-textured superstrates and sintering of the glass frit. The compositions of the glass frits can be tailored to match, for example, the expansion properties and physical properties of the glass superstrates.

Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.

Abstract: A method of fowling an opal layer on an optically transparent alkali-silicate glass sheet, wherein a liquidus viscosity of the alkali silicate glass forming the sheet is at least about 200,000 poise, a liquidus temperature of the alkali silicate glass is equal to or less than about 1200° C. and wherein the exposed surface of the glass sheet after the exposing comprises an opal layer. The method includes exposing a surface of the optically transparent alkali silicate glass sheet to an alkali metal salt bath at a temperature equal to or greater than 300° C. for at least 5 minutes.

Abstract: A system, method, and ink for printing a data carrying mark on a green ceramic honeycomb structure is provided. The system includes a printer having an ink jet print head that prints a mark, preferably in the form of a two-dimensional data matrix barcode, on a side wall of the green ceramic honeycomb structure. The ink may be a heat resistant ink that comprises a mixture of a glass or glass ceramic frit and a metal oxide colorant. An optical reader is provided for determining if the data is accurately reproduced in the printed mark, as well as any noise factor which may be present due to defective printing. The system includes a turntable that positions the green body for the printing operation, and then rotates the green body to position the printed mark first in front of a dryer, and then in front of the optical reader to determine the quality of the mark. Marked green and ceramic honeycombs are also provided as well as a method for repairing a defective applied bar code on a honeycomb structure.

Abstract: According to one embodiment a solid oxide fuel cell device incorporates a seal resistant to hydrogen gas permeation at a in the range of 600° C. to 9000 C, the seal having a CTE in the 100×10?7/° C. to 120×10?7/° C., wherein the seal includes a sealing material that comprises in weight %, of: (i) 80 to 100 wt % of glass frit, wherein the glass frit includes in mole % MgO, 0-10% CaO, 0-30% BaO, 30-50% B2O3, 0-40% Al2O3, 10-30% SiO2, 10-30%; and (ii) a filler, 0 wt % to 20 wt %.

Abstract: A hermetically sealed glass package preform is provided comprising a glass substrate; a frit comprising 65-100 wt. % of a base glass and about 0-35 wt. % of a filler; wherein the base glass comprises: about 0-5 mole % K2O; about 0-35 mole % Sb2O3; about 0-20 mole % ZnO; about 10-40 mole % P2O5; about 10-60 mole % V2O5; about 0-5 mole % TiO2; about 0-5 mole % B2O3; about 0-5 mole % SiO2; about 0-5 mole % WO3; and about 1-10 mole % of a metal oxide selected from the group consisting of Fe2O3, Nd2O3, La2O3, Ce2O4, Pr6O11, Er2O3, and CeO2; wherein the base glass has a mean particle size distribution of less than about 3 ?m; and wherein the filler has a mean particle size distribution of between about 3 and 7 ?m. The frit is sintered in an atmosphere less oxidizing than air at a temperature of between about 390° C. to 415° C.

Abstract: A solid oxide fuel cell device includes layers of solid electrolyte, cathode plates, anode plates, a frame and a non-contaminating, electrochemically stable sealing material. The sealing material may have a CTE of about 95×10?7/° C. to about 115×10?7/° C. The sealing material may include from about 65 wt % to about 100 wt % of glass frit and from about 0 wt % to about 35 wt % of a filler material. The glass frit may include from about 0 mol % to about 43 mol % of a metal oxide expressed as RO wherein R comprises magnesium, calcium, strontium, barium, zinc and/or combinations thereof. The glass frit may also include from about 0 mol % to about 5 mol % Al2O3; from about 0 mol % to about 7 mol % TiO2; and from about 41 mol % to about 60 mol % SiO2.

Abstract: A hermetically sealed glass package preform is provided comprising a glass substrate; a frit comprising 65-100 wt. % of a base glass and about 0-35 wt. % of a filler; wherein the base glass comprises: about 0-5 mole % K2O; about 0-35 mole % Sb2O3; about 0-20 mole % ZnO; about 10-40 mole % P2O5; about 10-60 mole % V2O5; about 0-5 mole % TiO2; about 0-5 mole % B2O3; about 0-5 mole % SiO2; about 0-5 mole % WO3; and about 1-10 mole % of a metal oxide selected from the group consisting of Fe2O3, Nd2O3, La2O3, Ce2O4, Pr6O11, Er2O3, and CeO2; wherein the base glass has a mean particle size distribution of less than about 3 ?m; and wherein the filler has a mean particle size distribution of between about 3 and 7 ?m. The frit is sintered in an atmosphere less oxidizing than air at a temperature of between about 390° C. to 415° C.

Abstract: A system, method, and ink for printing a data carrying mark on a green ceramic honeycomb structure is provided. The system includes a printer having an ink jet print head that prints a mark, preferably in the form of a two-dimensional data matrix barcode, on a side wall of the green ceramic honeycomb structure. The ink may be a heat resistant ink that comprises a mixture of a glass or glass ceramic frit and a metal oxide colorant. An optical reader is provided for determining if the data is accurately reproduced in the printed mark, as well as any noise factor which may be present due to defective printing. The system includes a turntable that positions the green body for the printing operation, and then rotates the green body to position the printed mark first in front of a dryer, and then in front of the optical reader to determine the quality of the mark. Marked green and ceramic honeycombs are also provided as well as a method for repairing a defective applied bar code on a honeycomb structure.

Abstract: A system, method, and ink for printing a data carrying mark on a green ceramic honeycomb structure is provided. The system includes a printer having an ink jet print head that prints a mark, preferably in the form of a two-dimensional data matrix barcode, on a side wall of the green ceramic honeycomb structure. The ink may be a heat resistant ink that comprises a mixture of a glass or glass ceramic frit and a metal oxide colorant. An optical reader is provided for determining if the data is accurately reproduced in the printed mark, as well as any noise factor which may be present due to defective printing. The system includes a turntable that positions the green body for the printing operation, and then rotates the green body to position the printed mark first in front of a dryer, and then in front of the optical reader to determine the quality of the mark. Marked green and ceramic honeycombs are also provided as well as a method for repairing a defective applied bar code on a honeycomb structure.

Abstract: A system, method, and ink for printing a data carrying mark on a green ceramic honeycomb structure is provided. The system includes a printer having an ink jet print head that prints a mark, preferably in the form of a two-dimensional data matrix barcode, on a side wall of the green ceramic honeycomb structure. The ink may be a heat resistant ink that comprises a mixture of a glass or glass ceramic frit and a metal oxide colorant. An optical reader is provided for determining if the data is accurately reproduced in the printed mark, as well as any noise factor which may be present due to defective printing. The system includes a turntable that positions the green body for the printing operation, and then rotates the green body to position the printed mark first in front of a dryer, and then in front of the optical reader to determine the quality of the mark. Marked green and ceramic honeycombs are also provided as well as a method for repairing a defective applied bar code on a honeycomb structure.

Abstract: A solid oxide fuel cell device incorporates a sealing material resistant to hydrogen gas permeation at a sealing temperature in the intermediate temperature range of 600° C.–900° C., the seal having a CTE in the 100×10?7/° C. to 120×10?7/° C., wherein the sealing material comprises in weight %, of: (i) a 80 wt % to 100 wt % glass frit, the glass frit itself having a composition comprising in mole percent of: SiO2 15–65; Li2O 0–5; Na2O 0–5; K2O 0–10; MgO 0–5; CaO 0–32; Al2O3 0–10; B2O3 0–50; SrO 0 to 25, wherein the total amount of alkalis is less than 10 mole %; and (ii) zirconia or leucite addition 0 wt % to 30 wt.