Abstract: A method for manufacturing a zeolite membrane structure includes a step of forming a first zeolite membrane on a porous support by hydrothermal synthesis in a state in which the porous support is immersed in a first zeolite membrane formation solution, a step of immersing the porous support formed the first zeolite membrane for greater than or equal to 5 minutes in a second zeolite membrane formation solution at greater than or equal to 10 degrees C. and less than or equal to 70 degrees C. and greater than or equal to pH 10, and a step of forming a second zeolite membrane on the first zeolite membrane by hydrothermal synthesis in a state in which the porous support formed the first zeolite membrane is immersed in the second zeolite membrane formation solution. The first zeolite membrane and the second zeolite membrane share at least one composite building unit constituting a framework structure.

Abstract: A separation membrane structure includes a porous support, a first separation membrane and a second separation membrane. The first separation membrane is formed on the porous support and contains high silica zeolite having Si/Al atomic ratio of greater than or equal to 200. The second separation membrane is formed on the first separation membrane and contains cation.

Abstract: A package comprises an airtight container having an oxygen permeability of less than or equal to 15 ml/m2dMPa and water vapor permeability of less than or equal to 2 g/m2d, and a sub-nano membrane structure accommodated in the airtight container. The sub-nano membrane structure having a porous support and a sub-nano membrane. The sub-nano membrane formed on the porous support and having an average pore diameter of less than or equal to 1 nm.

Abstract: A monolithic substrate comprises a porous base material body, a first support portion, a first cell seal portion, a second support portion, and a second cell seal portion. The base material body includes a plurality of cells respectively passing from a first end surface to a second end surface. The first support portion contains ceramics as an aggregate material, and is packed into the first end portion of a seal target cell. The first cell seal portion contains glass, and is disposed on an outer surface of the first support portion. The second support portion contains ceramics as an aggregate material, and is packed into the second end surface of the seal target cell. The second cell seal portion contains glass, and is disposed on an outer surface of the second support portion.

Abstract: A monolithic separation membrane structure comprises a porous monolithic substrate and a separation membrane. The monolithic substrate includes a first end surface, a second end surface and a plurality of through-holes respectively passing from the first end surface to the second end surface. The separation membrane is formed on an inner surface of the respective plurality of through-holes. The surface roughness Ra of the separation membrane is no more than 1 micrometer and the thickness of the separation membrane is no more than 5 micrometers.

Abstract: There are provided DDR type zeolite seed crystals capable of inhibiting generation of surplus DDR type zeolite crystals in the case of using the DDR type zeolite seed crystals as seed crystals upon forming a DDR type zeolite membrane on the surface of a porous support. The DDR type zeolite seed crystals have an average particle size of 0.05 to 1.5 ?m; contain 90% or more of particles having an aspect ratio, which is obtained by dividing the maximum Feret's diameter by the minimum Feret's diameter, of 1 to 3; and have not more than 0.3 of a coefficient of variation of the square of the aspect ratio.

Abstract: There is provided a honeycomb-shaped ceramic separation-membrane structure having higher pressure resistance than conventional ones and being capable of reducing production costs. The honeycomb-shaped ceramic separation-membrane structure is provided with a honeycomb-shaped base material, an intermediate layer, and a separation layer. At least part of a ceramic porous body has a structure where aggregate particles are bonded to one another by an inorganic bonding material component. In the ceramic separation-membrane structure, an internal pressure fracture strength capable of fracturing the structure by application of water pressure inside the cells is 7 MPa or more.

Abstract: The present invention aims to provide a honeycomb-shaped ceramic porous body where the strength reduction upon forming a separation layer is less than conventional porous bodies. The ceramic porous body is provided with a honeycomb-shaped base material and an intermediate layer. At least a part of the ceramic porous body has a structure where aggregate particles are bonded to one another by an inorganic bonding material component. In the ceramic porous body, the intermediate layer thickness, which is the thickness of the intermediate layer, is 100 ?m or more and 500 ?m or less, the base material thickness at the shortest portion between the cells, but excluding the intermediate layer and the separation layer is 0.51 mm or more and 1.55 mm or less, and the ratio of the base material thickness to the intermediate layer thickness is 2.5 or more.

Abstract: An aluminophosphate-metal oxide bonded body including a metal oxide having a bonding surface on a part of the surface thereof, and aluminophosphate that is disposed on the bonding surface of the metal oxide, wherein an alkali metal, an alkaline earth metal or both of these is/are disposed on the bonding surface of the metal oxide, and the content rate of the alkali metal, alkaline earth metal or both is from 0.3 to 30.0% by mass with respect to all of the substances that are disposed on the bonding surface of the metal oxide. An aluminophosphate-metal oxide bonded body that provides a favorable bonded state even for complicated shapes is provided.

Abstract: Provided is a zeolite membrane manufactured by: subjecting a porous body to heat treatment at 400° C. or more in the presence of oxygen as pretreatment, before adhering zeolite seed crystals to a surface of the porous body; storing the porous body under an environment of humidity of 30% or more for 12 hours or more after the heat treatment; and subsequently adhering the zeolite seed crystals to the porous body. The zeolite membrane having oxygen eight-membered rings, which is manufactured by subjecting the porous body to the heat treatment, provides a value that is obtained by dividing a permeance of CF4 by a permeance of CO2 to be 0.015 or less, and has fewer defects.

Abstract: Provided is a simple method for regenerating a zeolite membrane which has been exposed to water. The method for regenerating a zeolite membrane is a method for regenerating a zeolite membrane which is formed on a ceramic porous body and subjected to removal treatment of structure directing agent. Heating is performed at a regeneration temperature at which the difference in ratio of thermal expansion amount between the ceramic porous body and the zeolite membrane is 0.3% or less when 40° C. is set as datum. The regeneration temperature is preferably a temperature not exceeding the oxidative pyrolysis temperature of the structure directing agent used in the formation of the zeolite membrane.

Abstract: There are disclosed a ceramic separation membrane structure in which a zeolite separation membrane formed on a ceramic porous body is repaired, and a repair method thereof. In the ceramic separation membrane structure, a zeolite separation membrane 33 is disposed on a ceramic porous body 9, and defects of the zeolite separation membrane 33 are repaired by zeolite repaired portions 34 containing zeolite of structure different from the structure of zeolite of the zeolite separation membrane 33. The zeolite separation membrane 33 and the zeolite repaired portions 34 are made of a hydrophobic zeolite having a ratio of SiO2/Al2O3=100 or more.

Abstract: Provided is a simple method for regenerating a zeolite membrane which has been exposed to water. The method for regenerating a zeolite membrane is a method for regenerating a zeolite membrane which is formed on a ceramic porous body and subjected to removal treatment of structure directing agent. Heating is performed at a regeneration temperature at which the difference in ratio of thermal expansion amount between the ceramic porous body and the zeolite membrane is 0.3% or less when 40° C. is set as datum. The regeneration temperature is preferably a temperature not exceeding the oxidative pyrolysis temperature of the structure directing agent used in the formation of the zeolite membrane.

Abstract: Each cell is pressurized with gas from outside of the cell, the amount of permeation of the gas permeated into each cell is measured, and a cell having the amount of permeation greater than (average value of all cells+A) (wherein A is a predetermined value of ? to 6?, where ? is the standard deviation) is considered to be defective. Alternatively, pressure is reduced for each cell, the degree of vacuum in each cell is measured, and a cell having the degree of vacuum worse than (average value of all cells+A) is considered to be defective. Then, a polymer compound is poured into the defective cells of the monolithic separation membrane structure and cured so that the defective cells are sealed. Alternatively, the polymer compound formed in advance as the sealing member is inserted into the defective cells to seal the defective cells.

Abstract: A separation membrane structure 1 has partition walls 3 including a honeycomb shaped porous ceramic body 9 provided with a large number of pores, and cells 4 to become through channels of a fluid are formed by the partition walls 3. The cells 4 include separation cells 4a and slit cells 4b. In the separation cells 4a, the intermediate layer is disposed on the surface of a substrate 30, and a separation layer is further formed. The intermediate layer has a structure where aggregate particles are bonded to one another by an inorganic bonding material having a thermal expansion coefficient equal to or higher than that of the aggregate particles.

Abstract: There are disclosed a honeycomb shaped porous ceramic body to manufacture a honeycomb shaped ceramic separation membrane structure in which a separation performance does not deteriorate under a higher operation pressure than before, a manufacturing method for the porous body, and a honeycomb shaped ceramic separation membrane structure. The honeycomb shaped ceramic separation membrane structure 1 includes a honeycomb shaped substrate 30, an intermediate layer 31, an alumina surface layer 32, and a separation layer 33. The structure has the alumina surface layer 32 on the intermediate layer 31, whereby even when the insides of the cells 4 are pressurized, cracks are not easily generated in a porous body 9 or the separation layer 33 and the deterioration of the separation performance does not easily occur.

Abstract: There are provided DDR type zeolite seed crystals capable of inhibiting generation of surplus DDR type zeolite crystals in the case of using the DDR type zeolite seed crystals as seed crystals upon forming a DDR type zeolite membrane on the surface of a porous support. The DDR type zeolite seed crystals have an average particle size of 0.05 to 1.5 ?m; contain 90% or more of particles having an aspect ratio, which is obtained by dividing the maximum Feret's diameter by the minimum Feret's diameter, of 1 to 3; and have not more than 0.3 of a coefficient of variation of the square of the aspect ratio.

Abstract: An object of the present invention is to provide a honeycomb shaped porous ceramic body in which a strength deteriorates less than before after a separation layer is formed, a manufacturing method for the porous ceramic body, and a honeycomb shaped ceramic separation membrane structure. A honeycomb shaped porous ceramic body 9 includes a honeycomb shaped substrate 30 and an intermediate layer. At least a part of the intermediate layer of the honeycomb shaped porous ceramic body 9 has a structure in which aggregate particles are bonded to one another by a component of an inorganic bonding material. The inorganic bonding material is titania.

Abstract: A process for producing a zeolite film is provided in which seed crystals thinly adhere to the surface of a support to form a thin and even zeolite film having fewer defects than conventional zeolite films. Also provided is a zeolite film obtained by the producing process. The process for producing the zeolite film comprises: a particle adhesion step of allowing a slurry, where zeolite particles which become seeds are dispersed, to flow down on the surface of a base material by the self-weight of the slurry, so that the zeolite particles adhere to the base material; and a film formation step of immersing the base material, to which the zeolite particles adhere, into a sol to carry out hydrothermal synthesis, thereby forming the zeolite film on the base material.

Abstract: There is provided a honeycomb-shaped ceramic separation-membrane structure having higher pressure resistance than conventional ones and being capable of reducing production costs. The honeycomb-shaped ceramic separation-membrane structure (1) is provided with a honeycomb-shaped base material (30), an intermediate layer, and a separation layer. At least part of a ceramic porous body (9) has a structure where aggregate particles are bonded to one another by an inorganic bonding material component. In the ceramic separation-membrane structure (1), an internal pressure fracture strength capable of fracturing the structure by application of water pressure inside the cells (4) is 7 MPa or more.