Abstract: A gas sensor includes a sensor element, and the sensor element includes a bottomed tubular solid electrolyte, a detection electrode provided on an outer surface of the solid electrolyte, a reference electrode provided on an inner surface of the solid electrolyte. The detection electrode of the sensor element includes a detection electrode section provided at a position on a tip side of an axial direction, an attachment electrode section provided at a position on a base end side of the axial direction, and a lead electrode section provided at a position where the detection electrode section is connected to the attachment electrode section. An insulating layer is provided between a tube of the solid electrolyte and each of the attachment electrode section and the lead electrode section.

Abstract: A gas sensor includes a sensor element, and the sensor element includes a bottomed tubular solid electrolyte, a detection electrode provided on an outer surface of the solid electrolyte, a reference electrode provided on an inner surface of the solid electrolyte. The detection electrode of the sensor element includes a detection electrode section provided at a position on a tip side of an axial direction, an attachment electrode section provided at a position on a base end side of the axial direction, and a lead electrode section provided at a position where the detection electrode section is connected to the attachment electrode section. An insulating layer is provided between a tube of the solid electrolyte and each of the attachment electrode section and the lead electrode section.

Abstract: A gas sensor element having a porous protective layer with excellent water repellency. Provided is a gas sensor element having a detection portion, which has a stack of a solid electrolyte body having a pair of electrodes on opposite sides thereof and a heat generating body including a heat generating source, and a porous protective layer formed around the detection portion. The porous protective layer has thermal conductivity ? in the range of 0.2 to 5 W/mK, and has ?Cp?, which is the product of the thermal conductivity ?(W/mK), density ?(g/m3), and specific heat Cp(J/gK), in the range of 5.3×105 to 2.1×107 WJ/m4K2.

Abstract: A gas sensor element having a porous protective layer with excellent water repellency. Provided is a gas sensor element having a detection portion, which has a stack of a solid electrolyte body having a pair of electrodes on opposite sides thereof and a heat generating body including a heat generating source, and a porous protective layer formed around the detection portion. The porous protective layer has thermal conductivity ? in the range of 0.2 to 5 W/mK, and has ?Cpp, which is the product of the thermal conductivity ?(W/mK), density ?(g/m3), and specific heat Cp(J/gK), in the range of 5.3×105 to 2.1×107 WJ/m4K2.

Abstract: A gas sensor element is composed of a sensor section, a heater section, and a porous protective layer. The sensor section is composed of a solid electrolyte layer and a pair of electrodes. The heater section heats the sensor section to activate it. The porous protective layer covers surfaces of the sensor section and the heater section of the gas sensor element in a gas sensor which is exposed to a target detection gas to be detected. The porous protective layer is made of a mixture of hydrophobic heat resisting particles having a contact angle of not less than 75° to a drop of water, and the hydrophilic heat resisting particles having a contact angle not more than 30° to a drop of water. A gas sensor equipped with the above gas sensor element is also disclosed.

Abstract: A gas sensing member has a unit structure and a porous protective layer disposed on the unit structure. The unit structure has a solid electrolyte body, a gas measurement electrode disposed on a surface of the body and exposed to a measured gas entering at a gas inlet, a reference gas electrode disposed on another surface of the body and exposed to a reference gas, and a heater disposed close to the body. The heater has a heater substrate and heating elements disposed in the heater substrate. The heating elements heat the body. The heater substrate has side corner areas placed on side corners of the unit structure and being adjacent to the heating elements. The protective layer is disposed on the gas inlet such that the side corner areas are not covered with the protective layer and are directly exposed to the measured gas.

Abstract: A gas sensor element is composed of a sensor section, a heater section, and a porous protective layer. The sensor section is composed of a solid electrolyte layer and a pair of electrodes. The heater section heats the sensor section to activate it. The porous protective layer covers surfaces of the sensor section and the heater section of the gas sensor element in a gas sensor which is exposed to a target detection gas to be detected. The porous protective layer is made of a mixture of hydrophobic heat resisting particles having a contact angle of not less than 75° to a drop of water, and the hydrophilic heat resisting particles having a contact angle not more than 30° to a drop of water. A gas sensor equipped with the above gas sensor element is also disclosed.

Abstract: A ceramic laminate body, a gas sensor element employing such a ceramic laminate body and related manufacturing method are disclosed as including first and second ceramic sheets, made of material compositions different from each other, and an intermediate bonding layer, bonding the first and second ceramic sheets to each other so as to form a closed hollow space between the first and second ceramic sheets. The intermediate bonding layer has a multilayer structure including first and second unit intermediate layers laminated on each other such that innermost end portions of the first and second unit intermediate layers are displaced from each other to adapt a difference in degreasing contraction rates of associated component parts.

Abstract: A gas sensor element which may be employed in measuring the concentration of gas such O2 is provided. The gas sensor element is of a laminated type and designed to introduce gas to be measured into a measurement gas chamber through a diffusion resistor. The measurement gas chamber has a volume of 0.15 mm3 in order to facilitate expelling of the gas remaining within the measurement gas chamber during transition of thermal activation of the gas sensor element.

Abstract: A laminated gas sensor includes a solid electrolyte layer, a measurement gas chamber, a reference gas chamber, a measurement gas chamber formation layer, and a reference gas chamber formation layer. The measurement gas chamber formation layer has an opposite pair of inner side surfaces that extend in a longitudinal direction of the solid electrolyte layer and face each other in a lateral direction of the solid electrolyte layer through the measurement gas chamber. The reference gas chamber formation layer has an opposite pair of inner side surfaces that extend in the longitudinal direction and face each other in the lateral direction through the reference gas chamber. Further, at least one of the inner side surfaces of the measurement gas chamber formation layer is located more inside the laminated gas sensor than a corresponding one of the inner side surfaces of the reference gas chamber formation layer in the lateral direction.

Abstract: A gas sensor and method of manufacturing the gas sensor are disclosed. The gas sensor comprises a gas sensing element, an insulating element holder having an element inserting bore through which the gas sensing element axially extends, a housing fixedly supporting the insulating element holder, an airtight sealant and a cushioning filler. Ceramic slurry, composed of at least ceramic powder and binder, is filled in an area between the gas sensing element and the insulating element holder on a leading end portion of the element inserting bore and fired to form a cushioning filler. The ceramic slurry contains 47 to 53 wt % of ceramic solids for a gross weight of ceramic slurry and a binder laying in a value ranging from 5 to 10 wt % for a weight of the ceramic solids.

Abstract: A gas sensor element and related manufacturing method are disclosed comprising the steps of preparing a gas sensor element body, including a solid electrolyte body having both sides formed with a measuring-gas-side electrode and a reference-gas-side electrode, respectively, and a diffusion resistance layer formed the solid electrolyte body so as to surround the measuring-gas-side electrode, coating a trap layer forming slurry, having an aluminum ion content equal to or less than 1.2 wt %, on at least an outer sidewall of the difflusion resistance layer of the gas sensor element body, and baking a coated layer of the trap layer forming slurry to form a trap layer on the outer sidewall of the diffusion resistance layer.

Abstract: A ceramic laminate body, a gas sensor element employing such a ceramic laminate body and related manufacturing method are disclosed as including first and second ceramic sheets, made of material compositions different from each other, and an intermediate bonding layer, bonding the first and second ceramic sheets to each other so as to form a closed hollow space between the first and second ceramic sheets. The intermediate bonding layer has a multilayer structure including first and second unit intermediate layers laminated on each other such that innermost end portions of the first and second unit intermediate layers are displaced from each other to adapt a difference in degreasing contraction rates of associated component parts.

Abstract: A gas sensing member has a unit structure and a porous protective layer disposed on the unit structure. The unit structure has a solid electrolyte body, a gas measurement electrode disposed on a surface of the body and exposed to a measured gas entering at a gas inlet, a reference gas electrode disposed on another surface of the body and exposed to a reference gas, and a heater disposed close to the body. The heater has a heater substrate and heating elements disposed in the heater substrate. The heating elements heat the body. The heater substrate has side corner areas placed on side corners of the unit structure and being adjacent to the heating elements. The protective layer is disposed on the gas inlet such that the side corner areas are not covered with the protective layer and are directly exposed to the measured gas.

Abstract: A method of producing a ceramic raw material has steps of adding water into ceramic particles in order to produce a ceramic particle dispersed liquid, adding water into resin component in order to produce a resin component dispersed liquid, mixing the ceramic particle dispersed liquid and the resin component dispersed liquid in order to produce a mixed slurry, and freezing and drying the mixed slurry. In particular, the method further has filtering the ceramic particle dispersed liquid and the resin component dispersed liquid to eliminate coarse particles of not less than 100 ?m from each liquid. Further, a method of producing a ceramic molded body has steps of adding water into the above ceramic raw material and then extruding the mixed material by applying a pressure of a range of 1 to 50 MPa.

Abstract: A multilayered gas sensing element 2 is positioned in a cylindrical housing 10 via a cylindrical insulator 3. The multilayered gas sensing element 2 includes a narrow-width portion 21 and a wide-width portion 22. The wide-width portion 22 is in a fixed relationship with respect to the insulator 3. The narrow-width portion 21 is in a floating relationship with respect to the insulator 3. The narrow-width portion 21 has a gas sensing portion for detecting the concentration of a specific gas contained in a measuring objective gas.

Abstract: A gas sensor element which may be employed in measuring the concentration of gas such O2, NOx, or CO. The gas sensor element consists of an electrochemical cell made up of a solid electrolyte body formed by a partially stabilized zirconia and a pair of electrodes disposed on the solid electrolyte body. The electrochemical cell is subjected to an aging treatment in which the dc current is applied to the electrodes at a given voltage to enhance the activation of the electrochemical cell.

Abstract: A gas sensor element includes a solid electrolyte plate, a measurement gas-exposed and reference gas-exposed electrodes affixed the solid electrolyte plate to define a sensing portion, and a heater. The heater includes a heating element attached to a heater substrate in a given pattern which has a heating area S1. The solid electrolyte plate has a sensing area S2 in which the sensing portion is provided. The areas S1 and S2 are selected to meet a relation of S2/S1?0.9, thereby ensuring the heating efficiency of the heater without sacrificing a minimum required size of the area S1 of the solid electrolyte plate or a desired mechanical strength of the gas sensor element.

Abstract: A heater substrate contains insulating ceramic. Each of first and second solid electrolytic substrates contains first and second components. A thermal expansion coefficient of the second component is different from a thermal expansion coefficient of the insulating ceramic by an amount equal to or less than 2.0×10?6° C.?1. A second component content of the first solid electrolytic substrate is different from an insulating ceramic content of the heater substrate by an amount equal to or less than 90 wt. %. A second component content of the second solid electrolytic substrate is different from the second component content of the first solid electrolytic substrate by an amount equal to or greater than 10 wt. %. The second component content of the first or second solid electrolytic substrate is equal to or less than 80 wt. %.

Abstract: A multilayered gas sensing element includes a sensor cell and a ceramic heater which are integrally laminated. The sensor cell has a solid electrolytic substrate containing an electrolytic component serving as a main component of the ionic conductive solid electrolyte. The ceramic heater has a heater substrate containing the insulating ceramic as a main component. The solid electrolytic substrate includes a first electrolytic layer containing the insulating ceramic at a position closest to the ceramic heater, and a second electrolytic layer whose insulating ceramic content is smaller than that of the first electrolytic layer.