Abstract: An optical article comprising a primary mark disposed on the optical article and a secondary mark disposed on the optical article in close proximity to the primary mark. The primary mark comprises a first optical-state change material and the secondary mark comprises a second optical-state change material. The optical article is transformed from a pre-activated state to an activated state when a localized authorized activation method is used that selectively activates the primary mark. The optical article is transformed from a pre-activated state to an deactivated state when a non-localized unauthorized activation method is used that activates the secondary mark along with the primary mark resulting in the second optical-state change material undergoing a reverse color change when compared to the first optical-state change material. An optical article with a single mark including multiple color change optical-state change material is also disclosed.

Abstract: Methods for applying sensor materials to optical storage media substrates are disclosed. After exposure to a sample of interest, the resulting sensors may be read in optical storage media drives for quantitative analysis of physical, chemical and biological parameters of the sample.

Abstract: A method of printing comprising, placing a plurality of optically detectable marks on an optical article using a ink-jet printing method, wherein a mark of the plurality of marks has a thickness of less than or equal to about 1 micrometer, and wherein the plurality of optically detectable marks have uniform thickness.

Abstract: An optical article for playback in a player includes at least one sector comprising a first control logic configured to set the value of a first register, the first register having a default value before it is set, and a non-default value after it is set, and a first command to be read sequentially after the sector. The first command is configured to direct the player to play a first content on the article if the first register is set to the default value and to direct the player to play a second content on the article if the first register is set to the non-default value. The optical article includes a mark containing an optical state change material disposed on the sector, wherein the mark is in one of a first optical state or a second optical state, and wherein the first control logic can be read only when the mark is in the second optical state.

Abstract: An optical article for playback in a player includes a first file comprising a first control logic; and a second file comprising a second control logic. The first file is configured to direct the player to play a first content data stored on the optical article, when the first control logic is read by the player. The player is directed to read the second file if the player cannot read the first file. The second file is configured to direct the player to play a second content data stored on the article when the second control logic is read by the player. The optical article includes a mark containing an optical state change material disposed on at least a portion of the first file, wherein the mark is in one of a first optical state or a second optical state, and wherein the first control logic can be read only when the mark is in the second optical state.

Abstract: An optical article with a plurality of optically detectable marks on a first surface of the optical article, wherein a mark of the plurality of marks has a thickness of less than or equal to about 1 micrometer, and wherein the plurality of optically detectable marks have uniform thickness.

Abstract: A method for imparting tags to a media article, comprising: modifying predetermined locations on the article to change a surface energy of the predetermined locations, applying the tags to a surface of the article, and retaining the tags in the modified predetermined locations while the tags are removed from unmodified regions.

Abstract: A thermochromic ink composition comprises at least one thermochromic optical-state change material, at least one thermally responsive pH modifier, at least one solvent, and at least one binder material, wherein the thermochromic ink composition has a viscosity between about 0.1 centipoise (cPs) and about 10,000 cps, and a maximum optical absorbance in a range from about 200 nm (nanometers) to about 800 nm, and wherein the thermochromic ink composition is capable of transforming from a first optical state to a second optical state upon exposure to a thermal stimulus. The thermochromic ink composition may be used to deposit a thermochromic coating composition which may be used as part of an anti-theft system for optical articles. Methods for thermal activation of the compositions are also provided.

Abstract: A media can comprise: a reflective layer, an oxygen penetrable UV coating, and a reactive layer disposed between the UV coating and the reflective layer. The reactive layer can comprise a reactive material that oxidizes with exposure to oxygen.

Abstract: A limited play optical storage medium for data is described which comprises a first substrate, a reflective layer, a data layer disposed between said substrate and said reflective layer; a reactive layer comprising at least one carrier, and at least one reactive material, and an optically transparent second substrate comprised of a polymethacrylate copolymer or blend comprising a polymethacrylate copolymer or homopolymer. The second substrate is disposed between the reactive layer and a laser incident surface and is tailored to provide an oxygen permeability in a range between about 0.1 Barrers and about 1.35 Barrers at 25° C.

Abstract: The present invention provides a formulation for a reactive dye layer for a limited-play optical storage medium, the reactive formulation including at least one carrier material or curable acrylate monomer, at least one reactive material disposed within the carrier material or acrylate monomer, and at least one photo-bleaching retarder material disposed within the at least one adhesive material. The at least one photo-bleaching retarder material includes at least one polymeric polyhydroxy compound selected from the group consisting of polyhydroxystyrenes, cellulose, and functionalized cellulose derivatives.

Abstract: The present disclosure relates to a limited play optical storage media and a method for limiting access to data thereon. This storage media includes a first substrate; a reflective layer; a data storage layer disposed between said first substrate and said reflective layer; a reactive layer comprising at least one reactive material disposed on said at least one reflective layer; an optically transparent second substrate disposed between the reactive layer and a laser incident surface of the optical storage media; and an oxygen permeable barrier layer disposed between the reactive layer and a laser incident surface of the optical storage media, said reactive layer having an initial percent reflectivity of about 50% or greater and a percent reflectivity of about 45% or less after exposure to oxygen.

Abstract: An authenticable optical disc and a system and method for authenticating the optical disc are provided. The optical disc comprising a reflective layer; an optically transparent substrate disposed between the reflective layer and a light incident surface of the optical disc; a data layer disposed between the substrate and the reflective layer, the data layer including a predetermined signature; and at least one measurable feature, wherein the at least one feature is compared to the predetermined signature for authenticating the optical disc. The method comprises the steps of preparing an optical disc with at least one optical feature; measuring intensity of transmitted light from the at least one optical feature; and comparing the measured intensity to a predetermined signature, wherein if the measured intensity and predetermined signature matches, access to the optical disc is granted.

Abstract: An authentication system may comprise: a first light source, a second light source, and at least three optically filtered light sensing devices. The first light source can have a first light source spectral distribution and can be capable of providing sufficient excitation to produce a photoluminescent emission from a medium comprising a luminescent tag and a color. The second light source can have a visible multi-wavelength spectral distribution and can be capable of providing sufficient visible multi-wavelength illumination of the medium to generate a second analog response. Each light sensing device can have a different device spectral sensitivity range.

Abstract: A system and method employing optical disc drives for quantitative analysis of physical, chemical and biochemical parameters are provided. The system including a disc drive for supporting and rotating an optical disc including at least one sensor spot; a light source for directing light onto the sensor spot; at least one optical pickup for detecting light transmitted from the sensor spot, the transmitted light being indicative of a concentration of a compound; and an analog-to-digital converter for quantifying an intensity of the transmitted light. The method comprising the steps of preparing the optical disc with a plurality of sensor spots, the sensor spots being responsive to a compound; exposing the optical disc to a fluid; measuring intensity of transmitted light from at least one of the plurality of sensor spots; and correlating the measured intensity of transmitted light to an amount of compound exposed to the optical disc.

Abstract: Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4?-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.

Abstract: The present disclosure relates to a limited play optical storage media and a method for limiting access to data thereon. This storage media comprises: an optically transparent substrate; a reflective layer; an oxygen penetrable UV coating disposed on a side of the substrate opposite the reflective layer; and a reactive layer disposed between the UV coating and the substrate, the optical storage media having an initial percent reflectivity of about 50% or greater and a subsequent percent reflectivity of about 45% or less.

Abstract: The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as ?-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.

Abstract: The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as ?-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.

Abstract: The invention relates to transparent blends of polymers suitable for use in optical articles; the polymers contain residues of BCC and its derivatives, and have properties particularly suited for use in high density optical data storage media. The polymers further contain residues of other polymers, such as ?-methyl polystyrene and polystyrene derivatives; bisphenols, such as bisphenol A; cycloaliphatic polyester resins, such as PCCD and its derivatives or some combination of each.