Abstract: A coated composite electrode for supporting an anodic electrochemical reaction includes a substrate composed of an electrically conductive metal and a mixture composed of lead and manganese oxides of between about 70 and 90 weight percent and of binders and extenders together being of between about 10 and 30 weight percent. The mixture is in the form of a coating on the substrate which constitutes a site of electrochemical oxidation. The coating is pressed above about 1500 psi pressure and at a temperature within the range of about 25 to 230 degrees C. The composite electrode provides corrosion inhibition for the lead alloy and improved current efficiency in systems with iron, such as copper electrowinning.

Abstract: A composite electrode for supporting an anodic or cathodic electrochemical reaction such as occurs during a metal electrowinning process has a composition which includes between 90 and 95 weight percent of an electrically conductive metal compound and between 5 and 10 weight percent of a polymeric binder material blended with the conductive metal compound. The composite electrode is formed under a maximum pressure of 2.5 metric tons per square centimeter and at a temperature between ambient and 140 degrees C.

Abstract: An improved method for recovering lead sulfides from a mineral deposits. Pulverized mineral deposit material is mixed with water, agitated with pH adjustment from about 8 to about 10.5 to form a slurry. Rapeseed oil is added to the conditioned slurry to render the surface of the lead sulfide particles hydrophobic. After agitating and adding a frothing agent, air bubbles are injected into the resultant composition to cause hydrophobic lead sulfide particles to become attached to the air bubbles and to rise and form a froth fraction which is then separated and recovered. The process uses substantially non-toxic rapeseed oil as a hydrophilizing agent. The process is less environmentally damaging, less costly and more specific in separating lead sulfides from iron containing minerals which are normally present in ores together with the lead sulfides.