Abstract: Processes and apparatuses for benzene and/or toluene methylation under conditions of low temperatures in one of a vapor phase, a liquid phase or a mixed vapor-liquid phase, in an aromatics complex for producing para-xylene are described. More specifically, a process for producing a xylene isomer comprising reacting oxygenates with an aromatic feedstock comprising toluene and/or benzene in a methylation zone operating under alkylation conditions including one of a vapor, a liquid phase or a mixed vapor-liquid phase in the presence of a catalyst to provide a product stream comprising the xylene isomer is described.

Abstract: This present disclosure relates to processes and apparatuses for benzene and/or toluene methylation under conditions of low temperatures in one of a vapor phase, a liquid phase or a mixed vapor-liquid phase, in an aromatics complex for producing para-xylene. More specifically, the present disclosure relates to a process is provided for producing a xylene isomer comprising reacting oxygenates with an aromatic feedstock comprising toluene and/or benzene in a methylation zone operating under alkylation conditions including one of a vapor, a liquid phase or a mixed vapor-liquid phase in the presence of a catalyst to provide a product stream comprising the xylene isomer.

Abstract: One exemplary embodiment can be a process for reducing one or more insoluble solids in a black liquor. The process may include hydrothermal processing the black liquor to a temperature of about 250-less than about 300° C. for an effective time to reduce the one or more insoluble solids by more than about 40%, by weight, based on a weight of the one or more insoluble solids prior to hydrothermal processing.

Abstract: A process for the conversion of lignin to chemical precursors is presented. The process comprises treating the lignin to form less acidic compounds. The process includes reacting lignin with a hydrogenation catalyst under a hydrogen atmosphere to convert acidic oxygenate compounds to less acidic oxygenates or hydrocarbons. The oxygenate compounds are reacted in a dehydrogenation and deoxygenation process to remove the oxygen and to convert the cyclic hydrocarbons back to aromatic compounds.

Abstract: One exemplary embodiment can be a process for reducing one or more insoluble solids in a black liquor. The process may include hydrothermal processing the black liquor to a temperature of about 250-less than about 300° C. for an effective time to reduce the one or more insoluble solids by more than about 40%, by weight, based on a weight of the one or more insoluble solids prior to hydrothermal processing.

Abstract: Methods for producing phase stable, reduced acid biomass-derived pyrolysis oils are provided. Biomass-derived pyrolysis oil having a determined water content no greater than about 30% by weight is provided. A base is mixed with the biomass-derived pyrolysis oil to produce reduced acid biomass-derived pyrolysis oil. A base is selected from an inorganic base or a nitrogen-containing base.

Abstract: A process for the conversion of lignin to chemical precursors is presented. The process comprises treating the lignin to form less acidic compounds. The process includes reacting lignin with a hydrogenation catalyst under a hydrogen atmosphere to convert acidic oxygenate compounds to less acidic oxygenates or hydrocarbons. The oxygenate compounds are reacted in a dehydrogenation and deoxygenation process to remove the oxygen and to convert the cyclic hydrocarbons back to aromatic compounds.

Abstract: A system for recovering and purifying water from a gas stream may include, a gas stream purification unit for purifying the gas stream, a water separation unit for separating water from the purified gas stream, and a water purification unit for purifying the water separated by the water separation unit. The gas stream purification unit may include comprise a soot reactor and a catalytic oxidation reactor or both. The water separation unit may include a condenser, a water extractor and a cyclic reverse osmosis system.

Abstract: Systems and methods for recovering and purifying water from a gas stream, comprising a gas stream purification unit for purifying the gas stream, a water separation unit for separating water from the purified gas stream, and a water purification unit for purifying the water separated by the water separation unit. The gas stream purification unit may comprise at least one of a soot reactor and a catalytic oxidation reactor, the water separation unit may comprise at least one of a condenser and a water extractor, and the water purification unit may comprise a cyclic reverse osmosis system.

Abstract: A method for converting Explosive D, i.e., ammonium picrate to oxygenated products, particularly hydroquinone or cyclohexanediol and ammonia by hydrogenation over a supported Group VIII metal catalyst. Preferably, the ammonium picrate is dissolved in a suitable solvent and then hydrogenated at a temperature of about 25.degree. to 250.degree. C., and a pressure of about 10 to 1000 psig (69 to 6900 kPa gauge) followed by separation of the commercially valuable products and ammonia.

Abstract: A method for converting hydrazine and/or substituted hydrazines, particularly unsymmetric dimethyl hydrazine (UDMH), to ammonia or ammonia and the corresponding amines by hydrogenation over a supported Group VIII metal catalyst. Preferably, the hydrazines are dissolved in a suitable solvent and then hydrogenated at a temperature of about 0.degree. to 250.degree. C., followed by separation of the commercially valuable ammonia and amines. Alternatively, a gas phase reaction may be used.

Abstract: A method for converting hydrazine and/or substituted hydrazines, particularly unsymmetric dimethyl hydrazine (UDMH), to ammonia or ammonia and the corresponding amines by hydrogenation over a supported Group VIII metal catalyst. Preferably, the hydrazines are dissolved in a suitable solvent and then hydrogenated at a temperature of about 0.degree. to 250.degree. C., followed by separation of the commercially valuable ammonia and amines. Alternatively, a gas phase reaction may be used.

Abstract: A large class of crosslinked cyclodextrin resins soluble in water to an extent under about 200 ppm but soluble in an organic solvent to an extent of at least 0.1 weight percent have good film-forming properties with a wide variety of solid phase substrates. The films exhibit excellent adhesive properties toward virtually all solid surfaces which consequently can be readily coated with a thin film having a multiplicity of cyclodextrin moieties available at the surface for seperation and/or purification. Such coated substrates can be prepared in a variety of sizes, shapes, and cyclodextrin loading quite conveniently and relatively inexpensively.

Abstract: Resins resulting from the crosslinking of cyclodextrin with dicarboxylic acid dihalides often show marginal binding capacity for guest molecules and poor kinetics of guest molecule removal because of the limited porosity of the resins. Resins whose apparent bulk density has been reduced by at least 20% show an enhancement in both of the aforementioned properties resulting from an increase in porosity of the resins. Such resins in general can be formed by conducting the crosslinking reaction in the presence of a blowing agent. The resulting materials retained their desirable physical properties for use in a fixed or packed bed.

Abstract: Composites on a porous support of an insolubilized, crosslinked cyclodextrin show improved mass transfer characteristics relative to discrete particles of the same insolubilized cyclodextrin. Dicarboxylic acid dihalides are particularly effective crosslinking agents. The composites can be prepared quite simply and cost effectively by impregnating a support, such as alumina, with a cyclodextrin, then reacting the cyclodextrin within the impregnated support with a suitable dicarboxylic acid dihalide, such as one from the alkane dicarboxylic acid series containing from 4 through 12 carbon atoms.

Abstract: A multiple sensor which can be readily inserted into, and removed from a radial arterial cannula for use in continuous in vivo patent monitoring includes a plurality of individual sensors, each sensor including a sensing element disposed on an optical waveguide, the sensors being bonded together by an adhesive without covering the sensing elements.

Abstract: A multiple sensor which can be readily inserted into, and removed from a radial arterial cannula for use in continuous in vivo patent monitoring includes a plurality of individual sensors, each sensor including a sensing element disposed on an optical waveguide, the sensors being bonded together by an adhesive without covering the sensing elements.

Abstract: An adjustable arm includes a base member with a base rotatable joint member connected thereto, a lower arm having one end connected to the base rotatable joint member with a central joint member connected to the other end thereof and also to one end of an upper arm while a head joint member is connected to the other end of the upper arm. An elongated means under tension is provided within the arms and about the joint members for maintaining the position of the head end in given angular position.