Patents by Inventor Martin Dexter

Martin Dexter has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4902734
    Abstract: Acid-curable thermoset enamel compositions coming in contact with copper or copper-containing alloys are discolored and degrade more rapidly due to leaching of copper into the compositions. The presence of small amounts of benzotriazole or tolutriazole effectively prevents the discoloration and concomitantly retards degradation.
    Type: Grant
    Filed: August 10, 1987
    Date of Patent: February 20, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Rudolf A. Behrens
  • Patent number: 4724248
    Abstract: Esters and urethanes of certain polydialkylsiloxanepolyoxyalkylene block and graft copolymers which impart high voltage stabilization to dielectric olefin polymers, the stabilized olefin polymer insulating materials resulting therefrom and electric wire or cable insulated therewith.
    Type: Grant
    Filed: July 2, 1986
    Date of Patent: February 9, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, David H. Steinberg
  • Patent number: 4689362
    Abstract: Insulating material for electric wire and cable which consists of an olefin polymer stabilized against electrical failure resulting from voltage stress by the presence therein of a polydialkylsiloxanepolyoxyalkylene block or graft copolymer, the electric wire coated with said insulating material and a method for stabilizing said insulation.
    Type: Grant
    Filed: July 2, 1986
    Date of Patent: August 25, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Martin Dexter
  • Patent number: 4618638
    Abstract: Alpha-cyanocinnamate ultraviolet-absorbing stabilizers of the formula ##STR1## Where T is alkyl of 4 to 14 carbon atoms, and R.sub.4 is alkyl of 1 to 4 carbon atoms, are particularly resistant to loss during weathring of outdoor thermoset or thermoplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: November 23, 1984
    Date of Patent: October 21, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4544691
    Abstract: Ultraviolet-absorbing stabilizers of the formula E--(G--R).sub.n, L--(G--E).sub.m, or [G--E.sub.1 --G--Q].sub.p where E is a radical derived from an oxanilide, benzalmalonate, .alpha.-cyanocinnamate or o-hydroxyphenylbenzotriazole, E.sub.1 is a radical derived from an oxanilide, G is --OCH.sub.2 CHOH--, R is alkyl, phenyl or --CH.sub.2 OT where T is alkyl or alkenyl, n is 1 or 2, m is 2 or 3, L is a direct bond, alkylene or other bis or tris radical, Q has the same meaning as L when m is 2, and p is 1 to 4, are particularly resistant to loss during weathering of outdoor thermoset or theromplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: June 20, 1983
    Date of Patent: October 1, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4504419
    Abstract: Alpha-cyanocinnamate ultraviolet-absorbing stabilizers of the formula ##STR1## where T is alkyl of 4 to 14 carbon atoms, and R.sub.4 is alkyl of 1 to 4 carbon atoms, are particularly resistant to loss during weathering of outdoor thermoset or thermoplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: March 12, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4496676
    Abstract: Ultraviolet-absorbing stabilizers of the formula E-(G-R).sub.n, L-(G-E).sub.m, or [G-E.sub.1 -G-Q].sub.p where E is a radical derived from an oxanilide, benzalmalonate, .alpha.-cyanocinnamate or o-hydroxyphenylbenzotriazole, E.sub.1 is a radical derived from an oxanilide, G is --OCH.sub.2 CHOH--, R is alkyl, phenyl or --CH.sub.2 OT where T is alkyl or alkenyl, n is 1 or 2, m is 2 or 3, L is a direct bond, alkylene or other bis or tris radical, Q has the same meaning as L when m is 2, and p is 1 to 4, are particularly resistant to loss during weathering of outdoor thermoset or thermoplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: January 29, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4496757
    Abstract: Ultraviolet-absorbing stabilizers of the formula E-(G-R).sub.n, L-(G-E).sub.m, or [G-E.sub.1 -G-Q].sub.p where E is a radical derived from an oxanilide, benzalmalonate, .alpha.-cyanocinnamate or o-hydroxphenylbenzotriazole, E.sub.1 is a radical derived from an oxanilide, G is --OCH.sub.2 CHOH--, R is alkyl, phenyl or --CH.sub.2 OT where T is alkyl or alkenyl, n is 1 or 2, m is 2 or 3, L is a direct bond, alkylene or other bis or tris radical, Q has the same meaning as L when m is 2, and p is 1 to 4, are particularly resistant to loss during weathering of outdoor thermoset or thermoplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: January 29, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4477614
    Abstract: 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.
    Type: Grant
    Filed: April 12, 1982
    Date of Patent: October 16, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4447511
    Abstract: 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.This stabilizer and its 5-chloro analog exhibit great resistance to volatilization, enhanced solubility in selected solvents, desirable absorption characteristics in the ultraviolet range and photographic inertness. This combination of properties makes these benzotriazoles particularly useful in photographic compositions especially in protecting color dye images against the harmful effects of ultraviolet light.
    Type: Grant
    Filed: January 10, 1983
    Date of Patent: May 8, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4414393
    Abstract: Ultraviolet-absorbing stabilizers of the formula E-(G-R).sub.n, L-(G-E).sub.m, or [G-E.sub.1 -G-Q].sub.p where E is a radical derived from an oxanilide, benzalmalonate, .alpha.-cyanocinnamate or o-hydroxyphenylbenzotriazole, E.sub.1 is a radical derived from an oxanilide, G is --OCH.sub.2 CHOH--, R is alkyl, phenyl or --CH.sub.2 OT where T is alkyl or alkenyl, n is 1 or 2, m is 2 or 3, L is a direct bond, alkylene or other bis or tris radical, Q has the same meaning as L when m is 2, and p is 1 to 4, are particularly resistant to loss during weathering of outdoor thermoset or thermoplastic coating systems while exhibiting good stabilization efficacy and compatibility in said systems.
    Type: Grant
    Filed: November 5, 1981
    Date of Patent: November 8, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4383863
    Abstract: 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.This stabilizer and its 5-chloro analog exhibit great resistance to volatilization, enhanced solubility in selected solvents, desirable absorption characteristics in the ultraviolet range and photographic inertness. This combination of properties makes these benzotriazoles particularly useful in photographic compositions especially in protecting color dye images against the harmful effects of ultraviolet light.
    Type: Grant
    Filed: March 6, 1981
    Date of Patent: May 17, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4374219
    Abstract: The title compounds are prepared by reacting alkylated 1,1'-biphenyl-2,2'-diol or alkylated 2,2'-alkylidene-bis-phenol with phosphorus trichloride in an organic solvent and then reacting the intermediate phosphorochlorodite with an alkanolamine. Said phosphites are useful as stabilizers of organic polymers and lubricating oils, especially as processing stabilizers for polyolefins, elastomers, polyesters and polycarbonates.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: February 15, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Spivack, Martin Dexter, Stephen D. Pastor
  • Patent number: 4347180
    Abstract: Substituted 2-nitro-2'-hydroxyazobenzenes are prepared by adding an aqueous mineral acid solution of a diazotized o-nitroaniline to a strongly alkaline lower alkanol or aqueous lower alkanol solution of a substituted phenol, containing sufficient alkali metal hydroxide to assure a pH value substantially over 11 and an excess of hydroxyl ion in the reaction mixture even after all the acidic diazonium salt solution is added, wherein the reaction solvent mixture is at least 50% by weight of lower alkanol, at a reaction temperature between -15.degree. C. and +30.degree. C.The o-nitroazobenzenes obtained are intermediate products useful in the manufacture of benzotriazole UV absorbers.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: August 31, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Martin Dexter
  • Patent number: 4318845
    Abstract: The title compounds are prepared by reacting alkylated 1,1'-biphenyl-2,2'-diol or alkylated 2,2'-alkylidene-bis-phenol with phosphorus trichloride in an organic solvent and then reacting the intermediate phosphorochlorodite with an alkanolamine. Said phosphites are useful as stabilizers of organic polymers and lubricating oils, especially as processing stabilizers for polyolefins, elastomers, polyesters and polycarbonates.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: March 9, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Spivack, Martin Dexter, Stephen D. Pastor
  • Patent number: 4315848
    Abstract: 2-[2-Hydroxy-3,5-di-(.alpha.,.alpha.-dimethylbenzyl)phenyl]-2H-benzotriazol e exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions. The combination of the benzotriazole UV absorber with a hindered amine light stabilizer is particularly efficacious in protecting thermoset and thermoplastic acrylic resin automotive finishes and enamels.
    Type: Grant
    Filed: October 1, 1980
    Date of Patent: February 16, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4283327
    Abstract: 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.
    Type: Grant
    Filed: August 20, 1979
    Date of Patent: August 11, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4278590
    Abstract: 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.The combination of the benzotriazole UV absorber with a hindered amine light stabilizer is particularly efficacious in protecting thermoset and thermoplastic acrylic resin automotive finishes and enamels.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: July 14, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4278589
    Abstract: 2-[2-Hydroxy-3,5-di-(.alpha.,.alpha.-dimethylbenzyl)phenyl]-2H-benzotriazol e exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions. The combination of the benzotriazole UV absorber with a hindered amine light stabilizer is particularly efficacious in protecting thermoset and thermoplastic acrylic resin automotive finishes and enamels.
    Type: Grant
    Filed: May 10, 1979
    Date of Patent: July 14, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Dexter, Roland A. E. Winter
  • Patent number: 4275004
    Abstract: Substituted 2-nitro-2'hydroxyazobenzenes are prepared by adding an aqueous mineral acid solution of a diazotized o-nitroaniline to a strongly alkaline lower alkanol or aqueous lower alkanol solution of a substituted phenol, containing sufficient alkali metal hydroxide to assure a pH value substantially over 11 and an excess of hydroxyl ion in the reaction mixture even after all the acidic diazonium salt solution is added, wherein the reaction solvent mixture is at least 50% by weight of lower alkanol, at a reaction temperature between -15.degree. C. and +30.degree. C.The o-nitroazobenzenes obtained are intermediate products useful in the manufacture of benzotriazole UV absorbers.
    Type: Grant
    Filed: May 16, 1979
    Date of Patent: June 23, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Martin Dexter