Patents by Inventor Masaharu Nakazawa
Masaharu Nakazawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11028199Abstract: The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of —SO2Y, —COOR, —SO3X, —SO2NR12, and —COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M1/L or NR14, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 ?m.Type: GrantFiled: October 11, 2017Date of Patent: June 8, 2021Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuki Yotsumoto, Tadashi Ino, Kazuhiro Ohtsuka, Noriyuki Shinoki, Masaharu Nakazawa, Takashi Yoshimura, Masahiro Kondo
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Patent number: 10988559Abstract: The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of —SO2Y, —COOR, —SO3X, —SO2NR12, and —COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M1/L or NR14, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 ?m.Type: GrantFiled: October 11, 2017Date of Patent: April 27, 2021Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuki Yotsumoto, Tadashi Ino, Kazuhiro Ohtsuka, Noriyuki Shinoki, Masaharu Nakazawa, Takashi Yoshimura, Masahiro Kondo
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Publication number: 20190375866Abstract: The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of —SO2Y, —COOR, —SO3X, —SO2NR12, and —COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M1/L or NR14, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 ?m.Type: ApplicationFiled: October 11, 2017Publication date: December 12, 2019Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Yuki YOTSUMOTO, Tadashi INO, Kazuhiro OHTSUKA, Noriyuki SHINOKI, Masaharu NAKAZAWA, Takashi YOSHIMURA, Masahiro KONDO
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Patent number: 9627702Abstract: A method for producing an electrolyte emulsion, the method including: Step (1) in which an ethylenic fluoromonomer and a fluorovinyl compound having an SO2Z1 group, wherein Z1 is a halogen element, are copolymerized at a polymerization temperature of 0° C. or higher and 40° C. or lower to provide a precursor emulsion containing a fluoropolymer electrolyte precursor; and Step (2) in which a basic reactive liquid is added to the precursor emulsion and the fluoropolymer electrolyte precursor is chemically treated, whereby an electrolyte emulsion with a fluoropolymer electrolyte dispersed therein is provided, wherein the electrolyte emulsion has an equivalent weight (EW) of 250 or more and 700 or less.Type: GrantFiled: June 24, 2016Date of Patent: April 18, 2017Assignees: ASAHI KASEI KABUSHIKI KAISHA, DAIKIN INDUSTRIES, LTD.Inventors: Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Masaharu Nakazawa, Noriyuki Shinoki, Takashi Yoshimura, Masahiro Kondo
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Publication number: 20160308232Abstract: A method for producing an electrolyte emulsion, the method including: Step (1) in which an ethylenic fluoromonomer and a fluorovinyl compound having an SO2Z1 group, wherein Z1 is a halogen element, are copolymerized at a polymerization temperature of 0° C. or higher and 40° C. or lower to provide a precursor emulsion containing a fluoropolymer electrolyte precursor; and Step (2) in which a basic reactive liquid is added to the precursor emulsion and the fluoropolymer electrolyte precursor is chemically treated, whereby an electrolyte emulsion with a fluoropolymer electrolyte dispersed therein is provided, wherein the electrolyte emulsion has an equivalent weight (EW) of 250 or more and 700 or less.Type: ApplicationFiled: June 24, 2016Publication date: October 20, 2016Applicants: ASAHI KASEI KABUSHIKI KAISHA, DAIKIN INDUSTRIES, LTD.Inventors: Takahiko MURAI, Naoki SAKAMOTO, Naoto MIYAKE, Tadashi INO, Masaharu NAKAZAWA, Noriyuki SHINOKI, Takashi YOSHIMURA, Masahiro KONDO
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Patent number: 9406958Abstract: The present invention provides a fluoropolymer electrolyte material which has improved processability and which is easily produced. The electrolyte emulsion of the present invention comprises an aqueous medium and a fluoropolymer electrolyte dispersed in the aqueous medium. The fluoropolymer electrolyte has a monomer unit having an SO3Z group (Z is an alkali metal, an alkaline-earth metal, hydrogen, or NR1R2R3R4, and R1, R2, R3, and R4 each are individually a C1-C3 alkyl group or hydrogen). The fluoropolymer electrolyte has an equivalent weight (EW) of 250 or more and 700 or less and a proton conductivity at 110° C. and relative humidity 50% RH of 0.10 S/cm or higher. The fluoropolymer electrolyte is a spherical particulate substance having an average particle size of 10 to 500 nm. The fluoropolymer electrolyte has a ratio (the number of SO2F groups)/(the number of SO3Z groups) of 0 to 0.01.Type: GrantFiled: August 10, 2015Date of Patent: August 2, 2016Assignees: ASAHI KASEI KABUSHIKI KAISHA, DAIKIN INDUSTRIES, LTD.Inventors: Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Masaharu Nakazawa, Noriyuki Shinoki, Takashi Yoshimura, Masahiro Kondo
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Publication number: 20150349366Abstract: The present invention provides a fluoropolymer electrolyte material which has improved processability and which is easily produced. The electrolyte emulsion of the present invention comprises an aqueous medium and a fluoropolymer electrolyte dispersed in the aqueous medium. The fluoropolymer electrolyte has a monomer unit having an SO3Z group (Z is an alkali metal, an alkaline-earth metal, hydrogen, or NR1R2R3R4, and R1, R2, R3, and R4 each are individually a C1-C3 alkyl group or hydrogen). The fluoropolymer electrolyte has an equivalent weight (EW) of 250 or more and 700 or less and a proton conductivity at 110° C. and relative humidity 50% RH of 0.10 S/cm or higher. The fluoropolymer electrolyte is a spherical particulate substance having an average particle size of 10 to 500 nm. The fluoropolymer electrolyte has a ratio (the number of SO2F groups)/(the number of SO3Z groups) of 0 to 0.01.Type: ApplicationFiled: August 10, 2015Publication date: December 3, 2015Applicants: DAIKIN INDUSTRIES, LTD., ASAHI KASEI E-MATERIALS CORPORATIONInventors: Takahiko MURAI, Naoki SAKAMOTO, Naoto MIYAKE, Tadashi INO, Masaharu NAKAZAWA, Noriyuki SHINOKI, Takashi YOSHIMURA, Masahiro KONDO
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Patent number: 9133316Abstract: The present invention provides a fluoropolymer electrolyte material which has improved processability and which is easily produced. The electrolyte emulsion of the present invention comprises an aqueous medium and a fluoropolymer electrolyte dispersed in the aqueous medium. The fluoropolymer electrolyte has a monomer unit having an SO3Z group (Z is an alkali metal, an alkaline-earth metal, hydrogen, or NR1R2R3R4, and R1, R2, R3, and R4 each are individually a C1-C3 alkyl group or hydrogen). The fluoropolymer electrolyte has an equivalent weight (EW) of 250 or more and 700 or less and a proton conductivity at 110° C. and relative humidity 50% RH of 0.10 S/cm or higher. The fluoropolymer electrolyte is a spherical particulate substance having an average particle size of 10 to 500 nm. The fluoropolymer electrolyte has a ratio (the number of SO2F groups)/(the number of SO3Z groups) of 0 to 0.01.Type: GrantFiled: September 17, 2010Date of Patent: September 15, 2015Assignees: ASAHI KASEI E-MATERIALS CORPORATION, DAIKIN INDUSTRIES, LTD.Inventors: Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Masaharu Nakazawa, Noriyuki Shinoki, Takashi Yoshimura, Masahiro Kondo
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Patent number: 8993682Abstract: The present invention provides an electrolyte having high conductivity even under high-temperature low-humidification conditions (e.g. at a temperature of 100 to 120° C. and a humidity of 20 to 50% RH) and thereby makes it possible to realize a higher performance fuel cell. The present invention is a fluoropolymer electrolyte having an equivalent weight (EW) of not less than 250 but not more than 700 and a proton conductivity of not lower than 0.10 S/cm as measured at a temperature of 110° C. and a relative humidity of 50% RH and comprising a COOZ group- or SO3Z group-containing monomer unit, wherein Z represents an alkali metal, an alkaline earth metal, hydrogen atom or NR1R2R3R4 in which R1, R2, R3 and R4 each independently represents an alkyl group containing 1 to 3 carbon atoms or hydrogen atom.Type: GrantFiled: March 12, 2009Date of Patent: March 31, 2015Assignees: Asahi Kasei E-Materials Corporation, Daikin Industries, Ltd.Inventors: Kohei Kita, Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Noriyuki Shinoki, Masaharu Nakazawa, Masahiro Kondo, Takashi Yoshimura
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Patent number: 8344192Abstract: The invention provides a technique enabling the separation and recovery of an unreacted fluoromonomer from an aqueous fluoropolymer dispersion obtained by emulsion polymerization, without using any extraction solvent, and enabling the prevention of a hydrolysis of —SO2F and a like sulfonic acid precursor functional group convertible to sulfonic acid group. Thus, the invention provides a recovering method fluoromonomer having a sulfonic acid precursor functional group convertible to a sulfonic acid group and remaining unreacted from an aqueous fluoropolymer dispersion obtained by emulsion polymerization of the fluoromonomer, wherein the unreacted fluoromonomer is recovered from the aqueous fluoropolymer dispersion by evaporation, wherein the aqueous fluoropolymer dispersion has an acidic pH.Type: GrantFiled: December 7, 2007Date of Patent: January 1, 2013Assignee: Daikin Industries, Ltd.Inventors: Tadaharu Isaka, Tadashi Ino, Masaharu Nakazawa, Masahiro Kondo
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Publication number: 20120178017Abstract: The present invention provides a fluoropolymer electrolyte material which has improved processability and which is easily produced. The electrolyte emulsion of the present invention comprises an aqueous medium and a fluoropolymer electrolyte dispersed in the aqueous medium. The fluoropolymer electrolyte has a monomer unit having an SO3Z group (Z is an alkali metal, an alkaline-earth metal, hydrogen, or NR1R2R3R4, and R1, R2, R3, and R4 each are individually a C1-C3 alkyl group or hydrogen). The fluoropolymer electrolyte has an equivalent weight (EW) of 250 or more and 700 or less and a proton conductivity at 110° C. and relative humidity 50% RH of 0.10 S/cm or higher. The fluoropolymer electrolyte is a spherical particulate substance having an average particle size of 10 to 500 nm. The fluoropolymer electrolyte has a ratio (the number of SO2F groups)/(the number of SO3Z groups) of 0 to 0.01.Type: ApplicationFiled: September 17, 2010Publication date: July 12, 2012Applicants: DAIKIN INDUSTRIES, LTD., ASAHI KASEI E-MATERIALS CORPORATIONInventors: Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Masaharu Nakazawa, Noriyuki Shinok, Takashi Yoshimura, Masahiro Kondo
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Publication number: 20110020728Abstract: The present invention provides an electrolyte having high conductivity even under high-temperature low-humidification conditions (e.g. at a temperature of 100 to 120° C. and a humidity of 20 to 50% RH) and thereby makes it possible to realize a higher performance fuel cell. The present invention is a fluoropolymer electrolyte having an equivalent weight (EW) of not less than 250 but not more than 700 and a proton conductivity of not lower than 0.10 S/cm as measured at a temperature of 110° C. and a relative humidity of 50% RH and comprising a COOZ group- or SO3Z group-containing monomer unit, wherein Z represents an alkali metal, an alkaline earth metal, hydrogen atom or NR1R2R3R4 in which R1, R2, R3 and R4 each independently represents an alkyl group containing 1 to 3 carbon atoms or hydrogen atom.Type: ApplicationFiled: March 12, 2009Publication date: January 27, 2011Applicants: Asahi Kasei E-Materials Corporation, Daikin Industries, Ltd.Inventors: Kohei Kita, Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Noriyuki Shinoki, Masaharu Nakazawa, Masahiro Kondo, Takashi Yoshimura
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Publication number: 20100048956Abstract: The invention provides a technique enabling the separation and recovery of an unreacted fluoromonomer from an aqueous fluoropolymer dispersion obtained by emulsion polymerization, without using any extraction solvent, and enabling the prevention of a hydrolysis of —SO2F and a like sulfonic acid precursor functional group convertible to sulfonic acid group. Thus, the invention provides a recovering method fluoromonomer having a sulfonic acid precursor functional group convertible to a sulfonic acid group and remaining unreacted from an aqueous fluoropolymer dispersion obtained by emulsion polymerization of the fluoromonomer, wherein the unreacted fluoromonomer is recovered from the aqueous fluoropolymer dispersion by evaporation, wherein the aqueous fluoropolymer dispersion has an acidic pH.Type: ApplicationFiled: December 7, 2007Publication date: February 25, 2010Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Tadaharu Isaka, Tadashi Ino, Masaharu Nakazawa, Masahiro Kondo
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Patent number: 4971749Abstract: A nuclear excitation laser type intra-reactor neutron flux measuring system of this invention is comprised of a laser oscillator filled with a nuclear exciting gas such as .sup.3 He, KrF or XeF, mounted on the tip of a control rod. The nuclear exciting gas is made into a plasma by the neutrons or the fragments of fissioned nuclei when the tip is positioned in the reactor core by raising the control rod. Since the nuclear exciting gas made into a plasma itself generates a laser beam or amplifies a laser beam projected from the outside, the behavior of neutrons can be monitored in detail after guiding this light response to the light processing system located outside, distinguishing the energies of neutrons from the spectrum and calculating the density and the flux of the neutron in each energy. Furthermore, the detecting sensitivity can be enhanced by forming the responsive membrane made of U.sub.3 O.sub.8 and so on, on the laser oscillator.Type: GrantFiled: November 17, 1989Date of Patent: November 20, 1990Assignee: Doryokuro Kakunenryo Kaihatsu JigyodanInventors: Hisashi Nakamura, Masaharu Nakazawa