Patents by Inventor Masakatsu Nakatsuka

Masakatsu Nakatsuka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5324704
    Abstract: Disclosed are novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are different groups selected from cyclohexyl, n-butyl and isobutyl, e.g., in the form of crystals characterized by a specific X-ray diffraction diagram; crystalline toluene adducts thereof; and recording materials containing these fluoran compounds.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: June 28, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5306688
    Abstract: A heat-sensitive recording material comprising a color forming, electron donating compound and a salicylic acid derivative represented by the formula (1): ##STR1## wherein X.sub.1 and X.sub.2 are a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group or a halogen atom, Y.sub.1 and Y.sub.2 are an oxygen atom or a sulfur atom, R.sub.1 is a hydrogen atom, an alkyl group, an aralkyl group or an aryl group , and R.sub.2 is an alkyl group, an alkenyl group, an aralkyl group or an aryl group, and/or a metal salt of the salicylic acid derivative as an electron accepting compound, is disclosed.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: April 26, 1994
    Assignees: Mitsui Toatsu Chemicals, Inc., Mitsubishi Paper Mills Limited
    Inventors: Yoshimitsu Tanabe, Yuki Kobayashi, Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi, Naomasa Koike, Fumio Okumura
  • Patent number: 5302571
    Abstract: Disclosed are a crystal and crystalline solvate of a fluoran compound represented by the formula ##STR1## wherein R.sub.1 is ##STR2## and which are useful as chromogenic compounds in recording materials such as pressure-sensitive and heat-sensitive recording materials, a process for preparation of said crystal and said crystalline solvate, and recording materials comprising said crystal or said crystalline solvate.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: April 12, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5300473
    Abstract: Disclosed are a crystal of a fluoran compound having the formula comprising exhibiting high peaks at diffraction angles (2.theta.) of 7.5.degree. and 17.0.degree. and relatively high peaks at diffraction angles (2.theta.) of 15.1.degree., 19.1.degree., 21.5.degree. and 25.3.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam and a crystal of a fluoran compound having the formula (II) comprising exhibiting high peaks at diffraction angles (2.theta.) of 5.5.degree. and 19.2.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam, which is useful as a color forming compound in recording materials.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: April 5, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5300661
    Abstract: Disclosed are novel crystal of the fluoran compound represented by the formula (I) ##STR1## ,characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: April 5, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5286418
    Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: February 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
  • Patent number: 5283222
    Abstract: Disclosed are novel crystal of the fluoran compound represented by the formula (I) ##STR1## , characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5281570
    Abstract: A reversible thermochromic material, preferably in the form of a microcapsule, comprising:(a) an electron donative color former;(b) a sulfide, sulfoxide or sulfone containing a hydroxy phenyl radical; and(c) a chemical compound selected from alcohols, esters, ethers, ketones, carboxylic acids or acid amides,chromatizes very brightly and in a dense color, generates a change of chromic hue (colored - colorless) within a narrow temperature range and provides a stable thermochromatism on a long term basis.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: January 25, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kiyoharu Hasegawa, Yoshimitsu Tanabe, Kazuyoshi Kikkawa, Masakatsu Nakatsuka, Akihiro Yamaguchi
  • Patent number: 5270281
    Abstract: Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R.sub.2 and R.sub.4 denote an alkyl, alkenyl, aralkyl or aryl group, X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 stand for an oxygen or a sulfur atom, and --Z.sub.1 -- and --Z.sub.2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: ##STR2## wherein R.sub.1, R.sub.2, X.sub.1 and Y.sub.1 have the same meanings as defined above; R.sub.5 and R.sub.6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R.sub.5 and R.sub.6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z.sub.3 -- means a specific divalent group.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Atsuo Otsuji, Toshihiro Motoshima, Yoshimitsu Tanabe, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Masakatsu Nakatsuka, Akihiro Yamaguchi
  • Patent number: 5245049
    Abstract: Disclosed are a crystal and crystalline solvate of a fluoran compound represented by the formula ##STR1## wherein R.sub.1 is ##STR2## and which are useful as chromogenic compounds in recording materials such as pressure-sensitive and heat-sensitive recording materials, a process for preparation of said crystal and said crystalline solvate, and recording materials comprising said crystal or said crystalline solvate.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: September 14, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5231069
    Abstract: Heat-sensitive recording paper which employs as a chromogenic compound a novel fluoran compound represented by the formula: ##STR1## and prepared reacting a benzoic acid derivative of the formula: ##STR2## with a diphenylamine derivative of the formula: ##STR3## wherein R is a lower alkyl group have excellent stability.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: July 27, 1993
    Assignee: Mitsui Toatsu Chemicals Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5220038
    Abstract: Disclosed are novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are different groups selected from cyclohexyl, n-butyl and isobutyl, e.g., in the form of crystals characterized by a specific X-ray diffraction diagram; crystalline toluene adducts thereof; and recording materials containing these fluoran compounds.
    Type: Grant
    Filed: July 18, 1990
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5210221
    Abstract: Disclosed are a crystal of a fluoran compound having the formula (I) comprising exhibiting high peaks at diffraction angles (2.theta.) of 7.5.degree. and 17.0.degree. and relatively high peaks at diffraction angles (2.theta.) of 15.1.degree., 19.1.degree., 21.5.degree. and 25.3.degree. in an X-ray diffraction diagram by the Cu-K.alpha. beam and a crystal of a fluoran compound having the formula (II) comprising exhibiting high peaks at diffraction angles (2.theta.) of 5.5.degree. and 19.2.degree. in an X-ray diffraction diagram by the Cu-K.alpha. beam, which is useful as a color forming compound in recording materials.
    Type: Grant
    Filed: September 10, 1991
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5208209
    Abstract: Novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl group having from 1 to 4 carbon atoms, preparation process of the fluoran compounds, and a heat-sensitive and a pressure-sensitive recording material comprising the fluoran compound, are disclosed.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: May 4, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5196507
    Abstract: Polycarbonate granules are produced by adding a solution of polycarbonate in an organic solvent to a suspension composed of water, an anti-solvent for polycarbonate and polycarbonate powder with stirring while evaporating and removing the organic solvent for polycarbonate added to the suspension. The procedure may be effected in the presence of a stabilizing agent for polycarbonate. The resulting polycarbonate granules are easy in handling, and free from fine powder, have high bulk density, large particle size and uniform quality, and can be directly molded.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: March 23, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshiyuki Totani, Masakatsu Nakatsuka, Akihiro Yamaguchi
  • Patent number: 5194632
    Abstract: Disclosed are a novel fluoran compound represented by the formula (I): ##STR1## and a heat-sensitive recording paper which is obtained by using the fluoran compound as a chromogenic compound and is excellent in preserving stability.
    Type: Grant
    Filed: July 31, 1990
    Date of Patent: March 16, 1993
    Assignee: Mitsui Toatsu Chemicals Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5185453
    Abstract: Disclosed are novel crystal of the fluoran compound represented by the formula ##STR1## , characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: February 9, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5169556
    Abstract: A ferroelectric liquid crystal is formed by incorporating, as the main component, a predetermined amount of a ferroelectric liquid crystal having a specific naphthalene ring structure into conventional liquid crystals. This liquid crystal composition has a broad driving temperature range and in particular, can be effectively driven even in a low-temperature region. Moreover, this liquid crystal composition has a high orientation uniformity, a high memory stability, and a high contrast ratio.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: December 8, 1992
    Assignees: Fujitsu Limited, Mitsui Toatsu Chem., Inc.
    Inventors: Akihiro Mochizuki, Mitsuaki Hirose, Hideo Hama, Masakatsu Nakatsuka
  • Patent number: 5087706
    Abstract: Novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl group having from 1 to 4 carbon atoms, preparation process of the fluoran compounds, and a heat-sensitive and a pressure-sensitive recording material comprising the fluoran compound, are disclosed.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: February 11, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5072021
    Abstract: The present invention is directed to optically active compounds each containing a naphthalene skeleton, and to liquid crystal compositions which contain the aforesaid optical active compounds, these compositions being suitable for ferroelectric liquid crystal devices having excellent photostability and chemical stability and having a rapid responsivity.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: December 10, 1991
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Tsutomu Nishizawa