Patents by Inventor Masanao Hayashi

Masanao Hayashi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11952525
    Abstract: A compound having large refractive index anisotropy (?n), the effect of increasing the phase transition temperature of a liquid crystal phase, and high solubility, and showing large dielectric anisotropy (??) in a high frequency region, a composition containing the compound, a liquid crystal composition, and a device using the liquid crystal composition. The compound has large refractive index anisotropy ?n, sufficiently high Tn-i, and high compatibility with a liquid crystal composition, and shows large dielectric anisotropy in a high frequency region, and is thus useful for a material of an element of a device such as a high-frequency phase shifter, a phased array antenna, an image recognition device, a distance measuring device, a liquid crystal display device, a liquid crystal lens, a birefringent lens for stereoscopic image display.
    Type: Grant
    Filed: July 29, 2021
    Date of Patent: April 9, 2024
    Assignee: DIC Corporation
    Inventors: Masanao Hayashi, Takaya Ikeuchi
  • Publication number: 20230313044
    Abstract: A compound having large refractive index anisotropy (?n), the effect of increasing the phase transition temperature of a liquid crystal phase, and high solubility, and showing large dielectric anisotropy (??) in a high frequency region, a composition containing the compound, a liquid crystal composition, and a device using the liquid crystal composition. The compound has large refractive index anisotropy ?n, sufficiently high Tn-i, and high compatibility with a liquid crystal composition, and shows large dielectric anisotropy in a high frequency region, and is thus useful for a material of an element of a device such as a high-frequency phase shifter, a phased array antenna, an image recognition device, a distance measuring device, a liquid crystal display device, a liquid crystal lens, a birefringent lens for stereoscopic image display, or the like.
    Type: Application
    Filed: July 29, 2021
    Publication date: October 5, 2023
    Applicant: DIC Corporation
    Inventors: Masanao HAYASHI, Takaya IKEUCHI
  • Patent number: 11760934
    Abstract: The compound is represented by general formula (i). In the compound, in a group Ki1, at least two secondary carbon atoms in an alkyl group (a linear alkyl, halogenated alkyl, or cyanogenated alkyl group having 3 to 40 carbon atoms) are replaced with —C(?Xi1)— and/or —CH(—CN)—, where Xi1 is an oxygen atom, a sulfur atom, NH, or NR13; in addition, a group Ai2, a group Ai3, or the group Ki1 includes, as a substituent, at least one Pi1-Spi1- group, where Pi1 is a polymerizable group, and SPi1 is a spacer group or a single bond. The liquid crystal composition including the compound represented by general formula (i) can be adsorbed onto substrates between which a liquid crystal layer is held, and, consequently, without the use of an alignment film, liquid crystal molecules can be maintained in a state in which the liquid crystal molecules are aligned in a vertical direction.
    Type: Grant
    Filed: November 1, 2018
    Date of Patent: September 19, 2023
    Assignee: DIC CORPORATION
    Inventors: Kenta Shimizu, Masanao Hayashi, Yutaka Kadomoto, Tetsuo Kusumoto, Ayaki Hosono, Shinya Yamamoto, Masanori Miyamoto, Hidetomo Kai
  • Patent number: 11739270
    Abstract: The present invention provides a compound represented by the general formula (i), which has a partial structure Ki1 represented by one of the general formulae (K-1) to (K-6) and has a ring B with at least one P-Sp- group and with at least one Ri2 (Ri2 denotes a linear or branched alkyl group having 2 to 10 carbon atoms or a linear or branched halogenated alkyl group having 2 to 10 carbon atoms, —CH2— in the alkyl or halogenated alkyl group is optionally substituted with —CH?CH—, —O—, —COO—, or —OCO—, but —O— is not adjacent to another —O—). Thus, the compound in a liquid crystal composition adsorbs to substrates between which the liquid crystal composition (a liquid crystal layer) exists. The compound can hold vertically aligned liquid crystal molecules, can improve alignment stability, and can ensure low-temperature storage stability.
    Type: Grant
    Filed: February 14, 2019
    Date of Patent: August 29, 2023
    Assignee: DIC CORPORATION
    Inventors: Masanao Hayashi, Ayaki Hosono, Shota Kosaka
  • Patent number: 11639327
    Abstract: The present invention provides a compound represented by formula (i), a liquid crystal composition using the compound, and a liquid crystal display device using the liquid crystal composition. The compound represented by formula (i) has a partial structure Ki1 represented by any of general formulas (K-1) to (K-17) and further has ring B having at least two P-Sp- groups. Therefore, when used for a liquid crystal composition, the compound adsorbs to substrates sandwiching the liquid crystal composition (liquid crystal layer) and allows liquid crystal molecules to be held such that they are aligned in a vertical direction without a PI layer, and improved alignment stability and low-temperature storage stability can be achieved.
    Type: Grant
    Filed: December 6, 2018
    Date of Patent: May 2, 2023
    Assignee: DIC Corporation
    Inventors: Ayaki Hosono, Masanao Hayashi, Tetsuo Kusumoto
  • Patent number: 11639471
    Abstract: The present invention provides a compound represented by the following general formula (I), and provides a liquid crystal composition containing the compound and a device using the liquid crystal composition. The compound of the present invention has a large refractive index anisotropy ?n and a high compatibility with a liquid crystal composition, and exhibits a large dielectric constant anisotropy in a high frequency region; and therefore, it is useful as a material for a device of a high-frequency phase shifter, a phased array antenna, an image recognition device, distance measuring equipment, a liquid crystal display device, a liquid crystal lens, a birefringent lens for stereoscopic image display, or the like.
    Type: Grant
    Filed: November 19, 2020
    Date of Patent: May 2, 2023
    Assignee: DIC CORPORATION
    Inventors: Masahiro Horiguchi, Masanao Hayashi
  • Patent number: 11613701
    Abstract: A compound is represented by general formula (I), a liquid-crystal composition contains this compound, and devices are made using this liquid-crystal composition. Having a large refractive-index anisotropy ?n and a sufficiently high Tni, highly compatible with liquid-crystal compositions, and exhibiting a high dielectric anisotropy in the radio frequency range, the compound is a useful material for RF phase shifters, phased-array antennae, image recognition devices, distance meters, liquid-crystal displays, liquid-crystal lenses, and birefringent lenses for 3D image display, among other devices.
    Type: Grant
    Filed: June 30, 2021
    Date of Patent: March 28, 2023
    Assignee: DIC Corporation
    Inventors: Takaya Ikeuchi, Masanao Hayashi
  • Patent number: 11555152
    Abstract: [Object] An object of the present invention is to provide a liquid crystal composition containing a polymerizable compound for use in the manufacture of a PSA or PSVA liquid crystal display device. The polymerizable compound has a sufficiently high polymerization rate. The PSA or PSVA liquid crystal display device has few or no display defects due to a change in pretilt angle, has an adequate pretilt angle, and has high responsiveness. The present invention also provides a liquid crystal display device having the liquid crystal composition. [Solution] The object is achieved by using a liquid crystal composition containing one or two or more polymerizable compounds represented by the general formula (I).
    Type: Grant
    Filed: April 13, 2017
    Date of Patent: January 17, 2023
    Assignee: DIC CORPORATION
    Inventors: Marina Goto, Yuichi Inoue, Shota Kosaka, Go Sudo, Masanao Hayashi, Manabu Takachi
  • Patent number: 11345857
    Abstract: The spontaneous orientation aid for a liquid crystal composition provides storage stability and allows liquid crystal molecules to be vertically aligned without a PI layer when added to a liquid crystal composition. When used in a liquid crystal composition, the spontaneous orientation aid can adsorb to substrates sandwiching a liquid crystal composition (liquid crystal layer) and keep the liquid crystal molecules aligned in a vertical direction. The spontaneous orientation aid makes it possible to align liquid crystal molecules without a PI layer (to induce vertical alignment of liquid crystal molecules under no applied voltage and to achieve horizontal alignment of the liquid crystal molecules under an applied voltage).
    Type: Grant
    Filed: November 17, 2020
    Date of Patent: May 31, 2022
    Assignee: DIC CORPORATION
    Inventors: Masaomi Kimura, Yuuichi Inoue, Hidenari Akiyama, Masanao Hayashi, Tetsuo Kusumoto
  • Patent number: 11312906
    Abstract: A problem to be solved by the present invention is to provide a liquid crystal composition excellent in vertical alignment and compatibility and to provide a liquid crystal display device produced using the same. The problem is solved by a liquid crystal composition containing one or two or more kinds of self-aligning polymerizable monomers and one or two or more kinds of polymerizable monomers (or polymerizable compounds) having a specific chemical structure, and a liquid crystal display device produced using the same, specifically a liquid crystal composition containing a polymerizable monomer represented by General Formula (I) and a spontaneously aligning monomer which has a chemical structure different from that of the polymerizable monomer represented by General Formula (I), and has a polar group, and a liquid crystal display device containing the same.
    Type: Grant
    Filed: May 17, 2018
    Date of Patent: April 26, 2022
    Assignee: DIC CORPORATION
    Inventors: Junichi Mamiya, Yuichi Inoue, Masaomi Kimura, Junko Yamamoto, Masanao Hayashi, Hirokazu Sugiyama
  • Publication number: 20220025264
    Abstract: A compound is represented by general formula (I), a liquid-crystal composition contains this compound, and devices are made using this liquid-crystal composition. Having a large refractive-index anisotropy ?n and a sufficiently high Tni, highly compatible with liquid-crystal compositions, and exhibiting a high dielectric anisotropy in the radiofrequency range, the compound is a useful material for RF phase shifters, phased-array antennae, image recognition devices, distance meters, liquid-crystal displays, liquid-crystal lenses, and birefringent lenses for 3D image display, among other devices.
    Type: Application
    Filed: June 30, 2021
    Publication date: January 27, 2022
    Applicant: DIC Corporation
    Inventors: Takaya IKEUCHI, Masanao HAYASHI
  • Patent number: 11174217
    Abstract: A compound represented by formula (i) has, as Ki1 in the formula (i), a structure represented by any one of formula (K-1) to formula (K-3). When used in a liquid crystal composition, it adheres to substrates which hold the liquid crystal composition (liquid crystal layer) therebetween, thereby permitting liquid crystal molecules to be maintained in the state of being aligned in the vertical direction. The liquid crystal composition using the compound enables liquid crystal molecules to be aligned even when the PI layer is not provided (vertical alignment of liquid crystal molecules is induced without the voltage applied and horizontal alignment of liquid crystal molecules is realized with the voltage applied). It is possible to provide a polymerizable compound being excellent in storability and capable of uniform vertical alignment of liquid crystal molecules with no PI layer provided.
    Type: Grant
    Filed: May 29, 2018
    Date of Patent: November 16, 2021
    Assignee: DIC CORPORATION
    Inventors: Ayaki Hosono, Masanao Hayashi
  • Publication number: 20210214299
    Abstract: The present invention provides a compound represented by formula (i), a liquid crystal composition using the compound, and a liquid crystal display device using the liquid crystal composition. The compound represented by formula (i) has a partial structure Ki1 represented by any of general formulas (K-1) to (K-17) and further has ring B having at least two P-Sp- groups. Therefore, when used for a liquid crystal composition, the compound adsorbs to substrates sandwiching the liquid crystal composition (liquid crystal layer) and allows liquid crystal molecules to be held such that they are aligned in a vertical direction without a PI layer, and improved alignment stability and low-temperature storage stability can be achieved.
    Type: Application
    Filed: December 6, 2018
    Publication date: July 15, 2021
    Applicant: DIC Corporation
    Inventors: Ayaki HOSONO, Masanao HAYASHI, Tetsuo KUSUMOTO
  • Publication number: 20210179943
    Abstract: The present invention provides a compound represented by the following general formula (I), and provides a liquid crystal composition containing the compound and a device using the liquid crystal composition. The compound of the present invention has a large refractive index anisotropy ?n and a high compatibility with a liquid crystal composition, and exhibits a large dielectric constant anisotropy in a high frequency region; and therefore, it is useful as a material for a device of a high-frequency phase shifter, a phased array antenna, an image recognition device, distance measuring equipment, a liquid crystal display device, a liquid crystal lens, a birefringent lens for stereoscopic image display, or the like.
    Type: Application
    Filed: November 19, 2020
    Publication date: June 17, 2021
    Applicant: DIC Corporation
    Inventors: Masahiro Horiguchi, Masanao Hayashi
  • Publication number: 20210071084
    Abstract: The spontaneous orientation aid for a liquid crystal composition provides storage stability and allows liquid crystal molecules to be vertically aligned without a PI layer when added to a liquid crystal composition. When used in a liquid crystal composition, the spontaneous orientation aid can adsorb to substrates sandwiching a liquid crystal composition (liquid crystal layer) and keep the liquid crystal molecules aligned in a vertical direction. The spontaneous orientation aid makes it possible to align liquid crystal molecules without a PI layer (to induce vertical alignment of liquid crystal molecules under no applied voltage and to achieve horizontal alignment of the liquid crystal molecules under an applied voltage).
    Type: Application
    Filed: November 17, 2020
    Publication date: March 11, 2021
    Applicant: DIC CORPORATION
    Inventors: Masaomi Kimura, Yuuichi Inoue, Hidenari Akiyama, Masanao Hayashi, Tetsuo Kusumoto
  • Patent number: 10927300
    Abstract: The spontaneous orientation aid for a liquid crystal composition provides storage stability and allows liquid crystal molecules to be vertically aligned without a PI layer when added to a liquid crystal composition. The spontaneous orientation aid for a liquid crystal composition includes a compound having a partial structure represented by formula (i), particularly in which Ki1 is represented by one of formula (K-1) to formula (K-11). When used in a liquid crystal composition, the spontaneous orientation aid can adsorb to substrates sandwiching a liquid crystal composition (liquid crystal layer) and keep the liquid crystal molecules aligned in a vertical direction. The spontaneous orientation aid makes it possible to align liquid crystal molecules without a PI layer (to induce vertical alignment of liquid crystal molecules under no applied voltage and to achieve horizontal alignment of the liquid crystal molecules under an applied voltage).
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: February 23, 2021
    Assignee: DIC CORPORATION
    Inventors: Masaomi Kimura, Yuuichi Inoue, Hidenari Akiyama, Masanao Hayashi, Tetsuo Kusumoto
  • Patent number: 10919870
    Abstract: There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.
    Type: Grant
    Filed: November 9, 2015
    Date of Patent: February 16, 2021
    Assignee: DIC CORPORATION
    Inventors: Masahiro Horiguchi, Yutaka Kadomoto, Akihiro Koiso, Masanao Hayashi, Yoshitaka Saitou, Yan Teng, Zhimin Li
  • Publication number: 20200399539
    Abstract: The present invention provides a compound represented by the general formula (i), which has a partial structure Ki1 represented by one of the general formulae (K-1) to (K-6) and has a ring B with at least one P-Sp- group and with at least one Ri2 (Ri2 denotes a linear or branched alkyl group having 2 to 10 carbon atoms or a linear or branched halogenated alkyl group having 2 to 10 carbon atoms, —CH2— in the alkyl or halogenated alkyl group is optionally substituted with —CH?CH—, —O—, —COO—, or —OCO—, but —O— is not adjacent to another —O—). Thus, the compound in a liquid crystal composition adsorbs to substrates between which the liquid crystal composition (a liquid crystal layer) exists. The compound can hold vertically aligned liquid crystal molecules, can improve alignment stability, and can ensure low-temperature storage stability.
    Type: Application
    Filed: February 14, 2019
    Publication date: December 24, 2020
    Applicant: DIC Corporation
    Inventors: Masanao Hayashi, Ayaki Hosono, Shota Kosaka
  • Publication number: 20200308488
    Abstract: The compound is represented by general formula (i). In the compound, in a group Ki1, at least two secondary carbon atoms in an alkyl group (a linear alkyl, halogenated alkyl, or cyanogenated alkyl group having 3 to 40 carbon atoms) are replaced with —C(?Xi1)— and/or —CH(—CN)—, where Xi1 is an oxygen atom, a sulfur atom, NH, or NR13; in addition, a group Ai2, a group Ai3, or the group Ki1 includes, as a substituent, at least one Pi1-Spi1- group, where Pi1 is a polymerizable group, and SPi1 is a spacer group or a single bond. The liquid crystal composition including the compound represented by general formula (i) can be adsorbed onto substrates between which a liquid crystal layer is held, and, consequently, without the use of an alignment film, liquid crystal molecules can be maintained in a state in which the liquid crystal molecules are aligned in a vertical direction.
    Type: Application
    Filed: November 1, 2018
    Publication date: October 1, 2020
    Applicant: DIC Corporation
    Inventors: Kenta Shimizu, Masanao Hayashi, Yutaka Kadomoto, Tetsuo Kusumoto, Ayaki Hosono, Shinya Yamamoto, Masanori Miyamoto, Hidetomo Kai
  • Publication number: 20200224098
    Abstract: A problem to be solved by the present invention is to provide a liquid crystal composition excellent in vertical alignment and compatibility and to provide a liquid crystal display device produced using the same. The problem is solved by a liquid crystal composition containing one or two or more kinds of self-aligning polymerizable monomers and one or two or more kinds of polymerizable monomers (or polymerizable compounds) having a specific chemical structure, and a liquid crystal display device produced using the same, specifically a liquid crystal composition containing a polymerizable monomer represented by General Formula (I) and a spontaneously aligning monomer which has a chemical structure different from that of the polymerizable monomer represented by General Formula (I), and has a polar group, and a liquid crystal display device containing the same.
    Type: Application
    Filed: May 17, 2018
    Publication date: July 16, 2020
    Applicant: DIC Corporation
    Inventors: Junichi Mamiya, Yuichi Inoue, Masaomi Kimura, Junko Yamamoto, Masanao Hayashi, Hirokazu Sugiyama