Patents by Inventor Masanao Hinata
Masanao Hinata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4014702Abstract: A silver halide photographic emulsion containing a spectrally sensitizing amount of a sensitizing dye represented by the general formula (I) ##STR1## and a sensitizing dye represented by the formula (II) ##STR2## wherein Z.sub.1 and Z.sub.2 each is an atomic group necessary to complete a benzoxazole ring or a naphthoxazole ring; R.sub.1 is an alkyl group or an allyl group; R.sub. 2 is an alkyl group or an allyl group; R.sub.3 is an unsubstituted lower alkyl group, a hydroxyalkyl group or a carboxyalkyl group; R.sub.4 is same as R.sub.1 ; R.sub.5 is an alkyl group, an allyl group or a phenyl group; R.sub.6 is an alkoxycarbonylalkyl group, a hydroxyalkoxyalkyl group, an acyloxyalkoxyalkyl group, an N-(N,N-dialkylaminoalkyl)carbamoylalkyl group, an N-(N,N,N-trialkylammonium)carbamoylalkyl group or an N,N,N-trialkylammoniumalkyl group; X.sup.- is an acid anion; and n is 0 or 1.Type: GrantFiled: July 21, 1975Date of Patent: March 29, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Masanaga Ohki, Hartuo Takei, Akira Sato, Akira Ogawa
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Patent number: 4010037Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group required for forming a benzimidazole ring; R.sub.1 and R.sub.2 each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 represents an alkyl group having a carboxy group, a hydroxyalkyl group or an alkyl group having a sulfo group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 when the dye forms an inner salt (a betaine-like structure) and at least one sensitizing dye of the following general formula (II) ##STR2## wherein Z.sub.3 represents an atomic group required for forming a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required for forming a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.Type: GrantFiled: January 28, 1976Date of Patent: March 1, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Tadashi Ikeda, Mitsuo Iwamoto
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Patent number: 4002480Abstract: A photographic silver halide emulsion containing at least one dinuclear merocyanine sensitizing dye, and at least one compound represented by the following formula: ##STR1## wherein D represents a divalent aromatic group, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom, a hydroxyl group, an alkoxyl group, an aryloxy group, a halogen atom, a heterocyclic group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group, an amino group, an alkylamino group, a cycloalkylamino group, an arylamino group, a heterocyclic amino group, an aralkylamino group, or an aryl group.Type: GrantFiled: March 6, 1975Date of Patent: January 11, 1977Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Yuji Mihara, Reiichi Ohi, Keiichi Adachi, Akira Sato
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Patent number: 3994733Abstract: A silver halide photographic emulsion containing the combination of (i) at least one cyanine dye wherein two basic 5-membered and/or 6-membered nitrogen-containing heterocyclic nuclei are linked by methine groups having an odd number of carbon atoms not exceeding 7 and the substituents on the nitrogen atoms in the heterocyclic nuclei are aliphatic groups or aromatic groups with at least one of the substituents on the nitrogen atom being an alkyl group having a sulfo group or a carboxyl group, and (ii) at least one substantially colorless nitrogen-containing heterocyclic organic base selected from the group consisting of a benzothiazole, a benzothiazolone, a naphthothiazole, a naphthothiazolone, and a quinolone in a quantity sufficient to supersensitize.Type: GrantFiled: December 10, 1974Date of Patent: November 30, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Masanaga Ohki, Reiichi Ohi, Akira Ogawa, Akira Sato
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Patent number: 3988155Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following general formula (I) ##EQU1## wherein Z.sub.11 represents the atoms necessary to complete a pyridine nucleus or a quinoline nucleus; Z.sub.12 represents the atoms necessary to complete an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, an imidazole nucleus, a benzimidazole nucleus or a naphthoimidazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group with at least one of R.sub.11 and R.sub.12 having a carboxy or sulfo group; and at least one sensitizing dye represented by the following general formula (II) ##EQU2## wherein Z.sub.21 and Z.sub.22, which can be the same or different, each represents the atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a selenazole nucleus or a benzoselenazole nucleus; and R.sub.21 and R.sub.22 each represents an aliphatic group with at least one of R.sub.21 and R.sub.Type: GrantFiled: September 4, 1975Date of Patent: October 26, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
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Patent number: 3986878Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following general formula (I) ##EQU1## wherein Z.sub.11 represents the atoms necessary to complete a thiazole nucleus, a selenazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus; Z.sub.12 represents the atoms necessary to complete a naphthothiazole nucleus, or a naphthoselenazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group with at least one of R.sub.11 and R.sub.12 having a carboxy or sulfo group; and at least one sensitizing dye represented by the following general formula (II) ##EQU2## wherein Z.sub.21 represents the atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus or a naphthoselenazole nucleus; Z.sub.Type: GrantFiled: September 4, 1975Date of Patent: October 19, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
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Patent number: 3985563Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following General Formula (I): ##EQU1## in which Z.sub.11 represents an atomic group necessary for completing a pyridine or quinoline nucleus; Z.sub.12 represents an atomic group necessary for completing an oxazole, benzoxazole, naphthoxazole, imidazole, benzimidazole or naphthimidazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group and at least one of R.sub.11 and R.sub.12 is an aliphatic group containing a carboxy group or a sulfo group; and at least one sensitizing dye represented by the following General Formula (II): ##EQU2## in which Z.sub.21 represents an atomic group necessary for completing a thiazole, benzothiazole, naphthothiazole, selenazole, benzoselenazole or naphthoselenazole nucleus; Z.sub.22 represents an atomic group necessary for completing an imidazole, benzimidazole or naphthimidazole nucleus; an R.sub.21 and R.sub.Type: GrantFiled: September 9, 1975Date of Patent: October 12, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
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Patent number: 3977883Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##EQU1## WHEREIN Z.sub.1 and Z.sub.2 each represents an atomic group required to form a quinoline ring; R.sub.1 and R.sub.2 each represents an aliphatic group, with at least one of R.sub.1 and R.sub.2 being a hydroxyalkyl group, an alkyl group containing a carboxyl group or an alkyl group containing a sulfo group; X.sub.1 is an acid anion; and m is 1 or 2, and when m is 1 the dye forms an intramolecular salt and at least one sensitizing dye of the following general formula (II) ##EQU2## WHEREIN Z.sub.3 represents an atomic group required to form a benzimidazole ring, a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required to form a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.Type: GrantFiled: December 6, 1974Date of Patent: August 31, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto
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Patent number: 3976492Abstract: A silver halide photographic emulsion containing at least one sensitizing dye represented by the formula (I) ##EQU1## wherein Z.sub.1 represents a group of atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus; Z.sub.2 represents a group of atoms necessary to complete a naphthothiazole nucleus or a naphthoselenazole nucleus; and R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 is an aliphatic group containing a carboxyl group or a sulfo group; and at least one sensitizing dye represented by the formula (II) ##EQU2## wherein Z.sub.3 and Z.sub.4 which may be the same or different, each represents a group of atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus or a benzoselenazole nucleus; and R.sub.3 and R.sub.4, which may be the same or different, each represents an aliphatic group and at least one of R.sub.Type: GrantFiled: July 25, 1975Date of Patent: August 24, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
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Patent number: 3973969Abstract: Silver halide photographic emulsions are supersensitized by a combination of at least one sensitizing dye represent by following general formula (I): ##EQU1## And at least one sensitizing dye represented by following general formula (II): ##SPC1##Specific moieties given in the above formulae are identified in the specification.Type: GrantFiled: May 2, 1975Date of Patent: August 10, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Hirotetu Kato, Akiro Sato, Akira Ogawa
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Fogged, direct-positive silver halide emulsion containing carbocyanine dye having indolenine nucleus
Patent number: 3970461Abstract: A direct positive silver halide photographic emulsion containing a dye represented by the following general formula: ##SPC1##Wherein R and R.sub.1 are selected from the first group consisting of alkyl, allyl, substituted alkyl, aryl, and substituted aryl groups, at least one of the R and R.sub.1 being an alkyl group substituted with a carboxyl or sulfo radical; R.sub.2 and R.sub.3 are selected from the second group consisting of alkyl, aralkyl and allyl groups; L.sub.1 is selected from the third group consisting of methine and an atomic group capable of combining with R.sub.1, R.sub.2 or R.sub.3 to form a ring; L.sub.2 is methine; L.sub.3 is selected from the fourth group consisting of methine and an atomic group capable of forming a ring with R.sub.1 or a 3,3-substituent of an indolenine ring at the site near to L.sub.3, L.sub.3, such that a ring may be formed by L.sub.1 and L.sub.Type: GrantFiled: July 6, 1973Date of Patent: July 20, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Akira Sato, Akira Ogawa, Hirotetu Kato -
Patent number: 3967967Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least two carbocyanine dyes having structures hereinafter defined.Type: GrantFiled: December 6, 1974Date of Patent: July 6, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto
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Patent number: 3966477Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at last two carbocyanine sensitizing dyes as hereinafter defined.Type: GrantFiled: December 6, 1974Date of Patent: June 29, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Tadashi Ikeda, Akira Ogawa, Akira Sato, Atsuo Iwamoto
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Patent number: 3955996Abstract: A method for spectrally sensitizing a photographic light-sensitive emulsion, which comprises dissolving a photographic spectrally sensitizing dye having an amidinium ion auxochrome in an organic solvent containing a substantially water-free acid having a pKa not exceeding about 5, and adding this dye-containing acid-organic solvent solution to a light-sensitive emulsion.Type: GrantFiled: November 15, 1974Date of Patent: May 11, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Masanaga Ohki, Haruo Takei, Yuji Mihara
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Patent number: 3955979Abstract: A silver halide photographic light-sensitive element suitable for exposure to light for a period of time of less than (preferably) 0.0001 second comprising a support bearing thereon at least one layer of a silver halide photographic emulsion, the silver halide photographic emulsion containing at least one sensitizing dye represented by the following General Formula (I) in combination with at least one sensitizing dye represented by the following General Formula (II): ##SPC1##wherein R.sub.1 and R.sub.2 each represents an alkyl group, at least one of R.sub.1 and R.sub.2 being an alkyl group having a sulfo substituent; ##SPC2##Wherein R.sub.B represents a methyl group or an ethyl group, R.sub.3 and R.sub.4 have the same meaning as R.sub.1 and R.sub.2, at least one of R.sub.3 and R.sub.4 being an alkyl group having a sulfo substituent.Type: GrantFiled: March 24, 1975Date of Patent: May 11, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Hirotetu Kato
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Patent number: 3953216Abstract: A spectral-sensitized silver halide photographic emulsion containing in supersensitizing amounts the combination of1. at least one sensitizing dye represented by the formula ##EQU1## WHEREIN Z.sub.1 and Z.sub.2 are the atomic groups necessary for forming a benzoxazole ring or a napthoxazole ring, in which a benzene nucleus of the ring may be substituted; R.sub.1 and R.sub.2 are aliphatic groups and at least one of R.sub.1 or R.sub.2 is a carboxyalkyl group or a sulfoalkyl group; R.sub.3 is a hydrogen atom or an alkyl group; X is an acid anion group; and m is 1 or 2 and m is 1 when the dye forms an intramolecular salt having a betaine like-structure,2. at least one sensitizing dye represented by the formula (II) ##EQU2## wherein Z.sub.3 is an atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring which may be substituted by substituents other than R.sub.4 ; Z.sub.4 is an atomic group necessary for forming a 2-pyrazoline-5-one ring nucleus which may be substituted; R.sub.Type: GrantFiled: August 16, 1974Date of Patent: April 27, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Akira Ogawa
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Patent number: 3953215Abstract: A silver halide photographic emulsion containing in a supersensitizing amount the combination of at least one sensitizing dye represented by the general formula (I) ##SPC1##wherein, A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represents a member selected from the group consisting of a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom, a hydroxyl group, an aryl group, a carboxyl group, an alkoxycarbonyl group, a cyano group, a trifluoromethyl group, an amino group, an acylamide group, an acyloxyl group, an alkoxycarbonylamino group, and a carbalkoxy group; and A.sub.1 and A.sub.2 and A.sub.3 and A.sub.4 can combine to form a naphthoxazole nucleus; R.sub.o represents a hydrogen atom, a lower alkyl group or an aryl group; R.sub.1 and R.sub.2 each represents an alkyl group, provided that at least one of R.sub.1 or R.sub.2 represents a sulfoalkyl group; X.sub.Type: GrantFiled: July 16, 1974Date of Patent: April 27, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Masao Takano, Nobuaki Miyasaka
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Patent number: 3951666Abstract: A silver halide photographic emulsion containing a supersensitizing amount of the combination of at least one dye represented by the general formula (I) ##SPC1##wherein Z represents the non-metal atoms necessary to form a benzene nucleus; R.sub.0, R.sub.1 and R.sub.2 each represents aliphatic groups, with at least one of R.sub.1 and R.sub.2 representing an alkyl group containing a carboxy group or an alkyl group containing a sulfo group; Y represents a halogen atom; X represents an acid anion; n represents an integer of 1 to 2, with n being 1 when the dye forms an intramolecular salt; and at least one dye represented by the general formula (II) ##EQU1## wherein Z.sub.1 represents the non-metal atoms necessary to form a 5-or 6-membered heterocyclic nucleus; Q represents the atoms necessary to form a rhodanine nucleus, a 2-thio-2,4-imidazolidinedione nucleus, a 2-pyrazoline-5-one nucleus, or a 2-thio-2,4-oxazolidinedione nucleus; R.sub.3 represents an aliphatic group; R.sub.Type: GrantFiled: August 6, 1974Date of Patent: April 20, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Masanaga Ohki, Haruo Takei, Akira Sato, Tadashi Ikeda
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Patent number: 3945832Abstract: A direct positive silver halide photographic emulsion containing1. at least one dimethine dye having the general formula (I): ##EQU1## 2. AT LEAST ONE COMPOUND HAVING THE GENERAL FORMULA (II): ##SPC1##3. at least one compound having the general formula (III) ##EQU2## or the general formula (IV) ##SPC2##wherein Y, Y.sub.o, Z, L.sub.1, L.sub.2, R.sub.o, m, n, X, Z.sub.1, R.sub.1, X.sub.1, a, p, q, Y.sub.1, Y.sub.2, m.sub.1, R.sub.3, r, X.sub.2 and X.sub.3 are as hereinafter defined.Type: GrantFiled: March 27, 1974Date of Patent: March 23, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Reiichi Ohi, Tadao Shishido
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Patent number: 3930860Abstract: A light-sensitive silver halide material for the high temperature and rapid color development at least 30.degree.C, which light-sensitive silver halide material comprises at least one spectrally sensitized silver halide photographic emulsion layer, the emulsion layer containing at least one sensitizing dye having an halogen ion concentration increasing effect.Type: GrantFiled: January 2, 1974Date of Patent: January 6, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Seiiti Kubodera