Patents by Inventor Masanobu Masu

Masanobu Masu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4877847
    Abstract: A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin modified with a 1,2-substituted olefin compound having an acid anhydride group, the polyphenylene either resin before modification having structural units represented by the following ##STR1## wherein R.sup.1 represents a lower alkyl group having 1 to 3 carbon atoms, and R.sup.2 and R.sup.3, independently from each other, represent a hydrogen atom or a lower alkyl group having 1 to 3 carbon atoms, in the main chain, and(B) a polyamide resin having recurring units represented by the following formula (II)--R.sup.4 --NHCO--R.sup.5 --CONH-- (II)wherein R.sup.4 represents a xylylene group, and R.sup.5 represents a linear alkylene group having 4 to 10 carbon atoms.
    Type: Grant
    Filed: September 10, 1987
    Date of Patent: October 31, 1989
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Masanobu Masu, Hiroshi Yoshioka, Kenzi Kouno, Isao Nomura, Kazuo Yamamiya
  • Patent number: 4590239
    Abstract: A polyphenylene ether resin composition comprising:(a) a polyphenylene ether resin,(b) a polystyrene-type resin,(c) an A-B-A' type elastomeric block copolymer, wherein A and A' represent blocks resulting from polymerization of an aromatic vinyl compound, and B represents a block resulting from polymerization of a conjugated diene compound, and(d) an elastomeric stryene/butadiene random copolymer,which is suitable electroless plating. Molded articles formed by using the resin composition of this invention can be plated using conventional electroless plating processes for ABS resins.
    Type: Grant
    Filed: December 12, 1984
    Date of Patent: May 20, 1986
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Akikazu Amagai, Toshihiko Kobayashi
  • Patent number: 4556685
    Abstract: A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) a polystyrene resin,(C) an acrylonitrile/conjugated diene elastomeric copolymer,(D) a graft copolymer obtained by reacting butyl rubber and an unsaturated polyolefin in a bifunctional phenol as a reaction medium, and(E) an aromatic phosphate.
    Type: Grant
    Filed: October 10, 1984
    Date of Patent: December 3, 1985
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Toshihiko Kobayashi
  • Patent number: 4503186
    Abstract: A curable resin composition comprising (a) a polyphenylene resin, (b) a maleimide compound and/or a cyanate ester compound and (c) at least one compound selected from the group consisting of compounds having one or more acryloyl, methacryloyl, acryloxy or methacryloxy groups is disclosed. The curable resin composition can give a cured resin having resistance to heat, solvent and moisture and adhering property.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: March 5, 1985
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masatugu Matunaga, Hidenori Kimpara
  • Patent number: 4496695
    Abstract: A curable resin composition comprising:(a) a polyphenylene ether resin,(b) a maleimide component and/or a cyanate ester component, and(c) an epoxy compoundis disclosed. The cured resin composition can give a cured resin having resistance to heat, solvent and moisture, adhering property and electrical properties.
    Type: Grant
    Filed: February 24, 1982
    Date of Patent: January 29, 1985
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masatugu Matunaga
  • Patent number: 4489186
    Abstract: A polyphenylene ether resin composition comprising(1) a polyphenylene ether resin,(2) an oxanilide represented by the following formula ##STR1## wherein R.sup.1 and R.sup.6 are identical or different and each represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an alkoxy group having 1 to 15 carbon atoms, R.sup.2 and R.sup.7 are identical or different and each represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms, R.sup.3 and R.sup.8 are identical or different and each represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R.sup.4 and R.sup.5 are identical or different and each represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a dialkylaminoalkyl group with the alkyl moiety having 1 to 6 carbon atoms,(3) an organic phosphite, and(4) a hindered phenolic antioxidant.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: December 18, 1984
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Eiji Ukita
  • Patent number: 4472546
    Abstract: A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) at least one compound selected from the group consisting of 2-(o-hydroxyphenyl)benzotriazoles represented by the following formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each represents a hydrogen atom, a halogen atom, a hydroxyl group, an alkyl group, an alkoxy group, an alkoxycarbonylalkyl group, an aryl group or an aralkyl group, and X represents a halogen atom,and 2-hydroxybenzophenones represented by the following formula (II) ##STR2## wherein R.sup.5 represents a hydrogen atom, a hydroxyl group or an alkoxy group, R.sup.6 represents a hydrogen atom or a hydroxyl group, R.sup.7 represents a hydrogen atom or a sulfonic acid group, and R.sup.8 represents a hydrogen atom, an alkyl group or an aromatic acyl group,(C) an organic phosphite, and(D) a sterically hindered phenol.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: September 18, 1984
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Eiji Ukita
  • Patent number: 4448931
    Abstract: A resin composition comprising a polyphenylene ether resin and a rubber-modified polystyrene resin, wherein at least 80% of the rubber particles based on the total number of rubber particles in the elastomeric phase of the rubber-modified polystyrene resin have a particle diameter in the range of 0.5 to 4 microns, and the elastomeric phase has a particle size distribution index, SDI, defined by the equation ##EQU1## wherein x is the diameter in microns of the particles, and n is the number of particles having a particle diameter of x microns, of not more than 1.9.
    Type: Grant
    Filed: April 16, 1982
    Date of Patent: May 15, 1984
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Akikazu Amagai
  • Patent number: 4427814
    Abstract: A polyphenylene ether resin composition having improved heat stability and good color, said composition comprising a polyphenylene ether resin matrix, and dispersed therein, a diphosphonite of the formula ##STR1## wherein R.sub.1 groups are identical or different and each represents a linear or branched alkyl group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: January 24, 1984
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Yukio Sasaki, Kozo Ishiyama
  • Patent number: 4389516
    Abstract: A curable polyphenylene ether resin composition comprising(a) a polyphenylene ether resin, and(b) at least one polyfunctional compound selected from the group consisting of polyfunctional maleimides having at least two maleimide groups or the prepolymer thereof, polyfunctional cyanate esters having at least two cyanate ester groups or the prepolymer thereof, and pre-copolymers of the polyfunctional maleimides and the polyfunctional cyanate esters.The cured resin composition has utility in rustproofing paints, electrical insulating varnishes, adhesives and molding material.
    Type: Grant
    Filed: March 23, 1981
    Date of Patent: June 21, 1983
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masatugu Matunaga
  • Patent number: 4383066
    Abstract: A polyphenylene ether resin composition having improved heat stability, said composition comprising a polyphenylene ether resin matrix, and dispersed therein, a phosphonic acid or its derivative of the formula ##STR1## wherein R.sub.1 represents an unsubstituted or substituted phenyl or naphthyl group, or a linear or branched alkyl group with 1 to 18 carbon atoms, or a group of the following formula (a) ##STR2## R.sub.2 and R.sub.3 are identical or different and each represents hydrogen atom, a metal, an unsubstituted or substituted phenyl group, or an alkyl group with 1 to 10 carbon atoms; and R.sub.4 is a divalent hydrocarbon group with 2 to 10 carbon atoms.
    Type: Grant
    Filed: April 7, 1981
    Date of Patent: May 10, 1983
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Kozo Ishiyama
  • Patent number: 4341879
    Abstract: A polyphenylene ether resin composition having improved heat stability, said composition comprising a polymer matrix composed of a polyphenylene ether resin and a vinyl aromatic resin, and dispersed in the polymer matrix, at least one compound selected from the group consisting of(1). 2-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyanilino)-4,6-di-C.sub.5 -C.sub.15 -alkylthio-1,3,5-triazines,(2). .omega.,.omega.'-thiodi(C.sub.2 -C.sub.6 polymethylene)-bis[3-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)-carboxylates],(3). N,N'-C.sub.2 -C.sub.10 polymethylene-bis[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxamides], and(4). tetrakis-{methylene-[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxylate]}methanes.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: July 27, 1982
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Masatugu Matunaga, Kozo Ishiyama
  • Patent number: 4293660
    Abstract: A resin composition comprising(a) a polyphenylene ether resin or a mixture of it with a polystyrene resin, and(b) a grafted block copolymer of an unsaturated polyolefin and butyl rubber obtained by graft copolymerization in the presence of a bifunctional phenolic compound as a grafting vehicle.
    Type: Grant
    Filed: April 16, 1980
    Date of Patent: October 6, 1981
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masatugu Matunaga
  • Patent number: 4293478
    Abstract: An improved method for dispersing an inorganic pigment uniformly in polyphenylene ether resins. A polyphenylene ether composition having an inorganic pigment uniformly dispersed therein is obtained by intimately mixing a polyphenylene ether resin and the inorganic pigment in a weight ratio of from 0.5:1 to 2:1 by a high-speed mixer to form a pre-blend, and then mixing the pre-blend intimately with a polyphenylene ether in a conventional mixer such as an extruder. The pre-blend can also be uniformly dispersed in a mixture of the polyphenylene ether with polystyrene, a styrene/butadiene copolymer, a styrene/butadiene/acrylonitrile terpolymer, or a rubber-modified high impact polystyrene.
    Type: Grant
    Filed: October 3, 1979
    Date of Patent: October 6, 1981
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Hiroshi Nakai, Yukio Sasaki
  • Patent number: 4282335
    Abstract: A high molecular resin composition having superior impact strength and processability and comprising a polymeric matrix containing polyphenylene ether and a minor proportion of a low-molecular-weight olefin oligomer dispersed therein.
    Type: Grant
    Filed: March 26, 1980
    Date of Patent: August 4, 1981
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Yukio Sasaki, Zenpei Mizutani
  • Patent number: 4282139
    Abstract: A fiber-reinforced composition of a polyphenylene ether resin having improved rigidity and dimensional stability, said composition consisting essentially of (a) a polyphenylene ether resin or a mixture of it with a styrene resin, and (b) asbestos fibers.
    Type: Grant
    Filed: September 19, 1979
    Date of Patent: August 4, 1981
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masatugu Matunaga
  • Patent number: 4228258
    Abstract: A novel resin composition improved in moldability and impact resistance, comprising (A) a polyphenylene oxide having a molecular weight of 5,000 or higher, (B) an aromatic hydrocarbon-formaldehyde resin or a modified aromatic hydrocarbon-formaldehyde resin, and, if necessary, (C) a rubbery polymer, the weight ratio of the resin (A) to the resin (B) being from 10:90 to 99:1 and the amount of the rubbery polymer (C) being 3 to 40 parts by weight per 100 parts by weight of the sum of the resins (A) and (B). This resin composition has excellent mechanical and electrical properties of the polyphenylene oxide together with an improved moldability, impact resistance, and adhesiveness.
    Type: Grant
    Filed: January 29, 1979
    Date of Patent: October 14, 1980
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masaharu Kimura, Norio Sayama, Keiun Ko, Eiichi Yonemitsu
  • Patent number: 4153644
    Abstract: A novel resin composition improved in moldability and impact resistance, comprising (A) a polyphenylene oxide having a molecular weight of 5,000 or higher, (B) an aromatic hydrocarbon-formaldehyde resin or a modified aromatic hydrocarbon-formaldehyde resin, and, if necessary, (C) a rubbery polymer, the weight ratio of the resin (A) to the resin (B) being from 10:90 to 99:1 and the amount of the rubbery polymer (C) being 3 to 40 parts by weight per 100 parts by weight of the sum of the resins (A) and (B). This resin composition has excellent mechanical and electrical properties of the polyphenylene oxide together with an improved moldability, impact resistance, and adhesiveness.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: May 8, 1979
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masaharu Kimura, Norio Sayama, Keiun Ko, Eiichi Yonemitsu
  • Patent number: 4038343
    Abstract: A resin composition comprising (A) 5 to 95 parts by weight of a copolyphenylene ether derived from a mixture of 50 to 98 mole% of a 2,6-dialkylphenol and 2 to 50 mole% of a 2,3,6-trialkylphenol and (B) 5 to 95 parts by weight of a styrene resin. The composition has superior thermal resistance and oxidation stability under heat and satisfactory mechanical properties, and retains these desirable properties after heat-aging. The composition is suitable for preparation of molded articles.
    Type: Grant
    Filed: October 17, 1975
    Date of Patent: July 26, 1977
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Eiichi Yonemitsu, Akitoshi Sugio, Masanobu Masu, Takao Kawaki, Yukio Sasaki
  • Patent number: 3963804
    Abstract: A thermoplastic blend composition having especially superior impact strength and fatigue resistance comprising 15 ro 80% by weight of a polyphenylene oxide, 16 to 75% by weight of a rubber-modified polystyrene, 2 to 15% by weight of an aromatic polycarbonate and 2 to 15% by weight of a high styrene rubber, the sum total of the proportions of these ingredients being 100% by weight.
    Type: Grant
    Filed: April 18, 1974
    Date of Patent: June 15, 1976
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Eiichi Yonemitsu, Akitoshi Sugio, Takanari Nawata, Masanobu Masu, Masaharu Kimura, Norio Sayama