Patents by Inventor Masaru Utsunomiya

Masaru Utsunomiya has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220056208
    Abstract: A polyalkylene ether glycol composition containing a nitrogen-containing compound, wherein the nitrogen-containing compound constitutes 0.2 to 40 mass ppm of the polyalkylene ether glycol in terms of nitrogen atoms. A method for producing the polyalkylene ether glycol composition through a purification step of decreasing the amount of acetal in the polyalkylene ether glycol composition.
    Type: Application
    Filed: November 2, 2021
    Publication date: February 24, 2022
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Ryo YAMASHITA, Yusuke IZAWA, Masaru UTSUNOMIYA
  • Patent number: 10844030
    Abstract: The present invention relates to a method for producing furfural, including: obtaining a sugar solution containing at least one of a monosaccharide having 5 carbon atoms and a polysaccharide containing the monosaccharide having 5 carbon atoms by carrying out a reaction with a specific resource as a raw material in the presence of a catalyst in a solvent; converting at least one of the monosaccharide and the polysaccharide containing the monosaccharide in the sugar solution into furfural by a dehydration reaction, so as to obtain a reaction solution; and separating the reaction solution into an organic layer and an aqueous layer, wherein an aromatic hydrocarbon solvent having a density of from 0.90 g/cm3 to 1.1 g/cm3 at 25° C. and under atmospheric pressure is used, and wherein the reaction solution is separated at a temperature higher than 90° C. and lower than 150° C.
    Type: Grant
    Filed: September 24, 2018
    Date of Patent: November 24, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yusuke Izawa, Yosuke Suzuki, Masaru Utsunomiya
  • Patent number: 10487032
    Abstract: An object of the present invention is to provide high-quality 1,4BG capable of working out to a raw material of PBT with good color tone, by efficiently removing and refining impurities mixed when producing a biomass-derived 1,4BG on an industrial scale and the present invention relates to a production method of refined 1,4BG, where a crude 1,4BG-containing solution is obtained from refined raw material 1,4BG obtained by removing bacterial cells, salt contents and water from the fermentation culture medium, through a step of removing high-boiling-point components and/or low-boiling-point components by distillation and/or a step of converting an unsaturated compound to a hydride and the target product is obtained as a side stream in a further distillation step.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: November 26, 2019
    Assignees: MITSUBISHI CHEMICAL CORPORATION, GENOMATICA, INC.
    Inventors: Masaru Utsunomiya, Yusuke Izawa, Norikazu Konishi, Kota Tanaka, Shinichiro Matsuzono, Takayuki Suzuki, Michael Japs, Mark Burk, Warren Clark
  • Patent number: 10472311
    Abstract: A 1,4-butanediol-containing composition having a concentration of 1,4-butanediol of 99.00% by weight or more and not more than 99.99% by weight and containing 2-pyrrolidone or N-methylpyrrolidone in a concentration, as converted into a nitrogen atom, of from 1.0 to 25 ppm by weight and methods of use thereof.
    Type: Grant
    Filed: May 18, 2016
    Date of Patent: November 12, 2019
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka, Takayuki Suzuki, Shinichirou Matsuzono
  • Patent number: 10450404
    Abstract: At the time of producing a polyester by using a dicarboxylic acid component and a biomass-resource-derived diol as raw materials, a polyester is efficiently produced with good color tone, as the raw material diol derived from biomass resources, a diol in which the content of a cyclic carbonyl compound having a carbon atom number of 5 or 6 is from 0.01 to 12 ppm by mass, is used, and by controlling the content of a cyclic carbonyl compound having a carbon atom number of 5 or 6 in the raw material diol to fall in a prescribed range, the color tone of the polyester is improved.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: October 22, 2019
    Assignees: MITSUBISHI CHEMICAL CORPORATION, Genomatica, Inc.
    Inventors: Masaru Utsunomiya, Yusuke Izawa, Norikazu Konishi, Kota Tanaka, Shinichiro Matsuzono, Takayuki Suzuki, Michael Japs, Mark Burk, Warren Clark
  • Patent number: 10370684
    Abstract: The invention relates to a method for treating a solution containing a saccharide comprising a heat treatment step of heating the saccharide solution at a temperature of 100° C. or higher and 180° C. or lower and a reduction step of reacting a reducing agent with the saccharide solution heated in the heat treatment step, a method for producing a treated saccharide solution using the treatment method, a treated saccharide solution obtained through treatment by the treatment method, a method for producing an organic compound comprising an organic-matter production step of obtaining an organic compound by causing a microorganism capable of producing organic matter to act on an organic raw material containing the treated saccharide solution and a method for culturing a microorganism using the treated saccharide solution as a carbon source.
    Type: Grant
    Filed: September 13, 2016
    Date of Patent: August 6, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kiminori Kawakami, Yasuyo Saito, Takanao Matsumoto, Ryusuke Aoyama, Shigeki Nitta, Masaru Utsunomiya
  • Publication number: 20190023674
    Abstract: The present invention relates to a method for producing furfural, including: obtaining a sugar solution containing at least one of a monosaccharide having 5 carbon atoms and a polysaccharide containing the monosaccharide having 5 carbon atoms by carrying out a reaction with a specific resource as a raw material in the presence of a catalyst in a solvent; converting at least one of the monosaccharide and the polysaccharide containing the monosaccharide in the sugar solution into furfural by a dehydration reaction, so as to obtain a reaction solution; and separating the reaction solution into an organic layer and an aqueous layer, wherein an aromatic hydrocarbon solvent having a density of from 0.90 g/cm3 to 1.1 g/cm3 at 25° C. and under atmospheric pressure is used, and wherein the reaction solution is separated at a temperature higher than 90° C. and lower than 150° C.
    Type: Application
    Filed: September 24, 2018
    Publication date: January 24, 2019
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yusuke IZAWA, Yosuke Suzuki, Masaru Utsunomiya
  • Patent number: 10144687
    Abstract: An object of the present invention is to provide an industrially advantageous production method of 1,4BG, ensuring that generation of THF in the crude 1,4BG can be also suppressed and at the same time, the concentration of 2-(4-hydroxybutoxy)-tetrahydrofuran can be reduced. The present invention relates to a method for producing 1,4-butanediol, comprising heating crude 1,4-butanediol containing from 0.01 to 0.5 wt % of 2-(4-hydroxybutoxy)-tetrahydrofuran and from 1 to 25 wt % of water at 80° C. or more in the presence of an amine to obtain purified 1,4-butanediol.
    Type: Grant
    Filed: January 6, 2014
    Date of Patent: December 4, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Kouta Tanaka, Norikazu Konishi
  • Patent number: 10065938
    Abstract: The present invention relates to a method for producing a hydride having a carbon number of 4, comprising contacting, in liquid phase, an unsaturated compound having a carbon number of 4 as a raw material with a solid catalyst obtained by loading a metal element belonging to Groups 9 to 11 of the long periodic table on a support, thereby performing hydrogenation to produce a corresponding hydride having a carbon number of 4, wherein hydrogenation is performed in the presence of, as a solvent, a 1,4-butanediol having a nitrogen component concentration of 1 ppm by weight to 1 wt % in terms of nitrogen atom.
    Type: Grant
    Filed: June 23, 2016
    Date of Patent: September 4, 2018
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka
  • Patent number: 10023883
    Abstract: Provided are a method for treating a saccharide solution, which comprises subjecting a saccharide solution containing at least one selected from the group consisting of a carbonyl compound and an unsaturated alcohol other than a saccharide to hydrogenation reaction to hydrogenate the carbonyl compound and/or the unsaturated alcohol contained in the saccharide solution, a hydrogenated saccharide solution obtained by treating with the treatment method, and a method for producing an organic compound having a process of obtaining the organic compound by acting a microorganism having an organic material producing ability on an organic raw material containing the hydrogenated saccharide solution.
    Type: Grant
    Filed: December 30, 2015
    Date of Patent: July 17, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kiminori Kawakami, Takanao Matsumoto, Shigeki Nitta, Syuuichi Yunomura, Masaru Utsunomiya, Yuusuke Izawa
  • Patent number: 9695140
    Abstract: An object of the present invention is to provide high-purity gamma-butyrolactone (GBL) capable of preventing occurrence of reaction other than the object at the time of use, which reaction is caused due to a high acidity of GBL, and the present invention relates to a gamma-butyrolactone composition containing gamma-butyrolactone and a nitrogen-containing compound, wherein a content of the gamma-butyrolactone is 99.0% by mass or more, and a total content of the nitrogen-containing compound is 0.1 ppm by mass to 1,000 ppm by mass as converted to a nitrogen atom.
    Type: Grant
    Filed: August 17, 2016
    Date of Patent: July 4, 2017
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shohei Taniguchi, Yusuke Izawa, Masaru Utsunomiya
  • Patent number: 9598388
    Abstract: The present invention is concerned with a method for producing tetrahydrofuran including carrying out a dehydration cyclization reaction of 1,4-butanediol in the presence of an acid catalyst having a pKa value of not more than 4 within a reactor, wherein a raw material liquid containing 1,4-butanediol to be provided for the reaction contains from 0.01 to 0.35% by weight of 2-(4-hydroxybutoxy)-tetrahydrofuran and 1 ppm by weight or more and not more than 1,000 ppm by weight of at least one of an amine and an amide in terms of a concentration as converted into a nitrogen atom.
    Type: Grant
    Filed: January 6, 2014
    Date of Patent: March 21, 2017
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka
  • Patent number: 9556307
    Abstract: The present invention aims to provide a method for producing polybutylene terephthalate (PBT) with an excellent color using biomass-derived 1,4-butanediol (BG). The invention relates to a method for producing PBT comprising a step of subjecting a diol component containing raw material 1,4-BG having a nitrogen content of 0.01 to 50 ppm by mass and a dicarboxylic acid component to esterification or ester-exchange reaction, and a polycondensation reaction step for obtaining PBT from the reactant, wherein the content of gamma butyrolactone in the raw material 1,4-BG is 1 to 100 ppm by mass.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: January 31, 2017
    Assignees: MITSUBISHI CHEMICAL CORPORATION, Genomatica, Inc.
    Inventors: Masaru Utsunomiya, Yusuke Izawa, Norikazu Konishi, Shinichiro Matsuzono, Takayuki Suzuki, Michael Japs, Mark Burk, Warren Clark
  • Publication number: 20160376616
    Abstract: The invention relates to a method for treating a solution containing a saccharide comprising a heat treatment step of heating the saccharide solution at a temperature of 100° C. or higher and 180° C. or lower and a reduction step of reacting a reducing agent with the saccharide solution heated in the heat treatment step, a method for producing a treated saccharide solution using the treatment method, a treated saccharide solution obtained through treatment by the treatment method, a method for producing an organic compound comprising an organic-matter production step of obtaining an organic compound by causing a microorganism capable of producing organic matter to act on an organic raw material containing the treated saccharide solution and a method for culturing a microorganism using the treated saccharide solution as a carbon source.
    Type: Application
    Filed: September 13, 2016
    Publication date: December 29, 2016
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Kiminori KAWAKAMI, Yasuyo Saito, Takanao Matsumoto, Ryusuke Aoyama, Shigeki Nitta, Masaru Utsunomiya
  • Patent number: 9522897
    Abstract: The present invention relates to a method for producing a hydride having a carbon number of 4, comprising contacting, in liquid phase, an unsaturated compound having a carbon number of 4 as a raw material with a solid catalyst obtained by loading a metal element belonging to Groups 9 to 11 of the long periodic table on a support, thereby performing hydrogenation to produce a corresponding hydride having a carbon number of 4, wherein hydrogenation is performed in the presence of, as a solvent, a 1,4-butanediol having a nitrogen component concentration of 1 ppm by weight to 1 wt % in terms of nitrogen atom.
    Type: Grant
    Filed: January 22, 2014
    Date of Patent: December 20, 2016
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka
  • Publication number: 20160355491
    Abstract: An object of the present invention is to provide high-purity gamma-butyrolactone (GBL) capable of preventing occurrence of reaction other than the object at the time of use, which reaction is caused due to a high acidity of GBL, and the present invention relates to a gamma-butyrolactone composition containing gamma-butyrolactone and a nitrogen-containing compound, wherein a content of the gamma-butyrolactone is 99.0% by mass or more, and a total content of the nitrogen-containing compound is 0.1 ppm by mass to 1,000 ppm by mass as converted to a nitrogen atom.
    Type: Application
    Filed: August 17, 2016
    Publication date: December 8, 2016
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shohei Taniguchi, Yusuke Izawa, Masaru Utsunomiya
  • Publication number: 20160297786
    Abstract: The present invention relates to a method for producing a hydride having a carbon number of 4, comprising contacting, in liquid phase, an unsaturated compound having a carbon number of 4 as a raw material with a solid catalyst obtained by loading a metal element belonging to Groups 9 to 11 of the long periodic table on a support, thereby performing hydrogenation to produce a corresponding hydride having a carbon number of 4, wherein hydrogenation is performed in the presence of, as a solvent, a 1,4-butanediol having a nitrogen component concentration of 1 ppm by weight to 1 wt % in terms of nitrogen atom.
    Type: Application
    Filed: June 23, 2016
    Publication date: October 13, 2016
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke IZAWA, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka
  • Publication number: 20160264500
    Abstract: A 1,4-butanediol-containing composition having high thermal stability as compared with conventional 1,4BG, and a 1,4-butanediol-containing composition having a concentration of 1,4-butanediol of 99.00% by weight or more and not more than 99.99% by weight and containing an amide compound in a concentration, as converted into a nitrogen atom, of from 1.0 to 25 ppm by weight.
    Type: Application
    Filed: May 18, 2016
    Publication date: September 15, 2016
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke IZAWA, Masaru UTSUNOMIYA, Norikazu KONISHI, Kouta TANAKA, Takayuki SUZUKI, Shinichirou MATSUZONO
  • Patent number: 9434706
    Abstract: A 1,4-butanediol (1,4BG)-containing composition having high thermal stability, and having a concentration of 1,4-butanediol of 99.00% by weight or more and not more than 99.99% by weight and 2-pyrrolidone or N-methylpyrrolidone in a concentration, as converted into a nitrogen atom, of from 1.0 to 25 ppm by weight.
    Type: Grant
    Filed: January 8, 2014
    Date of Patent: September 6, 2016
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yusuke Izawa, Masaru Utsunomiya, Norikazu Konishi, Kouta Tanaka, Takayuki Suzuki, Shinichirou Matsuzono
  • Publication number: 20160177346
    Abstract: Provided are a method for treating a saccharide solution, which comprises subjecting a saccharide solution containing at least one selected from the group consisting of a carbonyl compound and an unsaturated alcohol other than a saccharide to hydrogenation reaction to hydrogenate the carbonyl compound and/or the unsaturated alcohol contained in the saccharide solution, a hydrogenated saccharide solution obtained by treating with the treatment method, and a method for producing an organic compound having a process of obtaining the organic compound by acting a microorganism having an organic material producing ability on an organic raw material containing the hydrogenated saccharide solution.
    Type: Application
    Filed: December 30, 2015
    Publication date: June 23, 2016
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Kiminori Kawakami, Takanao Matsumoto, Shigeki Nitta, Syuuichi Yunomura, Masaru Utsunomiya, Yuusuke Izawa