Patents by Inventor Masato Kashiwagi
Masato Kashiwagi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7820745Abstract: Disclosed is an aqueous water-repellent/oil-repellent composition containing the following components (A), (B) and (C). Fluorine-containing copolymer (A): a copolymer containing a polymerizable monomer (a1) having a perfluoroalkyl group with 1-6 carbon atoms or a perfluoroalkenyl group wherein the amount of (a1) is not less than 20% by weight relative to the copolymer. Surfactant (B): a surfactant essentially containing a sorbitan ester or an alkylene oxide addition product thereof. Aqueous medium (C): a medium substantially containing water only or water and a water-soluble organic solvent.Type: GrantFiled: August 2, 2005Date of Patent: October 26, 2010Assignee: Daikin Industries, Ltd.Inventor: Masato Kashiwagi
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Patent number: 7754836Abstract: Disclosed is a water- and oil-repellent agent comprising the following fluorine-containing copolymer (A). The fluorine-containing copolymer (A) comprises: (a1) a fluoroalkyl group-containing polymerizable monomer of the formula: wherein Y is a divalent organic group [for example, an aliphatic group having 1 to 10 carbon atoms, an aromatic or cycloaliphatic group having 6 to 10 carbon atoms, a —SO2N(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), a —CON(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), or a —CH2CH(OY1)CH2— group (in which Y1 is a hydrogen atom or an acyl group having 1 to 4 carbon atoms)]; and Rf is a linear or branched fluoroalkyl or fluoroalkenyl group having 1 to 6 carbon atoms; and (a2) vinylidene chloride.Type: GrantFiled: August 30, 2006Date of Patent: July 13, 2010Assignee: Daikin Industries, Ltd.Inventor: Masato Kashiwagi
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Patent number: 7709563Abstract: An aqueous dispersion type fluorine-containing water- and oil-repellent composition containing a polymer of a perfluoroalkyl group-containing ethylenically unsaturated monomer dispersed in an aqueous medium. The composition also contains a nonionic surfactant having an HLB value of at most 11 and a cationic surfactant. A homopolymer of at least one monomer constituting the polymer has Tg of at most 50° C.Type: GrantFiled: January 29, 2002Date of Patent: May 4, 2010Assignee: Daikin Industries, Ltd.Inventors: Kouji Kubota, Takuya Yoshioka, Masato Kashiwagi
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Patent number: 7560506Abstract: A water- and oil-repellent composition consisting of (A) a fluorine-containing copolymer comprising at least 20% by weight (based on the copolymer) of (a1) units derived from a polymerizable monomer having a C1-6 polyfluoroalkyl group or a polyfluoroalkenyl group, (B) a surfactant component comprising as the essential components (b1) a nonionic surfactant having an HLB value of 12 or below and (b2) a nonionic surfactant having an HLB value of 15 or above, and (C) an aqueous medium substantially consisting of water. This composition is free from operationally or environmentally undesirable solvents and superior to conventional ones in stabilities such as mechanical stability, chemical stability, and long-term shelf stability.Type: GrantFiled: April 14, 2005Date of Patent: July 14, 2009Assignee: Daikin Industries, Ltd.Inventor: Masato Kashiwagi
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Publication number: 20070293654Abstract: Disclosed is an aqueous water-repellent/oil-repellent composition containing the following components (A), (B) and (C). Fluorine-containing copolymer (A): a copolymer containing a polymerizable monomer (al) having a perfluoroalkyl group with 1-6 carbon atoms or a perfluoroalkenyl group wherein the amount of (al) is not less than 20% by weight relative to the copolymer. Surfactant (B): a surfactant essentially containing a sorbitan ester or an alkylene oxide addition product thereof. Aqueous medium (C): a medium substantially containing water only or water and a water-soluble organic solvent.Type: ApplicationFiled: August 2, 2005Publication date: December 20, 2007Applicant: DAIKIN INDUSTRIES, LTD.Inventor: Masato Kashiwagi
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Publication number: 20070238812Abstract: A water- and oil-repellent composition consisting of (A) a fluorine-containing copolymer comprising at least 20% by weight (based on the copolymer) of (a1) units derived from a polymerizable monomer having a C1-6 polyfluoroalkyl group or a polyfluoroalkenyl group, (B) a surfactant component comprising as the essential components (b1) a nonionic surfactant having an HLB value of 12 or below and (b2) a nonionic surfactant having an HLB value of 15 or above, and (C) an aqueous medium substantially consisting of water. This composition is free from operationally or environmentally undesirable solvents and superior to conventional ones in stabilities such as mechanical stability, chemical stability, and long-term shelf stability.Type: ApplicationFiled: April 14, 2005Publication date: October 11, 2007Inventor: Masato Kashiwagi
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Patent number: 7217760Abstract: A fluoropolymer-based water-and-oil repellant composition which comprises a copolymer comprising units derived from (a) an ethylenic monomer having a perfluoroalkyl group, (b) an ethylenic monomer having a group comprising an aromatic ring and a halogen atom or halogenomethyl group bonded thereto, and (c) an ethylenic monomer copolymerizable with these. The composition imparts excellent water and oil repellency through cold cure.Type: GrantFiled: March 6, 2002Date of Patent: May 15, 2007Assignee: Daikin Industries, Ltd.Inventors: Takuya Yoshioka, Masato Kashiwagi
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Publication number: 20070088141Abstract: Disclosed is a water- and oil-repellent agent comprising the following fluorine-containing copolymer (A). The fluorine-containing copolymer (A) comprises: (a1) a fluoroalkyl group-containing polymerizable monomer of the formula: ?wherein Y is a divalent organic group [for example, an aliphatic group having 1 to 10 carbon atoms, an aromatic or cycloaliphatic group having 6 to 10 carbon atoms, a —SO2N(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), a —CON(R1)R2— group (in which R1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R2 is an alkylene group having 1 to 10 carbon atoms), or a —CH2CH(OY1)CH2— group (in which Y1 is a hydrogen atom or an acyl group having 1 to 4 carbon atoms)]; and ?Rf is a linear or branched fluoroalkyl or fluoroalkenyl group having 1 to 6 carbon atoms; and (a2) vinylidene chloride.Type: ApplicationFiled: August 30, 2006Publication date: April 19, 2007Inventor: Masato Kashiwagi
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Publication number: 20040147665Abstract: A fluoropolymer-based water-and-oil repellant composition which comprises a copolymer comprising units derived from (a) an ethylenic monomer having a perfluoroalkyl group, (b) an ethylenic monomer having a group comprising an aromatic ring and a halogen atom or halogenomethyl group bonded thereto, and (c) an ethylenic monomer copolymerizable with these. The composition imparts excellent water and oil repellency through cold cure.Type: ApplicationFiled: January 16, 2004Publication date: July 29, 2004Inventors: Takuya Yoshioka, Masato Kashiwagi
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Patent number: 6750277Abstract: A composition comprising (A) a copolymer which comprises (I) repeating units which are derived from a monomer having a fluoroalkyl group, a carbon-carbon double bond, (II) optional repeating units which are derived from a monomer having at least two urethane or urea bonds and a carbon-carbon double bond, but no fluorine atom, (III) optional repeating units which are derived from a monomer, the homopolymer of which having a glass transition temperature (Tg) of 50° C. or less, (IV) optional repeating units which are derived from a monomer having a hydrophilic group and a carbon-carbon double bond, and (V) optional repeating units which are derived from a monomer having a chlorine atom and a carbon-carbon double bond; and (B) a film-forming auxiliary can impart high water and oil repellency by drying at room temperature (0 to 30° C.) without requiring a heat treatment step.Type: GrantFiled: August 19, 1999Date of Patent: June 15, 2004Assignee: Daikin Industries Ltd.Inventors: Masayuki Yamana, Ikuo Yamamoto, Masato Kashiwagi, Koji Kubota
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Publication number: 20040075074Abstract: Excellent water- and oil-repellency performances resulting from low temperature curing are achieved by an aqueous dispersion type fluorine-containing water- and oil-repellent composition containing a polymer of a perfluoroalkyl group-containing ethylenically unsaturated monomer dispersed in an aqueous medium, wherein the composition contains a nonionic surfactant having an HLB value of at most 11 and a cationic surfactant, and a homopolymer of at lest one monomer constituting the polymer has Tg of at most 50° C.Type: ApplicationFiled: July 29, 2003Publication date: April 22, 2004Inventors: Kouji Kubota, Takuya Yoshioka, Masato Kashiwagi
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Patent number: 6074588Abstract: A mold releasing agent comprising a silicon-containing compound represented by the formula:R.sup.1.sub.n SiR.sup.2.sub.4-nwherein R.sup.1 is ##STR1## (R.sup.3 and R.sup.4 are a hydrocarbon group having 1 to 4 carbon atoms), R.sup.2 is a hydrocarbon group having 1 to 4 carbon atoms or a halogenated hydrocarbon group having 1 to 4 carbon atoms, n is 3 or 4, and a silicon- and/or fluorine-containing compound having at least two hydroxyl groups or alkoxyl groups in one molecule. The mold releasing agent of the present invention is excellent in mold releasing property, has a long life, provides a good surface finishing of molded article, and has no influence on secondary processability.Type: GrantFiled: May 15, 1996Date of Patent: June 13, 2000Assignee: Daikin Industries, Ltd.Inventors: Masayuki Yamana, Tomohiro Hosomi, Hirotoshi Sakashita, Masato Kashiwagi
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Patent number: 5804674Abstract: A mold release agent containing (A) a silane compound, (B) a silicon and/or fluorine-containing compound having at least two hydroxyl groups or alkoxy groups in one molecule and (C) a polymer of a perfluoroalkyl group-containing (meth)acrylate ester gives a long mold release life and a good surface finishing property of a molded article, and does not exert a harmful influence on fabricability such as painting and adhesion of the molded article.Type: GrantFiled: April 21, 1997Date of Patent: September 8, 1998Assignee: Daikin Industries, Ltd.Inventors: Masayuki Yamana, Yasushi Nakamae, Hirotoshi Sakashita, Masato Kashiwagi
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Patent number: 5734001Abstract: A novel fluorosilicone compound having at least two hydroxyl groups in its molecule and a curable composition containing such a compound and a commercially available general purpose curing agent; the compound is used suitably for a lubricant and a fiber treating agent, and the curable composition is used suitably for a mold releasing agent, a water- and oil-repelling agent, a stain-proof coating agent, a non-tackifying coating agent, a coating agent for optical use and a sealant.Type: GrantFiled: November 20, 1996Date of Patent: March 31, 1998Assignee: Daikin Industries, Ltd.Inventors: Fumihiko Yamaguchi, Tatsuya Otsuka, Masayuki Yamana, Masato Kashiwagi, Hirotoshi Sakashita
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Patent number: 4877859Abstract: The present invention provides a fluroine-containing novolak resin or its derivative having a repeating unit of the formula ##STR1## wherein R.sup.1 is hydrogen atom, OH or ##STR2## R.sup.2 is hydrogen atom or alkyl group having 1 to 4 carbon atoms, X is fluorine-containing monovalent organic group having 2 to 20 carbon atoms.The present invention also provides a perfluoroalkenyloxphenol or its derivative of the formula ##STR3## wherein R.sup.10 is OH or ##STR4## R.sup.11 is H, OH, alkyl group having 1 to 4 carbon atoms or ##STR5## Y is perfluoroalkenyl group having 6 to 14 carbon atoms.Type: GrantFiled: March 21, 1988Date of Patent: October 31, 1989Assignee: Daikin Industries, Ltd.Inventors: Sinji Tamaru, Motonobu Kubo, Masato Kashiwagi