Patents by Inventor Mason K. Harrup

Mason K. Harrup has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240072302
    Abstract: A solid electrolyte, comprising a solid polymer, ceramic, and/or polymer/ceramic composite materials and a phosphorus-containing plasticizer selected from the group consisting of a phosphazene and a phosphoranimine, which lacks hydroxyl and unstable phosphorus-halogen bonds, is electrochemically stable at a voltage of at least 3.5 V (vs. Li/Li+), and has a flash point of at least 100° C., wherein the solid electrolyte has a lithium ion conductivity of at least 1×10?6 S/cm.
    Type: Application
    Filed: August 25, 2023
    Publication date: February 29, 2024
    Inventor: Mason K. Harrup
  • Publication number: 20220190384
    Abstract: An all-inorganic electrolyte formulation for use in a lithium-ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. The phosphoranimine, phosphazene, and monomeric phosphorus compound preferably do not have any direct halogen-phosphorus bonds. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Application
    Filed: March 5, 2022
    Publication date: June 16, 2022
    Inventor: Mason K. Harrup
  • Patent number: 11271248
    Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. The phosphoranimine, phosphazene, and monomeric phosphorus compound preferably do not have any direct halogen-phosphorus bonds. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Grant
    Filed: July 6, 2020
    Date of Patent: March 8, 2022
    Assignee: New Dominion Enterprises, Inc.
    Inventor: Mason K. Harrup
  • Publication number: 20210043969
    Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. The phosphoranimine, phosphazene, and monomeric phosphorus compound preferably do not have any direct halogen-phosphorus bonds. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Application
    Filed: July 6, 2020
    Publication date: February 11, 2021
    Inventor: Mason K. Harrup
  • Patent number: 10707531
    Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Grant
    Filed: September 27, 2017
    Date of Patent: July 7, 2020
    Assignee: New Dominion Enterprises Inc.
    Inventors: Mason K. Harrup, Jay Fraser
  • Patent number: 10707526
    Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. The phosphoranimine, phosphazene, and monomeric phosphorus compound preferably do not have any direct halogen-phosphorus bonds. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Grant
    Filed: March 28, 2016
    Date of Patent: July 7, 2020
    Assignee: New Dominion Enterprises Inc.
    Inventor: Mason K. Harrup
  • Patent number: 9761910
    Abstract: An electrolyte solution comprising at least one phosphoranimine compound and a metal salt. The at least one phosphoranimine compound comprises a compound of the chemical structure where X is an organosilyl group or a tert-butyl group and each of R1, R2, and R3 is independently selected from the group consisting of an alkyl group, an aryl group, an alkoxy group, or an aryloxy group. An energy storage device including the electrolyte solution is also disclosed.
    Type: Grant
    Filed: May 22, 2015
    Date of Patent: September 12, 2017
    Assignee: Battelle Energy Alliance, LLC
    Inventors: John R. Klaehn, Eric J. Dufek, Harry W. Rollins, Mason K. Harrup, Kevin L. Gering
  • Publication number: 20170179530
    Abstract: An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.
    Type: Application
    Filed: March 9, 2017
    Publication date: June 22, 2017
    Inventors: Kevin L. Gering, Mason K. Harrup, Harry W. Rollins
  • Publication number: 20170110761
    Abstract: An ion transporting solvent for use with batteries can be improved by simultaneously shortening a phosphazene compound's pendent groups, eliminating most or all of the distal ion carriers, and randomizing the solvent molecules so as to intentionally disrupt symmetry to the maximum degree possible. The combination of these strategies dramatically improves battery performance to the point where the performance recorded is comparable to batteries using conventional organic solvents.
    Type: Application
    Filed: December 27, 2016
    Publication date: April 20, 2017
    Applicant: PRINCESS ENERGY SYSTEMS, INC.
    Inventors: John L. Burba, III, Mason K. Harrup, Thomas A. Luther
  • Publication number: 20160294013
    Abstract: An ion transporting solvent for use with batteries can be improved by simultaneously shortening a phosphazene compound's pendent groups, eliminating most or all of the distal ion carriers, and randomizing the solvent molecules so as to intentionally disrupt symmetry to the maximum degree possible. The combination of these strategies dramatically improves battery performance to the point where the performance recorded is comparable to batteries using conventional organic solvents.
    Type: Application
    Filed: June 7, 2016
    Publication date: October 6, 2016
    Applicant: PRINCESS ENERGY SYSTEMS, INC.
    Inventors: John L. Burba, III, Mason K. Harrup, Thomas A. Luther
  • Publication number: 20160285132
    Abstract: An ion transporting solvent for use with batteries can be improved by simultaneously shortening a phosphazene compound's pendent groups, eliminating most or all of the distal ion carriers, and randomizing the solvent molecules so as to intentionally disrupt symmetry to the maximum degree possible. The combination of these strategies dramatically improves battery performance to the point where the performance recorded is comparable to batteries using conventional organic solvents.
    Type: Application
    Filed: June 7, 2016
    Publication date: September 29, 2016
    Applicant: PRINCESS ENERGY SYSTEMS, INC.
    Inventors: John L. Burba, III, Mason K. Harrup, Thomas A. Luther
  • Publication number: 20160285125
    Abstract: An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. The phosphoranimine, phosphazene, and monomeric phosphorus compound preferably do not have any direct halogen-phosphorus bonds. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ?80° C.
    Type: Application
    Filed: March 28, 2016
    Publication date: September 29, 2016
    Inventor: Mason K. Harrup
  • Publication number: 20160056506
    Abstract: An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.
    Type: Application
    Filed: November 2, 2015
    Publication date: February 25, 2016
    Inventors: KEVIN L. GERING, MASON K. HARRUP, HARRY W. ROLLINS
  • Patent number: 9206210
    Abstract: An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.
    Type: Grant
    Filed: October 5, 2011
    Date of Patent: December 8, 2015
    Assignee: BATTELLE ENERGY ALLIANCE, LLC
    Inventors: Kevin L. Gering, Mason K. Harrup, Harry W. Rollins
  • Publication number: 20150340739
    Abstract: An electrolyte solution comprising at least one phosphoranimine compound and a metal salt. The at least one phosphoranimine compound comprises a compound of the chemical structure where X is an organosilyl group or a tert-butyl group and each of R1, R2, and R3 is independently selected from the group consisting of an alkyl group, an aryl group, an alkoxy group, or an aryloxy group. An energy storage device including the electrolyte solution is also disclosed.
    Type: Application
    Filed: May 22, 2015
    Publication date: November 26, 2015
    Inventors: JOHN R. KLAEHN, ERIC J. DUFEK, HARRY W. ROLLINS, MASON K. HARRUP, KEVIN L. GERING
  • Publication number: 20140079955
    Abstract: An additive comprising a phosphazene compound that has at least two reactive functional groups and at least one capping functional group bonded to phosphorus atoms of the phosphazene compound. One of the at least two reactive functional groups is configured to react with cellulose and the other of the at least two reactive functional groups is configured to react with a resin, such as an amine resin or a polycarboxylic acid resin. The at least one capping functional group is selected from the group consisting of a short chain ether group, an alkoxy group, and an aryloxy group. Also disclosed are an additive-resin admixture, a method of treating a wood product, and a wood product.
    Type: Application
    Filed: November 20, 2013
    Publication date: March 20, 2014
    Applicant: Battelle Energy Alliance, LLC
    Inventors: Mason K. Harrup, Harry W. Rollins
  • Patent number: 8592628
    Abstract: An additive comprising a phosphazene compound that has at least two reactive functional groups and at least one capping functional group bonded to phosphorus atoms of the phosphazene compound. One of the at least two reactive functional groups is configured to react with cellulose and the other of the at least two reactive functional groups is configured to react with a resin, such as an amine resin or a polycarboxylic acid resin. The at least one capping functional group is selected from the group consisting of a short chain ether group, an alkoxy group, and an aryloxy group. Also disclosed are an additive-resin admixture, a method of treating a wood product, and a wood product.
    Type: Grant
    Filed: May 27, 2011
    Date of Patent: November 26, 2013
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Mason K. Harrup, Harry W. Rollins
  • Publication number: 20130089793
    Abstract: An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.
    Type: Application
    Filed: October 5, 2011
    Publication date: April 11, 2013
    Applicant: BATTELLE ENERGY ALLIANCE, LLC
    Inventors: Kevin L. Gering, Mason K. Harrup, Harry W. Rollins
  • Publication number: 20120088162
    Abstract: An ion transporting solvent for use with batteries can be improved by simultaneously shortening a phosphazene compound's pendent groups, eliminating most or all of the distal ion carriers, and randomizing the solvent molecules so as to intentionally disrupt symmetry to the maximum degree possible. The combination of these strategies dramatically improves battery performance to the point where the performance recorded is comparable to batteries using conventional organic solvents.
    Type: Application
    Filed: May 13, 2011
    Publication date: April 12, 2012
    Inventors: Mason K. Harrup, Thomas A. Luther, John Leslie Burba
  • Patent number: 8124414
    Abstract: A taggant comprising at least one perfluorocarbon compound surrounded by a polyphosphazene compound. The polyphosphazene compound has the chemical structure: wherein G1 and G2 are pendant groups having different polarities, m is an integer greater than or equal to 100, and each of A and B is independently selected from hydrogen, an alkyl, an alkene, an alkoxide, a polyether, a polythioether, a siloxane, and —X(CH2)nY1(CH2)p1Y2(CH2)p2 . . . Yi(CH2)piCH3, where n ranges from 1 to 6, X and Y are independently selected from oxygen, sulfur, selenium, tellurium, and polonium, and p1 through pi range from 1 to 6. Cyclic polyphosphazene compounds lacking the A and B groups are also disclosed, as are methods of forming the taggant and of detecting an object.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: February 28, 2012
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Mason K. Harrup, Frederick F. Stewart, Mark L. Stone