Abstract: Terpene-based spotting fluid compositions and processes for freeing differentially stuck pipe are provided. A spotting fluid composition includes a terpene and an acid, such that the acid initiates an exothermic polymerization reaction of the terpene. Another spotting fluid composition includes an invert emulsion having a terpene external phase and a non-miscible organic hygroscopic fluid internal phase. The terpene emulsion spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts a filter cake surrounding the portion of the differentially stuck pipe. An acid may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the acid initiates an exothermic polymerization reaction of the terpene of the terpene emulsion spotting fluid composition.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: Terpene-based spotting fluid compositions and processes for freeing differentially stuck pipe are provided. A spotting fluid composition includes a terpene and an acid, such that the acid initiates an exothermic polymerization reaction of the terpene. Another spotting fluid composition includes an invert emulsion having a terpene external phase and a non-miscible organic hygroscopic fluid internal phase. The terpene emulsion spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts a filter cake surrounding the portion of the differentially stuck pipe. An acid may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the acid initiates an exothermic polymerization reaction of the terpene of the terpene emulsion spotting fluid composition.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: The present disclosure relates to the creation of emulsifiers for use in an oil-based drilling mud. The disclosed emulsifiers may be created by the reaction of synthetic linear saturated fatty acids and polyamines under the conditions specified. The synthesized product may be used as a replacement for the wetting agent in conventional muds. Further improvements in conventional drilling muds are also disclosed where the synthesized product is used to replace incumbent wetting agents and the primary emulsifiers are replaced by synthetic fatty acids.

Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.

Abstract: This document relates to non-aqueous compositions including a maleic anhydride copolymer and a polyamine or polyaziridine crosslinker. The maleic anhydride copolymer includes repeat units I and II: Each R1 is independently —H, —(C1-C5)alkyl, —C?O(O)(C1-C5)alkyl, or aryl; and each R2 is independently —H, —(C1-C5)alkyl, —C?O(O)(C1-C5)alkyl, and aryl.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gelling agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently —NH2 or —OM1. The gelling agent includes at least one of: a calcium chelating agent, a calcium precipitating agent, a pH buffer, an agent reactive with hydroxide, and an acid generating agent, and promotes formation of a gel from the maleic anhydride copolymer and the amine crosslinker in contact with set cement.

Abstract: The present application provides a composition containing a maleic anhydride copolymer, a polyaziridine crosslinker, optionally an additional crosslinking agent such as an amine crosslinker, and optionally a gel time control agent. Methods of using the composition to treat a subterranean formation are also provided.

Abstract: The present disclosure relates to the creation of emulsifiers for use in an oil-based drilling mud. The disclosed emulsifiers may be created by the reaction of synthetic linear saturated fatty acids and polyamines under the conditions specified. The synthesized product may be used as a replacement for the wetting agent in conventional muds. Further improvements in conventional drilling muds are also disclosed where the synthesized product is used to replace incumbent wetting agents and the primary emulsifiers are replaced by synthetic fatty acids.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gel time control agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently —NH2 or —OM1. The gel time control agent accelerates or retards formation of a gel from the composition compared to a composition having the same percentage by weight of the maleic anhydride copolymer and the amine crosslinker in the absence of the gel time control agent.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer and an aminosilane crosslinker. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently —NH2 or —OM1. The aminosilane crosslinker has at least one primary amine group. Siloxane bonds may be formed between the aminosilane crosslinker and a siliceous material in contact with the gelled composition in the subterranean formation.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gelling agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently —H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently —NH2 or —OM1. The gelling agent includes at least one of: a calcium chelating agent, a calcium precipitating agent, a pH buffer, an agent reactive with hydroxide, and an acid generating agent, and promotes formation of a gel from the maleic anhydride copolymer and the amine crosslinker in contact with set cement.

Abstract: The present application provides a composition containing a maleic anhydride copolymer, a polyaziridine crosslinker, optionally an additional crosslinking agent such as an amine crosslinker, and optionally a gel time control agent. Methods of using the composition to treat a subterranean formation are also provided.

Abstract: Terpene-based spotting fluid compositions and processes for freeing differentially stuck pipe are provided. A spotting fluid composition includes a terpene and an acid, such that the acid initiates an exothermic polymerization reaction of the terpene. Another spotting fluid composition includes an invert emulsion having a terpene external phase and a non-miscible organic hygroscopic fluid internal phase. The terpene emulsion spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts a filter cake surrounding the portion of the differentially stuck pipe. An acid may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the acid initiates an exothermic polymerization reaction of the terpene of the terpene emulsion spotting fluid composition.