Patents by Inventor Matthias Kroner

Matthias Kroner has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5830985
    Abstract: A process for preparing polyaspartic acid by polycondensation of fine-particle aspartic acid at temperatures above 150.degree. C. in the presence of acidic catalysts, wherein first contact between the acidic catalysts and the fine-particle aspartic acid takes place in the reaction zone where the polycondensation takes place.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: November 3, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Hans-Jacob Feindt, Thomas Meyer, Alfons Ludwig, Udo Metzmann
  • Patent number: 5817721
    Abstract: A biodegradable polyester obtainable by reacting a mixture comprising(a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising(b1) a mixture comprising35-95 mol % of adipic acid or ester-forming derivatives thereof,5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and0-5 mol % of a compound containing sulfonate groups, and(b2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1,(a2) from 0.1 to 5% by weight of a divinyl ether C1 and(a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D,and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: October 6, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Rainer Buschl
  • Patent number: 5770553
    Abstract: The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120.degree. C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: June 23, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5756839
    Abstract: A process is disclosed for preparing D,L-aspartic acid by beating aqueous solutions of ammonium salts of the maleic acid. The molar ratio of maleic acid to ammonia ranges from 1:1 to 1:50. The process is carried out at temperatures from 60.degree. to 250.degree. C. and pressures of at least 1 bar. The pressure applied during the reaction is adjusted to ensure that the reaction mixture is almost completely present in liquid phase. Excess ammonia is removed and the reaction solution is acidified so as to release D,L-aspartic acid, which is then isolated.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Detlef Kratz, Tom Witzel, Rudolf Bazner, Matthias Kroner, Uwe Pressler
  • Patent number: 5756594
    Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
  • Patent number: 5747635
    Abstract: Modified polyaspartic acids useful as detergent and cleaner additives, as water treatment agents and as scale inhibitors in the evaporation of sugar juice are obtainable by polycondensation of(a) from 1 to 99.9 mol % of aspartic acid with(b) from 99 to 0.1 mol % of fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugarcarboxylic acids and/or non-proteinogenic aminocarboxylic acidsor by polymerizing monoethylenically unsaturated monomers in the presence of polyaspartic acids in the manner of a free-radically initiated graft polymerization.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: May 5, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Angelika Funhoff, Richard Baur, Alexander Kud, Volker Schwendemann, Birgit Potthoff-Karl, Karl-Heinz Buechner
  • Patent number: 5710327
    Abstract: Modified polyaspartic acids are prepared by condensing aspartic acid with polybasic carboxylic acids or anhydrides of polybasic carboxylic acids and ammonia without a diluent at temperatures of at least 140.degree. C. in the absence of inorganic acids.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: January 20, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick
  • Patent number: 5665693
    Abstract: Use of carboxyl-containing reaction products of(a) maleic anhydride, maleic acid and/or fumaric acid, and(b) proteins or protein hydrolyzateshaving an acid number of at least 1.5 mmol of NaOH/g of reaction product, as ingredient of reduced-phosphate and phosphate-free detergents and cleaners.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 9, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5656646
    Abstract: Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: August 12, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Perner, Paul Diessel, Helmut Guembel, Walter Denzinger, Heinrich Hartmann, Matthias Kroner
  • Patent number: 5639832
    Abstract: Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C.sub.1 -C.sub.30 -fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Dieter Boeckh, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Christian Schade, Alexander Kud
  • Patent number: 5639723
    Abstract: Reaction products of polybasic acids and amino-containing compounds, which are obtainable by heating a mixture of (a) a polybasic carboxylic acid selected from the group consisting of citric acid, isocitric acid, aconitic acid, itaconic acid and/or tartaric acid and (b) an amino-containing compound in a molar ratio of (a) to (b) of from 1:0.1 to 1:10 to at least 80.degree. C. are used as additives in low-phosphate and phosphate-free detergents and cleaning agents.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5576407
    Abstract: Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of(a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether,(b) from 1 to 99% by weight of an adduct of a C.sub.2 -C.sub.4 -alkylene oxide with a hydroxyalkyl vinyl ether and(c) from 0 to 98% by weight of other copolymerizable monomers,and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: November 19, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Gerhard Wolf, Richard Baur, Paul Diessel, Hans-Ulrich Jaeger, Volker Schwendemann, Johannes Perner
  • Patent number: 5574113
    Abstract: Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: November 12, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Walter Denzinger, Richard Baur, Alexander Kud, Birgit Potthoff-Karl, Volker Schwendemann
  • Patent number: 5548036
    Abstract: Process for the preparation of polymers of aspartic acid by reacting (a) maleic anhydride and (b) ammonia and/or primary or secondary amines without diluent in the (a):(b) molar ratio of 1:0.1 to 1:3 to give monoamides of maleic acid, fumaric acid or their ammonium salts at up to 100.degree. C. and subsequent condensation of the reaction products, with or without compounds capable of cocondensation, at above 100.degree. C. and, where appropriate, hydrolysis of the condensates and use of the polymers as scale inhibitor, as dispersants for pigments and as additive to detergents and cleaners.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: August 20, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Gunnar Schornick, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Alexander Kud
  • Patent number: 5540663
    Abstract: Use of polyacetals containing acetaldehyde acetal units, and of mixtures of these polyacetals with fillers, for preparing compostable moldings, as coating and as adhesive, and also diapers with an outer layer comprising polyacetals containing acetaldehyde acetal units in the form of a compostable film or a compostable coating.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: July 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Karl-Heinz Schumacher, Eckehardt Wistuba
  • Patent number: 5520834
    Abstract: Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of(a) compounds containing at least 3 hydroxyl groups, and(b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of(c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: May 28, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Johannes Perner, Hans-Ulrich Jaeger, Paul Diessel, Richard Baur, Volker Schwendemann
  • Patent number: 5514288
    Abstract: A method for the pretreatment of fabrics and textiles to impart soil release properties thereto involves contacting the fabrics with homopolymers or copolymers of vinyl ethers.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: May 7, 1996
    Assignee: BASF Corporation
    Inventors: Richard J. Holland, Kathleen M. Guiney, Richard Baur, Matthias Kroner
  • Patent number: 5504189
    Abstract: Antitumor peptides of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the meanings stated in the description, and the preparation thereof.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: April 2, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Emling, Andreas Haupt, Michael Kluge, Matthias Kroner, Gerhard Haas, Ulrich Schmidt, Helmut Griesser, Bernd Riedl
  • Patent number: 5488095
    Abstract: Condensation products that contain N,O-acetal or carboxamide structures and are useful as detergent and cleaner additives are obtainable by condensation of(a) compounds that contain at least one unit of the structural elements ##STR1## where X is OH or NHR and R is C.sub.1 -C.sub.6 -alkyl or --CH.sub.2 --COOH, with(b) aldehydes, ketones or aldehyde- or keto-carboxylic acids to form acetal-lactones, and subsequent cleavage of the acetal-lactones with(c) aminocarboxylic acids, primary or secondary amines and/or polyethyleneimines.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: January 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Angelika Funhof, Matthias Kroner, Heinrich Hartmann, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5466762
    Abstract: There are described block copolyacetals obtainable by cationically initiated polyaddition of(A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and(B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule.in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Volker Schwendemann, Heinrich Hartmann