Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: Vacuum insulated glass units having layered pillars. The glass units include two glass panes and an edge seal between the glass panes with a substantial vacuum gap between them. A plurality of pillars are located between the glass panes as spacers to maintain the vacuum gap. The pillars have a sintered ceramic, alpha alumina, or zirconia body with a tapered sidewall and a functional layer on a surface of the body.

Abstract: A multilayer optical film (130) has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film Heating elements (122) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered regions of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered regions to pattern the film The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g.

Abstract: Pillar delivery films for vacuum insulated glass units are disclosed. The delivery films include a support film or pocket tape, a sacrificial material on the support film, and a plurality of pillars. The pillars are at least partially embedded in the sacrificial material or formed within sacrificial material molds, and the sacrificial material is capable of being removed while leaving the pillars substantially intact. Methods of transferring pillars to a substrate using the pillar delivery films are disclosed. In order to make an insulated glass unit, the delivery films are laminated to a receptor such as a glass pane, and the support film and sacrificial material are removed to leave the pillars remaining on the glass.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: Methods of making articles using structured tapes are disclosed. The structured tapes may include a structured template layer having a structured surface and an opposed second surface and an uncured backfill layer, the uncured backfill layer has a lower refractive index than the structured template layer, and the uncured backfill layer has a structured surface conforming to the structured surface of the structured template layer and an opposed second surface. The structured tapes may include a structured template layer having a structured surface and an opposed second surface and an uncured backfill layer, the uncured backfill layer has a higher refractive index than the structured template layer, and the uncured backfill layer has a structured surface conforming to the structured surface of the structured template layer and an opposed second surface. The structure tapes may be laminated via the uncured backfill layer to a receptor substrate to form an article.

Abstract: A microstructured article includes a nanovoided layer having opposing first and second major surfaces, the first major surface being microstructured to form prisms, lenses, or other features. The nanovoided layer includes a polymeric binder and a plurality of interconnected voids, and optionally a plurality of nanoparticles. A second layer, which may include a viscoelastic layer or a polymeric resin layer, is disposed on the first or second major surface. A related method includes disposing a coating solution onto a substrate. The coating solution includes a polymerizable material, a solvent, and optional nanoparticles. The method includes polymerizing the polymerizable material while the coating solution is in contact with a microreplication tool to form a microstructured layer. The method also includes removing solvent from the microstructured layer to form a nanovoided microstructured article.

Abstract: Lamination transfer films and methods for transferring a structured layer to a receptor substrate. The transfer films include a carrier substrate having a releasable surface, a sacrificial template layer applied to the releasable surface of the carrier substrate and having a non-planar structured surface, and a thermally stable backfill layer applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer is capable of being removed from the backfill layer, such as via pyrolysis, while leaving the structured surface of the backfill layer substantially intact.

Abstract: Articles and methods of making light redirecting film constructions including a micro structured optical film bonded in selected areas to another film, and including a diffuser are described. The diffuser has an optical haze in the range of (20) to (85) percent and an optical clarity of no greater than (50) percent. The diffuser may be a surface diffuser and may be an asymmetric surface diffuser.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: Pillar delivery films for vacuum insulated glass units are disclosed. The delivery films include a support film or pocket tape, a sacrificial material on the support film, and a plurality of pillars. The pillars are at least partially embedded in the sacrificial material or formed within sacrificial material molds, and the sacrificial material is capable of being removed while leaving the pillars substantially intact. Methods of transferring pillars to a substrate using the pillar delivery films are disclosed. In order to make an insulated glass unit, the delivery films are laminated to a receptor such as a glass pane, and the support film and sacrificial material are removed to leave the pillars remaining on the glass.

Abstract: Inorganic multilayer lamination transfer films, methods of forming these lamination transfer films, and methods of using these lamination transfer films. These inorganic multilayer lamination transfer films can have alternating layers including inorganic nanoparticles, sacrificial materials, and optionally inorganic precursors that can be densified to form an inorganic optical stack. Receptor substrates, such as glass or metal, are laminated to the multilayer lamination transfer films.

Abstract: Lamination transfer films and methods for transferring a structured layer to a receptor substrate. The transfer films include a carrier substrate having a releasable surface, a sacrificial template layer applied to the releasable surface of the carrier substrate and having a non-planar structured surface, and a thermally stable backfill layer applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer is capable of being removed from the backfill layer, such as via pyrolysis, while leaving the structured surface of the backfill layer substantially intact.

Abstract: A transfer film is provided which includes a sacrificial template layer having a first surface and a second surface opposite the first surface, wherein the second surface comprises a non-planar structured surface and a thermally stable backfill layer applied to the second surface of the sacrificial template layer, wherein the backfill layer has a structured surface corresponding with and applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer comprises oriented dimensionally anisotropic inorganic nanomaterials and is capable of being removed from the backfill layer while leaving the structured surface of the backfill layer and the oriented dimensionally anisotropic inorganic nanomaterials substantially intact.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form an electrical stack are disclosed. The transfer films (100) may include a plurality of co-extensive electrical protolayers (22, 23, 24) forming an electrical protolayer stack (20), at least selected or each electrical protolayer independently comprising at least 25 wt % sacrificial material and a thermally stable material and having a uniform thickness of less than 25 micrometers. The transfer films may include a plurality of co-extensive electrical protolayers forming an electrical protolayer stack, at least selected or each protolayer independently exhibiting a complex viscosity of between 103 and 104 Poise at a shear rate of 100/s when heated to a temperature between its Tg and Tdec.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form bridged nanostructures are disclosed.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films that include antireflective structures are disclosed.

Abstract: A transfer tape is disclosed that includes a carrier, a template layer having a first surface applied to the carrier and having a second surface opposite the first surface, wherein the second surface comprises a non-planar structured surface, a release coating disposed upon the non-planar structured surface of the template layer, and a backfill layer disposed upon and conforming to the non-planar structured surface of the release coating. In some embodiments, the backfill layer includes a silsesquioxane such as polyvinyl silsesquioxane. The disclosed transfer tape can be used to transfer replicated structures to a receptor substrate.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form an inorganic optical stack are disclosed.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.