Abstract: A method of making an interconnect for a solid oxide fuel cell stack includes providing a chromium alloy interconnect and providing a nickel mesh in contact with a fuel side of the interconnect. Formation of a chromium oxide layer is reduced or avoided in locations between the nickel mesh and the fuel side of the interconnect. A Cr—Ni alloy or a Cr—Fe—Ni alloy is located at least in the fuel side of the interconnect under the nickel mesh.

Abstract: A cross-flow interconnect and a fuel cell stack including the same, the interconnect including fuel inlets and outlets that extend through the interconnect adjacent to opposing first and second peripheral edges of the interconnect; an air side; and an opposing fuel side. The air side includes an air flow field including air channels that extend in a first direction, from a third peripheral edge of the interconnect to an opposing fourth peripheral edge of the interconnect; and riser seal surfaces disposed on two opposing sides of the air flow field and in which the fuel inlets and outlets are formed. The fuel side includes a fuel flow field including fuel channels that extend in a second direction substantially perpendicular to the first direction, between the fuel inlets and outlets; and a perimeter seal surface surrounding the fuel flow field and the fuel inlets and outlets.

Abstract: A solid oxide fuel cell system and method including a hotbox containing a fuel cell stack, a fuel supply configured to provide a fuel to the fuel cell stack, and a hydrogen supply thermally integrated with the hotbox. The hydrogen supply is configured to produce hydrogen during or shortly after the SOFC system is shutdown using residual heat of the hot box, and to provide the hydrogen to the SOFC stack such that an anode reducing environment is maintained in the stack.

Abstract: Solid oxide fuel cells and methods for fabricating solid oxide fuel cells include an electrolyte reinforcement (ERI) layer. An ink composition including a ceramic material and a sintering aid, such as a metal or metal oxide material, is applied to select portions of a solid oxide electrolyte and sintered to form an ERI layer. The ERI layer may improve the strength and durability of the electrolyte and may facilitate bonding to a high-temperature seal.

Abstract: A solid oxide fuel cell (SOFC) includes a solid oxide electrolyte with a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes a ceria-based ceramic component and an electrically conductive component. Another SOFC includes a solid oxide electrolyte containing a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes an electrically conductive component and an ionically conductive component, in which the ionically conductive component includes a zirconia-based ceramic containing scandia and at least one of ceria, ytterbia and yttria.

Abstract: A system and method in which a high temperature fuel cell stack exhaust stream is recycled back into the fuel inlet stream of the high temperature fuel cell stack. The recycled stream may be sent to a carbon dioxide separator that separates carbon dioxide from the fuel exhaust stream. The carbon dioxide separator may include a carbon dioxide separation membrane, an oxygen blocking membrane, and a water blocking membrane.

Abstract: A solid oxide fuel cell (SOFC) includes a solid oxide electrolyte with a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes a ceria-based ceramic component and an electrically conductive component. Another SOFC includes a solid oxide electrolyte containing a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes an electrically conductive component and an ionically conductive component, in which the ionically conductive component includes a zirconia-based ceramic containing scandia and at least one of ceria, ytterbia and yttria.

Abstract: A solid oxide fuel cell, system including the same, and method of using the same, the fuel cell including an electrolyte disposed between an anode and a cathode. The anode includes a first layer including a metallic phase and a ceramic phase, and a second layer including a metallic phase. The metallic phase of the second layer includes a metal catalyst and a dopant selected from Al, Ca, Ce, Cr, Fe, Mg, Mn, Nb, Pr, Ti, V, W, or Zr, any oxide thereof, or any combination thereof. The second layer may also include a ceramic phase including ytterbia-ceria-scandia-stabilized zirconia (YCSSZ).

Abstract: A system and method in which a high temperature fuel cell stack exhaust stream is recycled back into the fuel inlet stream of the high temperature fuel cell stack. The recycled stream may be sent to a carbon dioxide separator that separates carbon dioxide from the fuel exhaust stream. The carbon dioxide separator may include a carbon dioxide separation membrane, an oxygen blocking membrane, and a water blocking membrane.

Abstract: A carbon dioxide membrane structure, a method of making the same, and a carbon dioxide separator including the same. The membrane structure may include a carbon dioxide separation membrane containing PVA and a carrier, and a polysulfone-based support having an average pore size ranging from about 40 to about 90 ?m.

Abstract: A method of making an interconnect for a solid oxide fuel cell stack includes providing a chromium alloy interconnect and providing a nickel mesh in contact with a fuel side of the interconnect. Formation of a chromium oxide layer is reduced or avoided in locations between the nickel mesh and the fuel side of the interconnect. A Cr—Ni alloy or a Cr—Fe—Ni alloy is located at least in the fuel side of the interconnect under the nickel mesh.

Abstract: A chromium-iron interconnect includes at least one of Fe rich regions in the interconnect and carbon in the interconnect.

Abstract: A solid oxide fuel cell system and method including a hotbox containing a fuel cell stack, a fuel supply configured to provide a fuel to the fuel cell stack, and a hydrogen supply thermally integrated with the hotbox. The hydrogen supply is configured to produce hydrogen during or shortly after the SOFC system is shutdown using residual heat of the hot box, and to provide the hydrogen to the SOFC stack such that an anode reducing environment is maintained in the stack.

Abstract: A method of making an interconnect for a solid oxide fuel cell stack includes providing a chromium alloy interconnect and providing a nickel mesh in contact with a fuel side of the interconnect. Formation of a chromium oxide layer is reduced or avoided in locations between the nickel mesh and the fuel side of the interconnect. A Cr—Ni alloy or a Cr—Fe—Ni alloy is located at least in the fuel side of the interconnect under the nickel mesh.

Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte and an anode electrode containing a first portion having a cermet containing a nonzero volume percent of a nickel containing phase and a nonzero volume percent of a ceramic phase and a second portion having a cermet containing a nonzero volume percent of a nickel containing phase and a nonzero volume percent of a ceramic phase, such that the first portion is located between the electrolyte and the second portion. The SOFC is an electrolyte-supported SOFC and the first portion of the anode electrode contains a lower ratio of the nickel containing phase to the ceramic phase than the second portion of the anode electrode. The first portion of the anode electrode has a porosity of 5-30 volume percent and the second portion of the anode electrode has a porosity of 31-60 volume percent.

Abstract: Various embodiments include methods of fabricating an interconnect for a fuel cell stack. Methods for controlled pre-oxidation of an interconnect include oxidizing in a nitride-inhibiting environment to inhibit the formation of nitrides.

Abstract: Solid oxide fuel cells and methods for fabricating solid oxide fuel cells include an electrolyte reinforcement (EM) layer. An ink composition including a ceramic material and a sintering aid, such as a metal or metal oxide material, is applied to select portions of a solid oxide electrolyte and sintered to form an EM layer. The EM layer may improve the strength and durability of the electrolyte and may facilitate bonding to a high-temperature seal.

Abstract: Methods and systems for oxidizing an interconnect for a fuel cell stack include introducing at least one interconnect to an oxidizing gas containing water vapor, the oxidizing gas being at least substantially free of nitrogen, and oxidizing the at least one interconnect in the presence of the oxidizing gas at an elevated temperature. The oxidation may be performed at a sub-atmospheric pressure. The oxidation of the interconnect may be a controlled oxidation that is performed prior to incorporating the interconnect into a fuel cell stack.

Abstract: A system and method in which a high temperature fuel cell stack exhaust stream is recycled back into the fuel inlet stream of the high temperature fuel cell stack. The recycled stream may be sent to a carbon dioxide separator that separates carbon dioxide from the fuel exhaust stream. The carbon dioxide separator may include a carbon dioxide separation membrane, an oxygen blocking membrane, and a water blocking membrane.

Abstract: A solid oxide fuel cell (SOFC) includes a solid oxide electrolyte with a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes a ceria-based ceramic component and an electrically conductive component. Another SOFC includes a solid oxide electrolyte containing a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes an electrically conductive component and an ionically conductive component, in which the ionically conductive component includes a zirconia-based ceramic containing scandia and at least one of ceria, ytterbia and yttria.