Abstract: A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C.

Abstract: A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C.

Abstract: A method for separating hydrogen from a high pressure gas containing hydrogen and carbon dioxide using a vanadium/nickel alloy membrane having a palladium coating, the membrane containing from zero up to about 10 atomic percent nickel, and having a thickness of from about 75 to about 500 microns. The membrane is employed at a temperature of from about 300 to about 440° C., under a pressure of from about 250 to about 500 psia, and a hydrogen partial pressure gradient across the membrane is maintained to provide a hydrogen partial pressure on the permeate side of the membrane of from about 0.02 to about 2 psia.

Abstract: Composite hydrogen transport membranes used for extraction of hydrogen from gas mixtures are provided. Membranes are described comprising metals and metal alloys which exhibit high hydrogen permeability and which exhibit resistance to differential pressures across the membrane and wherein the metals and alloys are protected from embrittlement by hydrogen. Support materials of the membranes are selected in some cases to be lattice matched to the metals and alloys. In specific embodiments, membranes useful in the invention contain binary, ternary or quaternary alloys of vanadium which exhibit high hydrogen permeability and improved strength and/or longevity in application.