Patents by Inventor Michael W. Helioff
Michael W. Helioff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5605685Abstract: This invention relates to an acidic non-irritating lotion, cream or ointment for rejuvenating skin and hair which comprises a micronized, homogenized hydrogel of a crosslinked N-vinyl lactam polymer and an organic rejuvenating agent selected from the group consisting of pyruvic acid, a mono- or poly-carboxylated C.sub.1 to C.sub.20 hydrocarbon optionally substituted with from 1 to 3 hydroxy groups and ammonium and alkali metal salts of said acids and mixtures thereof including mixtures of the acids and/or said salts.Type: GrantFiled: November 30, 1995Date of Patent: February 25, 1997Assignee: ISP Investments Inc.Inventors: Susan Y. Tseng, Michael W. Helioff, Jui-Chang Chuang, H. Karl Krummel, Mary R. Davis
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Patent number: 5294644Abstract: The invention relates to properties and uses of N-hydrocarbon substituted lactams, particularly N-alkyl substituted lactams having the formula ##STR1## wherein R' is a hydrophobic radical such as linear or branched chain alkyl group containing from 8 to 27 carbon atoms, most preferably micelle forming pyrrolidones having 12 to 16 carbon atoms in the R' group. The invention particularly relates to the uses of the N-hydrocarbon substituted lactams which involve surfactant properties, such as solubility, wetting, viscosity building, emulsifying and/or complexing properties.Type: GrantFiled: February 12, 1991Date of Patent: March 15, 1994Assignee: ISP Investments Inc.Inventors: Robert B. Login, Ratan K. Chaudhuri, Rama K. Haldar, Mohamed M. Hashem, Michael W. Helioff, David J. Tracy
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Patent number: 5252325Abstract: What is provided herein are conditioning hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) an emulsifiers, (c) a thickener, optionally, (d) a cationic surfactant, and the balance being (e) water.Type: GrantFiled: March 25, 1992Date of Patent: October 12, 1993Assignee: ISP Investments Inc.Inventors: Carmen D. Bires, Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Robert B. Login, Mohammed Tazi
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Patent number: 5252324Abstract: What is provided herein are conditioning shampoo hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) a surfactant, (c) a foam stabilizer, and the balance being (d) water.Type: GrantFiled: February 18, 1992Date of Patent: October 12, 1993Assignee: ISP Investments Inc.Inventors: Carmen D. Bires, Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Robert B. Login, Mohammed Tazi
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Patent number: 5169622Abstract: What is provided herein are hair and skin care compositions containing discrete microdroplets of an oil in water stabilized by in situ polymerization of a water-soluble vinyl monomer and a water-soluble acryl comonomer. The stabilized microdroplets are prepared by dispersing the oil in water, adding the water-soluble vinyl monomer, preferably vinylpyrrolidone, with the comonomer, and copolymerizing the monomer and comonomer in situ such that the oil is stabilized in the resulting copolymer solution as discrete microdroplets.Type: GrantFiled: January 8, 1991Date of Patent: December 8, 1992Assignee: ISP Investments Inc.Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
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Patent number: 5169623Abstract: What is provided herein are conditioning hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) a surfactant, and the balance being (c) water.Type: GrantFiled: January 8, 1991Date of Patent: December 8, 1992Assignee: ISP Investments Inc.Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
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Patent number: 5145669Abstract: What is provided herein is a sunscreen composition consisting essentially of a crosslinked, neutralized terpolymer of maleic anhydride, a C.sub.1 -C.sub.5 alkyl vinyl ether and a C.sub.12 -C.sub.14 alpha-olefin monomer as a thickener; water; an ultraviolet sunscreening agent; and an emulsifier. In the preferred form of the invention, the monomers are present in a molar ratio of about 1:0.90-0.99:0.01-0.10, respectively, and are crosslinked with about 2-8 wt. % of a crosslinking agent based on the total weight of the monomers. Suitably, the crosslinked terpolymer is neutralized to increase water solubility.Type: GrantFiled: July 19, 1991Date of Patent: September 8, 1992Assignee: ISP Investments Inc.Inventors: Yoon T, Kwak, Stephen L. Kopolow, Michael W. Helioff, Mohammed Tazi
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Patent number: 5139770Abstract: What is provided herein are cosmetic compositions for the care of hair and skin containing about 0.2 to 10% by wt. of a strongly swellable, moderately crosslinked polyvinylpyrrolidone polymers in the form of fine, white powders characterized by (a) an aqueous swelling parameter defined by its gel volume of about 15 to 150 ml/g, (b) a Brookfield viscosity in 5% aqueous solution of at least about 10,000 cps, and (c) being prepared directly by a precipitation polymerization process in an organic solvent, in the presence of about 0.2 to 1% by weight of vinylpyrrolidone of a multifunctional crosslinking agent, preferably about 0.25 to 0.6%, and optimally, about 0.35 to 0.6%.Type: GrantFiled: December 17, 1990Date of Patent: August 18, 1992Assignee: ISP Investments Inc.Inventors: Jenn S. Shih, Jui-Chang Chuang, Terry E. Smith, Carmen D. Bires, Michael W. Helioff, Robert B. Login
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Patent number: 5130121Abstract: What is provided herein are skin care compositions containing discrete microdroplets of an oil in water stabilized by in situ polymerization of a water-soluble vinyl monomer. The discrete microdroplets are prepared by dispersing the oil, preferably a silicone, in water, adding the water-soluble vinyl monomer, preferably vinylpyrrolidone, and polymerizing the monomer in situ such that the oil is stabilized in the resulting polymer solution as discrete microdroplets.Type: GrantFiled: January 8, 1991Date of Patent: July 14, 1992Assignee: ISP Investments Inc.Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
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Patent number: 5122370Abstract: What is provided herein is a method for treating acne vulgaris with a composition containing a stable, high purity, substantially anhydrous complex of PVP and H.sub.2 O.sub.2 in which the constituents are present respectively in substantially a 1:1 molar ratio and the complex is a free-flowing, fine white powder.Type: GrantFiled: May 20, 1991Date of Patent: June 16, 1992Assignee: ISP Investments Inc.Inventors: John J. Merianos, Michael W. Helioff
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Patent number: 5118498Abstract: The hair setting shampoo composition of the invention comprises a resin provided by about 1-15% by weight of about a 20-50% resin active alcoholic solution of the alkyl half-ester of a C.sub.1 -C.sub.5 alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90% neutralized, preferably with about 0.01-1% by weight of 2-amino-2-methyl-1-propanol, about 5-60% by weight of a surfactant, optionally 0-10% by weight of added ethanol, and about 30-90% by weight of water. The composition provides a subtle temporary set on hair of the user without the use of auxiliary fixatives in the composition.Type: GrantFiled: November 19, 1990Date of Patent: June 2, 1992Assignee: ISP Investments Inc.Inventors: Michael W. Helioff, Krystyna Plochocka, Mohammed Tazi
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Patent number: 5110585Abstract: The invention relates primarily to quaternized polycyclic compounds having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.2 together with the quaternary nitrogen, forms a 5 to 14 membered heterocyclic ring, said ring containing at least 2 hetero atoms selected from the group of nitrogen, sulfur and oxygen; R.sub.1 forms a double bond in the heterocyclic ring of the quaternized nitrogen or is alkyl, alkyleneoxyalkyl, alkylhydroxy, aryl, aralkyl, aralkenyl, alkaryl, alkylamidoalkyl and X.sup.- is an anion. The invention also relates to the preparation and use of said quaternized polycyclic compounds.Type: GrantFiled: March 1, 1989Date of Patent: May 5, 1992Assignee: ISP Investments Inc.Inventors: Ratan K. Chaudhuri, David J. Tracy, Robert B. Login, Michael W. Helioff
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Patent number: 5093031Abstract: The invention relates to properties and uses of N-hydrocarbon substituted lactams, particularly N-alkyl substituted lactams having the formula ##STR1## wherein R' is a hydrophobic radical such as linear or branched chain alkyl group containing from 8 to 27 carbon atoms, most preferably micelle forming pyrrolidones having 12 to 16 carbon atoms in the R' group. The invention particularly relates to the uses of the N-hydrocarbon substituted lactams which involve surfactant properties, such as solubility, wetting, viscosity building, emulsifying and/or complexing properties.Type: GrantFiled: October 14, 1988Date of Patent: March 3, 1992Assignee: ISP Investments Inc.Inventors: Robert B. Login, Ratan K. Chaudhuri, Rama K. Haldar, Mohamed M. Hashem, Michael W. Helioff, David J. Tracy
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Patent number: 5066481Abstract: The mousse hair composition of the invention comprises a resin provided by about 3-15% by weight of about a 20-50% alcoholic solution of the half-alkyl ester of a C.sub.1 -C.sub.5 alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90% neutralized, preferably with about 0.15-1.0% by weight of ammonium hydroxide, about 60-95% by weight of water, about 0.3-2.0% by weight of a surfactant, and about 0-30% by weight of added ethanol.Type: GrantFiled: November 5, 1990Date of Patent: November 19, 1991Assignee: ISP Investments Inc.Inventors: Michael W. Helioff, Krystyna Plochocka, Mohammed Tazi
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Patent number: 5034220Abstract: A non-aerosol shaving gel of the invention consists essentially of a major amount of a resin gel-former which is a crosslinked, neutralized copolymer of maleic anhydride and a C.sub.1 -C.sub.5 alkyl vinyl ether, a water-soluble soap and water.Type: GrantFiled: June 20, 1990Date of Patent: July 23, 1991Assignee: GAF Chemicals CorporationInventors: Michael W. Helioff, Mohammed Tazi, Robert B. Login, John F. Tancredi, Stephen L. Kopolow, William J. Burlant
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Patent number: 5032391Abstract: This invention relates to a hair styling gel containing a neutralized, crosslinked maleic anhydride C.sub.1 -C.sub.5 -alkyl vinyl ether copolymer. The formulation is a clear gel of suitable viscosity and pH. This composition provides effective hair styling at low copolymer levels. The favorable characteristics of the composition includes no drag on comb-out and a clean feel on the hair after use.Type: GrantFiled: August 9, 1990Date of Patent: July 16, 1991Assignee: GAF Chemicals CorporationInventors: Michael W. Helioff, Mohammed Tazi, Robert B. Login, Yoon T. Kwak
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Patent number: 5024779Abstract: What is disclosed herein is a nail polish remover composition having a cream-like consistency, and, in use, leaves a thin, bufferable coating on the nail which does not yellow, peel or crack, is non-toxic, and which can be removed easily with soap and water. The active components are (a) about 50 to 95% by weight of a solvent to remove nail polish from the nail; and (b) about 0.25-3.0% by weight of a hydrolyzed and neutralized crosslinked maleic anhydride-C.sub.1 -C.sub.4 alkyl vinyl ether copolymer, which is neutralized with about 0.2 to 2.4% by weight of a neutralizing agent.Type: GrantFiled: September 6, 1990Date of Patent: June 18, 1991Assignee: GAF Chemicals CorporationInventors: Michael W. Helioff, Mohammed Tazi, Yoon T. Kwak, Robert B. Login
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Patent number: 4957731Abstract: A composition comprising an aqueous hair coloring, bleaching, reducing, oxidizing or permanent structure altering formulation and a conditioning amount of a quaternized compound having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is linear alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxyalkyl, alkyleneoxyalkenyl, alkoxy, hydroxyalkyl, aryl, aralkyl, alkaryl, alkyleneamidoalkyl, alkylenecarbamoylalkyl, aryleneamidoalkyl and arylenecarbamoylalkyl radicals, and R.sub.2 and R.sub.3, together with the quaternized nitrogen atom can form a heterocyclic radical containing from 1 to 2 heteroatoms selected from the group of nitrogen, sulfur and oxygen, in which case R.sub.1 can represent a double bond in the heterocyclic structure or can be any of the aforementioned groups for R.sub.1, R.sub.2 and R.sub.3 ; said groups R.sub.1, R.sub.Type: GrantFiled: April 19, 1989Date of Patent: September 18, 1990Assignee: GAF Chemicals CorporationInventors: Michael W. Helioff, Carmen D. Bires, Robert B. Login
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Patent number: 4952559Abstract: The invention relates to an odoriferous formulation containing an odoriferous compound of between 3 and 60 carbon atoms and having an acidic hydrogen atom and a quaternized fragrance extender having the formula ##STR1## wherein X.sup.- is an anion; m is an integer having a value of from 1 to 4; R is linear alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxyalkyl, alkoxy, alkyleneoxyalkenyl, alkylhydroxy, aryl, aralkenyl, aralkyl, alkaryl, alkyleneamidoalkyl, alkylenecarbamoyalkyl, arylenecarbamoylalkyl and aryleneamidoalkyl radicals, said groups each having up to 30 carbon atoms and at least one of R.sub.1, R.sub.2 and R.sub.3 is a radical having from 8 to 30 carbon atoms, except that alternatively R.sub.2 and R.sub.Type: GrantFiled: March 1, 1989Date of Patent: August 28, 1990Assignee: GAF Chemicals CorporationInventors: Robert B. Login, Michael W. Helioff
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Patent number: 4883655Abstract: The invention relates primarily to quaternized polycyclic compounds having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.2 together with the quaternary nitrogen, forms a 5 to 14 membered heterocyclic ring, said ring containing from 1 to 2 hetero atoms selected from the group of nitrogen, sulfur and oxygen; R.sub.1 forms a double bond in the heterocyclic ring of the quaternized nitrogen or is alkyl, alkyleneoxyalkyl, alkylhydroxy, aryl, aralkyl, aralkenyl, alkaryl, alkylamidoalkyl and X.sup.- is a chloride, bromide or iodide anion. The invention also relates to the preparation and use of said quaternized polycyclic compounds.Type: GrantFiled: August 28, 1987Date of Patent: November 28, 1989Assignee: GAF CorporationInventors: Robert B. Login, Ratan K. Chaudhuri, David J. Tracy, Michael W. Helioff