Patents by Inventor Michael W. Helioff

Michael W. Helioff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5605685
    Abstract: This invention relates to an acidic non-irritating lotion, cream or ointment for rejuvenating skin and hair which comprises a micronized, homogenized hydrogel of a crosslinked N-vinyl lactam polymer and an organic rejuvenating agent selected from the group consisting of pyruvic acid, a mono- or poly-carboxylated C.sub.1 to C.sub.20 hydrocarbon optionally substituted with from 1 to 3 hydroxy groups and ammonium and alkali metal salts of said acids and mixtures thereof including mixtures of the acids and/or said salts.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: February 25, 1997
    Assignee: ISP Investments Inc.
    Inventors: Susan Y. Tseng, Michael W. Helioff, Jui-Chang Chuang, H. Karl Krummel, Mary R. Davis
  • Patent number: 5294644
    Abstract: The invention relates to properties and uses of N-hydrocarbon substituted lactams, particularly N-alkyl substituted lactams having the formula ##STR1## wherein R' is a hydrophobic radical such as linear or branched chain alkyl group containing from 8 to 27 carbon atoms, most preferably micelle forming pyrrolidones having 12 to 16 carbon atoms in the R' group. The invention particularly relates to the uses of the N-hydrocarbon substituted lactams which involve surfactant properties, such as solubility, wetting, viscosity building, emulsifying and/or complexing properties.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: March 15, 1994
    Assignee: ISP Investments Inc.
    Inventors: Robert B. Login, Ratan K. Chaudhuri, Rama K. Haldar, Mohamed M. Hashem, Michael W. Helioff, David J. Tracy
  • Patent number: 5252325
    Abstract: What is provided herein are conditioning hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) an emulsifiers, (c) a thickener, optionally, (d) a cationic surfactant, and the balance being (e) water.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: October 12, 1993
    Assignee: ISP Investments Inc.
    Inventors: Carmen D. Bires, Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Robert B. Login, Mohammed Tazi
  • Patent number: 5252324
    Abstract: What is provided herein are conditioning shampoo hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) a surfactant, (c) a foam stabilizer, and the balance being (d) water.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: October 12, 1993
    Assignee: ISP Investments Inc.
    Inventors: Carmen D. Bires, Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Robert B. Login, Mohammed Tazi
  • Patent number: 5169622
    Abstract: What is provided herein are hair and skin care compositions containing discrete microdroplets of an oil in water stabilized by in situ polymerization of a water-soluble vinyl monomer and a water-soluble acryl comonomer. The stabilized microdroplets are prepared by dispersing the oil in water, adding the water-soluble vinyl monomer, preferably vinylpyrrolidone, with the comonomer, and copolymerizing the monomer and comonomer in situ such that the oil is stabilized in the resulting copolymer solution as discrete microdroplets.
    Type: Grant
    Filed: January 8, 1991
    Date of Patent: December 8, 1992
    Assignee: ISP Investments Inc.
    Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
  • Patent number: 5169623
    Abstract: What is provided herein are conditioning hair care compositions comprising (a) a stabilized silicone product obtained by in situ polymerization of a water-soluble vinyl monomer, preferably vinylpyrrolidone, in the presence of discrete microdroplets of a silicone oil in water, (b) a surfactant, and the balance being (c) water.
    Type: Grant
    Filed: January 8, 1991
    Date of Patent: December 8, 1992
    Assignee: ISP Investments Inc.
    Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
  • Patent number: 5145669
    Abstract: What is provided herein is a sunscreen composition consisting essentially of a crosslinked, neutralized terpolymer of maleic anhydride, a C.sub.1 -C.sub.5 alkyl vinyl ether and a C.sub.12 -C.sub.14 alpha-olefin monomer as a thickener; water; an ultraviolet sunscreening agent; and an emulsifier. In the preferred form of the invention, the monomers are present in a molar ratio of about 1:0.90-0.99:0.01-0.10, respectively, and are crosslinked with about 2-8 wt. % of a crosslinking agent based on the total weight of the monomers. Suitably, the crosslinked terpolymer is neutralized to increase water solubility.
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: September 8, 1992
    Assignee: ISP Investments Inc.
    Inventors: Yoon T, Kwak, Stephen L. Kopolow, Michael W. Helioff, Mohammed Tazi
  • Patent number: 5139770
    Abstract: What is provided herein are cosmetic compositions for the care of hair and skin containing about 0.2 to 10% by wt. of a strongly swellable, moderately crosslinked polyvinylpyrrolidone polymers in the form of fine, white powders characterized by (a) an aqueous swelling parameter defined by its gel volume of about 15 to 150 ml/g, (b) a Brookfield viscosity in 5% aqueous solution of at least about 10,000 cps, and (c) being prepared directly by a precipitation polymerization process in an organic solvent, in the presence of about 0.2 to 1% by weight of vinylpyrrolidone of a multifunctional crosslinking agent, preferably about 0.25 to 0.6%, and optimally, about 0.35 to 0.6%.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: August 18, 1992
    Assignee: ISP Investments Inc.
    Inventors: Jenn S. Shih, Jui-Chang Chuang, Terry E. Smith, Carmen D. Bires, Michael W. Helioff, Robert B. Login
  • Patent number: 5130121
    Abstract: What is provided herein are skin care compositions containing discrete microdroplets of an oil in water stabilized by in situ polymerization of a water-soluble vinyl monomer. The discrete microdroplets are prepared by dispersing the oil, preferably a silicone, in water, adding the water-soluble vinyl monomer, preferably vinylpyrrolidone, and polymerizing the monomer in situ such that the oil is stabilized in the resulting polymer solution as discrete microdroplets.
    Type: Grant
    Filed: January 8, 1991
    Date of Patent: July 14, 1992
    Assignee: ISP Investments Inc.
    Inventors: Stephen L. Kopolow, William J. Burlant, Michael W. Helioff, Carmen D. Bires, Robert B. Login, Mohammed Tazi
  • Patent number: 5122370
    Abstract: What is provided herein is a method for treating acne vulgaris with a composition containing a stable, high purity, substantially anhydrous complex of PVP and H.sub.2 O.sub.2 in which the constituents are present respectively in substantially a 1:1 molar ratio and the complex is a free-flowing, fine white powder.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: June 16, 1992
    Assignee: ISP Investments Inc.
    Inventors: John J. Merianos, Michael W. Helioff
  • Patent number: 5118498
    Abstract: The hair setting shampoo composition of the invention comprises a resin provided by about 1-15% by weight of about a 20-50% resin active alcoholic solution of the alkyl half-ester of a C.sub.1 -C.sub.5 alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90% neutralized, preferably with about 0.01-1% by weight of 2-amino-2-methyl-1-propanol, about 5-60% by weight of a surfactant, optionally 0-10% by weight of added ethanol, and about 30-90% by weight of water. The composition provides a subtle temporary set on hair of the user without the use of auxiliary fixatives in the composition.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: June 2, 1992
    Assignee: ISP Investments Inc.
    Inventors: Michael W. Helioff, Krystyna Plochocka, Mohammed Tazi
  • Patent number: 5110585
    Abstract: The invention relates primarily to quaternized polycyclic compounds having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.2 together with the quaternary nitrogen, forms a 5 to 14 membered heterocyclic ring, said ring containing at least 2 hetero atoms selected from the group of nitrogen, sulfur and oxygen; R.sub.1 forms a double bond in the heterocyclic ring of the quaternized nitrogen or is alkyl, alkyleneoxyalkyl, alkylhydroxy, aryl, aralkyl, aralkenyl, alkaryl, alkylamidoalkyl and X.sup.- is an anion. The invention also relates to the preparation and use of said quaternized polycyclic compounds.
    Type: Grant
    Filed: March 1, 1989
    Date of Patent: May 5, 1992
    Assignee: ISP Investments Inc.
    Inventors: Ratan K. Chaudhuri, David J. Tracy, Robert B. Login, Michael W. Helioff
  • Patent number: 5093031
    Abstract: The invention relates to properties and uses of N-hydrocarbon substituted lactams, particularly N-alkyl substituted lactams having the formula ##STR1## wherein R' is a hydrophobic radical such as linear or branched chain alkyl group containing from 8 to 27 carbon atoms, most preferably micelle forming pyrrolidones having 12 to 16 carbon atoms in the R' group. The invention particularly relates to the uses of the N-hydrocarbon substituted lactams which involve surfactant properties, such as solubility, wetting, viscosity building, emulsifying and/or complexing properties.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: March 3, 1992
    Assignee: ISP Investments Inc.
    Inventors: Robert B. Login, Ratan K. Chaudhuri, Rama K. Haldar, Mohamed M. Hashem, Michael W. Helioff, David J. Tracy
  • Patent number: 5066481
    Abstract: The mousse hair composition of the invention comprises a resin provided by about 3-15% by weight of about a 20-50% alcoholic solution of the half-alkyl ester of a C.sub.1 -C.sub.5 alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90% neutralized, preferably with about 0.15-1.0% by weight of ammonium hydroxide, about 60-95% by weight of water, about 0.3-2.0% by weight of a surfactant, and about 0-30% by weight of added ethanol.
    Type: Grant
    Filed: November 5, 1990
    Date of Patent: November 19, 1991
    Assignee: ISP Investments Inc.
    Inventors: Michael W. Helioff, Krystyna Plochocka, Mohammed Tazi
  • Patent number: 5034220
    Abstract: A non-aerosol shaving gel of the invention consists essentially of a major amount of a resin gel-former which is a crosslinked, neutralized copolymer of maleic anhydride and a C.sub.1 -C.sub.5 alkyl vinyl ether, a water-soluble soap and water.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: July 23, 1991
    Assignee: GAF Chemicals Corporation
    Inventors: Michael W. Helioff, Mohammed Tazi, Robert B. Login, John F. Tancredi, Stephen L. Kopolow, William J. Burlant
  • Patent number: 5032391
    Abstract: This invention relates to a hair styling gel containing a neutralized, crosslinked maleic anhydride C.sub.1 -C.sub.5 -alkyl vinyl ether copolymer. The formulation is a clear gel of suitable viscosity and pH. This composition provides effective hair styling at low copolymer levels. The favorable characteristics of the composition includes no drag on comb-out and a clean feel on the hair after use.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: July 16, 1991
    Assignee: GAF Chemicals Corporation
    Inventors: Michael W. Helioff, Mohammed Tazi, Robert B. Login, Yoon T. Kwak
  • Patent number: 5024779
    Abstract: What is disclosed herein is a nail polish remover composition having a cream-like consistency, and, in use, leaves a thin, bufferable coating on the nail which does not yellow, peel or crack, is non-toxic, and which can be removed easily with soap and water. The active components are (a) about 50 to 95% by weight of a solvent to remove nail polish from the nail; and (b) about 0.25-3.0% by weight of a hydrolyzed and neutralized crosslinked maleic anhydride-C.sub.1 -C.sub.4 alkyl vinyl ether copolymer, which is neutralized with about 0.2 to 2.4% by weight of a neutralizing agent.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: June 18, 1991
    Assignee: GAF Chemicals Corporation
    Inventors: Michael W. Helioff, Mohammed Tazi, Yoon T. Kwak, Robert B. Login
  • Patent number: 4957731
    Abstract: A composition comprising an aqueous hair coloring, bleaching, reducing, oxidizing or permanent structure altering formulation and a conditioning amount of a quaternized compound having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is linear alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxyalkyl, alkyleneoxyalkenyl, alkoxy, hydroxyalkyl, aryl, aralkyl, alkaryl, alkyleneamidoalkyl, alkylenecarbamoylalkyl, aryleneamidoalkyl and arylenecarbamoylalkyl radicals, and R.sub.2 and R.sub.3, together with the quaternized nitrogen atom can form a heterocyclic radical containing from 1 to 2 heteroatoms selected from the group of nitrogen, sulfur and oxygen, in which case R.sub.1 can represent a double bond in the heterocyclic structure or can be any of the aforementioned groups for R.sub.1, R.sub.2 and R.sub.3 ; said groups R.sub.1, R.sub.
    Type: Grant
    Filed: April 19, 1989
    Date of Patent: September 18, 1990
    Assignee: GAF Chemicals Corporation
    Inventors: Michael W. Helioff, Carmen D. Bires, Robert B. Login
  • Patent number: 4952559
    Abstract: The invention relates to an odoriferous formulation containing an odoriferous compound of between 3 and 60 carbon atoms and having an acidic hydrogen atom and a quaternized fragrance extender having the formula ##STR1## wherein X.sup.- is an anion; m is an integer having a value of from 1 to 4; R is linear alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group of alkyl, alkyleneoxyalkyl, alkoxy, alkyleneoxyalkenyl, alkylhydroxy, aryl, aralkenyl, aralkyl, alkaryl, alkyleneamidoalkyl, alkylenecarbamoyalkyl, arylenecarbamoylalkyl and aryleneamidoalkyl radicals, said groups each having up to 30 carbon atoms and at least one of R.sub.1, R.sub.2 and R.sub.3 is a radical having from 8 to 30 carbon atoms, except that alternatively R.sub.2 and R.sub.
    Type: Grant
    Filed: March 1, 1989
    Date of Patent: August 28, 1990
    Assignee: GAF Chemicals Corporation
    Inventors: Robert B. Login, Michael W. Helioff
  • Patent number: 4883655
    Abstract: The invention relates primarily to quaternized polycyclic compounds having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.2 together with the quaternary nitrogen, forms a 5 to 14 membered heterocyclic ring, said ring containing from 1 to 2 hetero atoms selected from the group of nitrogen, sulfur and oxygen; R.sub.1 forms a double bond in the heterocyclic ring of the quaternized nitrogen or is alkyl, alkyleneoxyalkyl, alkylhydroxy, aryl, aralkyl, aralkenyl, alkaryl, alkylamidoalkyl and X.sup.- is a chloride, bromide or iodide anion. The invention also relates to the preparation and use of said quaternized polycyclic compounds.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: November 28, 1989
    Assignee: GAF Corporation
    Inventors: Robert B. Login, Ratan K. Chaudhuri, David J. Tracy, Michael W. Helioff