Abstract: The present invention relates to a photosensitive organic semiconductor composition comprising an organic p-type semiconductor pigment with a p-type conducting polymer, wherein the ionization potentials of the organic p-type semiconductor pigment and the p-type conducting polymer are nominally equivalent and a photosensitive organic semiconductor composition comprising an organic n-type semiconductor pigment with an n-type conducting polymer, wherein the electron affinities of the organic semiconductor pigment and the conducting polymer are nominally equivalent. The present invention also relates to a p/n heterojunction utilizing the photosensitive organic semiconductor compositions.

Abstract: The present invention relates to a photosensitive organic semiconductor composition comprising an organic p-type semiconductor pigment with a p-type conducting polymer, wherein the ionization potentials of the organic p-type semiconductor pigment and the p-type conducting polymer are nominally equivalent and a photosensitive organic semiconductor composition comprising an organic n-type semiconductor pigment with an n-type conducting polymer, wherein the electron affinities of the organic semiconductor pigment and the conducting polymer are nominally equivalent. The present invention also relates to a p/n heterojunction utilizing the photosensitive organic semiconductor compositions.

Abstract: The present invention provides an electrophotographic element. The element has a charge generation layer including binder and, dispersed in the binder, a physical mixture of (1) a high speed cocrystallized mixture of TiOPc and TiOFPc having a first intensity peak at 7.4 with respect to X-rays characteristic of Cu K? at a wavelength of 1.541 ? of the Bragg angle 2? and a second intensity peak at 28.6°±0.2°, and (2) a low speed phthalocyanine pigment.

Abstract: The present invention relates to photoconductive elements having an electrically conductive support, an electrical barrier layer and, disposed over the barrier layer, a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation. The electrical barrier layer, which restrains injection of positive charge carriers from the conductive support, comprises a crosslinker, a crosslinkable condensation polymer having as a repeating unit a planar, electron-deficient, tetracarbonylbisimide group.

Abstract: The present invention is a photoconductive element that includes an electrically conductive support, an electrical barrier layer disposed over said electrically conductive support, and disposed over said barrier layer, a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation. The barrier layer includes a vinyl polymer with aromatic tetracarbonylbisimide side groups and crosslinking sites.

Abstract: A method for preparing a coating solution containing a cocrystallized titanyl phthalocyanine-titanyl fluorophthalocyanine, the method comprising: dry milling a charge-generation pigment or mixtures of charge-generation pigments; increasing the amorphousness of the pigment mixture as determined by X-ray crystallography using X-radiation characteristic of Cu K? at a wavelength of 1.

Abstract: The present invention relates to a photosensitive organic semiconductor composition comprising an organic p-type semiconductor pigment with a p-type conducting polymer, wherein the ionization potentials of the organic p-type semiconductor pigment and the p-type conducting polymer are nominally equivalent and a photosensitive organic semiconductor composition comprising an organic n-type semiconductor pigment with an n-type conducting polymer, wherein the electron affinities of the organic semiconductor pigment and the conducting polymer are nominally equivalent. The present invention also relates to a p/n heterojunction utilizing the photosensitive organic semiconductor compositions.

Abstract: In a process for manufacturing an organic photoconductive drum there is sequentially formed on an electrically-conductive substrate that includes a cylindrical support of known weight the following layers: an optional dry undercoat layer, a dry barrier layer, a dry charge-generation layer, and a dry charge-transport layer. Following the formation of each dry layer, the cumulative weights of the cylindrical support and the dry layer(s) sequentially formed on the support are determined. Using the cumulative weights, the weight of each dry layer is determined by subtraction. The thickness of each dry layer is then determined, using previously acquired data correlating weight with thickness for each dry layer.

Abstract: A method and a composition for the production of surface smoothing polyurethane layers for application to a substrate prior to subsequent application of a charge generation layer for electrophotographic applications by preparing a coating solution containing a dialkyl malonate capped isocyanate or polyisocyanate, a polyol and at least one finely-divided metal oxide, coating the substrate with the coating solution and heating the coating solution to a temperature up to about 140° C.

Abstract: This invention relates to an aqueous composition for dip coating electrophotographic process equipment members and to a method for coating such electrophotographic members and to a coating produced on such electrophotographic process members by the use of the present composition and method. The composition includes a dispersion of a finely divided metal oxide in water or alcohol, a latex polymer composition, a water-soluble viscosity enhancer and a water miscible volatile solvent.

Abstract: This invention relates to electrophotography and to amorphous condensation polymers comprising a polyester-co-imide, polyester-co-imide, polyesterionomer-co-imide, or polyamide-co-imide as a polymeric electrical charge barrier layer.

Abstract: This invention relates to electrophotographic elements containing a layer formed from coating compositions containing a mixture of polymeric binders, including a polyvinyl butyral and a polyester ionomer and a crystalline mixture of unsubstituted titanyl phthalocyanine pigment, titanyl phthalocyanine pigments or mixtures thereof dispersed in the mixture. More particularly the invention relates to electrophotographic elements containing photoconductive layers which are especially useful for forming a photoconductive layer that is very uniform and highly absorptive at relatively thin coverage with good inter layer adhesion. The electrophotographic elements produced using this coating composition are particularly suited for high quality applications such as providing copy images with very low grain.

Abstract: A process for forming a cocrystalline mixture of titanyl phthalocyanine (TiOPc) and titanyl fluorophthalocyanine (TiOFPc) includes: dry milling a mixture of crude TiOPc and crude TiOFPc, thereby forming an amorphous pigment mixture of TiOPc and TiOFPc; and heating the amorphous pigment mixture at a temperature effective to form a cocrystalline composition comprising titanyl phthalocyanine (TiOPc) and titanyl fluorophthalocyanine (TiOFPc), the cocrystalline composition being characterized by an X-ray diffraction spectrum exhibiting intensity peaks at 7.2°, 12.9°, 16.3°, 22.3°, 24.60, 26.2°, and 28.8° with respect to X-rays of Cu K?at a wavelength of 1.54 1 ? of the Bragg angle 2?.

Abstract: A method for controlling the thickness and uniformity of a dip coated layer, using a coating apparatus under conditions of controlled temperature and controlled low humidity, includes the following steps: under normal coating conditions of ambient temperature and relative humidity, forming on a metal substrate having a thickness of at least about 500 microns a series of coated layers using variations in coating solution viscosity m, coating substrate withdrawal speed v, capillary number Ca, coating solution surface tension S, and boiling point bp (a correlative of evaporation rate)of the coating solution solvent, a coated layer including at least a portion of uniform thickness T(even) and, optionally, a portion of non-uniform thickness L(uneven); statistically analyzing measurements carried out on the series of coated layers and generating the constants, a, b, c, d, and e for Equations 2, 3, and 4: T(even)=a+b(m*v) ??(Equation 2) L(uneven)=c+d*(v*bp)+e*(Ca*bp) ??(Equation 3) v(even)=?cfbp*(d+e*m/S) ??(Eq

Abstract: A method for controlling the thickness and uniformity of a dip coated layer, using a coating apparatus in a normal coating environment, includes the following steps: forming under normal coating conditions of ambient temperature and relative humidity a series of coated layers on a metal substrate having a thickness of at least about 500 microns, using variations in coating solution viscosity m, coating substrate withdrawal speed v, capillary number Ca, coating solution surface tension S, and boiling point bp (a correlative of evaporation rate)of the coating solution solvent, a coated layer including at least a portion of uniform thickness T(even) and, optionally, a portion of non-uniform thickness L (uneven); statistically analyzing measurements carried out on the series of coated layers and generating the constants, a, b, c, d, and e for Equations 2, 3, and 4: T(even)=a+b(m*v) ??(Equation 2) L(uneven)=c+d*(v*bp)+e*(Ca*bp) ??(Equation 3) v(even)=?c/bp*(d+e*m/S) ??(Equation 4) using Equation 4, determini

Abstract: A photoconductive primary image-forming sleeve member for use in an electrophotographic apparatus includes: a cylindrical conductive substrate, a compliant layer formed on the substrate, an electrically conducting protective layer including dispersed tin oxide particles formed on the compliant layer, a barrier layer formed on the protective layer, a charge-generating layer formed on the barrier layer, and a charge-transport layer formed on the charge-generating layer.