Patents by Inventor Mihai Duduta
Mihai Duduta has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Publication number: 20200106094Abstract: Embodiments described herein relate generally to electrochemical cells having pre-lithiated semi-solid electrodes, and particularly to semi-solid electrodes that are pre-lithiated during the mixing of the semi-solid electrode slurry such that a solid-electrolyte interface (SEI) layer is formed in the semi-solid electrode before the electrochemical cell formation. In some embodiments, a semi-solid electrode includes about 20% to about 90% by volume of an active material, about 0% to about 25% by volume of a conductive material, about 10% to about 70% by volume of a liquid electrolyte, and lithium (as lithium metal, a lithium-containing material, and/or a lithium metal equivalent) in an amount sufficient to substantially pre-lithiate the active material. The lithium metal is configured to form a solid-electrolyte interface (SEI) layer on a surface of the active material before an initial charging cycle of an electrochemical cell that includes the semi-solid electrode.Type: ApplicationFiled: October 16, 2019Publication date: April 2, 2020Inventors: Naoki OTA, Mihai DUDUTA, Takaaki FUKUSHIMA, Hiuling Zoe YU, Taison TAN, Hiromitsu MISHIMA
-
Patent number: 10566603Abstract: A method of manufacturing an electrochemical cell includes transferring an anode semi-solid suspension to an anode compartment defined at least in part by an anode current collector and an separator spaced apart from the anode collector. The method also includes transferring a cathode semi-solid suspension to a cathode compartment defined at least in part by a cathode current collector and the separator spaced apart from the cathode collector. The transferring of the anode semi-solid suspension to the anode compartment and the cathode semi-solid to the cathode compartment is such that a difference between a minimum distance and a maximum distance between the anode current collector and the separator is maintained within a predetermined tolerance. The method includes sealing the anode compartment and the cathode compartment.Type: GrantFiled: October 29, 2015Date of Patent: February 18, 2020Assignee: 24M Technologies, Inc.Inventors: Alexander H. Slocum, Tristan Doherty, Ricardo Bazzarella, James C. Cross, III, Pimpa Limthongkul, Mihai Duduta, Jeffry Disko, Allen Yang, Throop Wilder, William Craig Carter, Yet-Ming Chiang
-
Patent number: 10522870Abstract: Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance.Type: GrantFiled: October 24, 2017Date of Patent: December 31, 2019Assignee: 24M Technologies, Inc.Inventors: Taison Tan, Yet-Ming Chiang, Naoki Ota, Throop Wilder, Mihai Duduta
-
Patent number: 10497935Abstract: Embodiments described herein relate generally to electrochemical cells having pre-lithiated semi-solid electrodes, and particularly to semi-solid electrodes that are pre-lithiated during the mixing of the semi-solid electrode slurry such that a solid-electrolyte interface (SEI) layer is formed in the semi-solid electrode before the electrochemical cell formation. In some embodiments, a semi-solid electrode includes about 20% to about 90% by volume of an active material, about 0% to about 25% by volume of a conductive material, about 10% to about 70% by volume of a liquid electrolyte, and lithium (as lithium metal, a lithium-containing material, and/or a lithium metal equivalent) in an amount sufficient to substantially pre-lithiate the active material. The lithium metal is configured to form a solid-electrolyte interface (SEI) layer on a surface of the active material before an initial charging cycle of an electrochemical cell that includes the semi-solid electrode.Type: GrantFiled: November 3, 2015Date of Patent: December 3, 2019Assignees: 24M Technologies, Inc., Kyocera CorporationInventors: Naoki Ota, Mihai Duduta, Takaaki Fukushima, Hiuling Zoe Yu, Taison Tan, Hiromitsu Mishima
-
Publication number: 20190355998Abstract: Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.Type: ApplicationFiled: January 18, 2019Publication date: November 21, 2019Inventors: Yet-Ming CHIANG, William Craig CARTER, Mihai DUDUTA, Pimpa LIMTHONGKUL
-
Patent number: 10483582Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 ?m to about 2,000 ?m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.Type: GrantFiled: October 24, 2017Date of Patent: November 19, 2019Assignee: 24M Technologies, Inc.Inventors: Yet-Ming Chiang, Mihai Duduta, Richard Holman, Pimpa Limthongkul, Taison Tan
-
Publication number: 20190103549Abstract: In some embodiments, a dielectric elastomer device may include at least first and second dielectric elastomer layers, and a first layer of conductive particles disposed between the first and second dielectric elastomer layers and forming a first electrode of the device, wherein portions of the second dielectric elastomer layer are directly bonded with portions of the first dielectric elastomer layer through the first layer of the conductive particles. The dielectric elastomer layer may, for example, comprise a cured acrylic elastomer precursor with an additive including urethane, polybutadiene, or silicone. Electrodes in different layers may be interconnected by infusing a liquid or semi-liquid conductive material in contact with each of a plurality of the electrodes of the actuator or sensor device, and solidifying the conductive material to form a conductive path that interconnects the plurality of electrodes.Type: ApplicationFiled: March 20, 2017Publication date: April 4, 2019Applicant: President and Fellows of Harvard CollegeInventors: Mihai Duduta, David Clarke, Robert J. Wood
-
Patent number: 10236518Abstract: Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.Type: GrantFiled: August 31, 2015Date of Patent: March 19, 2019Assignees: 24M Technologies, Inc., Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, William Craig Carter, Mihai Duduta, Pimpa Limthongkul
-
Patent number: 10230128Abstract: Embodiments described herein relate generally to electrochemical cells having semi-solid electrodes that have damage tolerance, and in particular, are tolerant to physical damage due to short circuit, crushing, or overheating. In some embodiments, an electrochemical cell includes a positive electrode, a negative electrode and an ion-permeable membrane separating the positive electrode and the negative electrode. At least one of the positive electrode and the negative electrode can include a semi-solid ion-storing redox composition which has a thickness of at least about 250 ?m. The electrochemical cell can have a first operating voltage in a first planar configuration and a second operating voltage in a second non-planar configuration such that the first operating voltage and the second operating voltage are substantially similar. In some embodiments, the electrochemical cell has a bend axis such that the electrochemical cell is bent about the bend axis in the second non-planar configuration.Type: GrantFiled: April 9, 2015Date of Patent: March 12, 2019Assignee: 24M Technologies, Inc.Inventors: Yet-Ming Chiang, Taison Tan, Jeffry Disko, Richard Holman, Mihai Duduta
-
Publication number: 20180175428Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell, includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 ?m to about 2,000 ?m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.Type: ApplicationFiled: October 24, 2017Publication date: June 21, 2018Inventors: Yet-Ming CHIANG, Mihai DUDUTA, Richard HOLMAN, Pimpa LIMTHONGKUL, Taison TAN
-
Publication number: 20180175445Abstract: Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance.Type: ApplicationFiled: October 24, 2017Publication date: June 21, 2018Inventors: Taison Tan, Yet-Ming Chang, Naoki Ota, Throop Wilder, Mihai Duduta
-
Publication number: 20180034090Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.Type: ApplicationFiled: June 8, 2017Publication date: February 1, 2018Applicants: Massachusetts Institute of Technology, 24-M Technologies, Inc.Inventors: Yet-Ming Chiang, W. Craig Carter, Bryan Y. Ho, Mihai Duduta, Pimpa Limthongkul
-
Patent number: 9831522Abstract: Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance.Type: GrantFiled: August 4, 2016Date of Patent: November 28, 2017Assignee: 24M Technologies, Inc.Inventors: Taison Tan, Yet-Ming Chiang, Naoki Ota, Throop Wilder, Mihai Duduta
-
Patent number: 9831519Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode, a semi-solid cathode that includes a suspension of an active material and a conductive material in a liquid electrolyte, and an ion permeable membrane disposed between the anode and the cathode. The semi-solid cathode has a thickness in the range of about 250 ?m-2,500 ?m, and the electrochemical cell has an area specific capacity of at least 5 mAh/cm2 at a C-rate of C/2.Type: GrantFiled: June 6, 2016Date of Patent: November 28, 2017Assignee: 24M Technologies, Inc.Inventors: Yet-Ming Chiang, Mihai Duduta, Richard Holman, Pimpa Limthongkul, Taison Tan
-
Patent number: 9831518Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 ?m to about 2,000 ?m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.Type: GrantFiled: May 6, 2016Date of Patent: November 28, 2017Assignee: 24M Technologies, Inc.Inventors: Yet-Ming Chiang, Mihai Duduta, Richard Holman, Pimpa Limthongkul, Taison Tan
-
Patent number: 9786944Abstract: Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.Type: GrantFiled: December 16, 2010Date of Patent: October 10, 2017Assignees: Massachusetts Institute of Technology, 24M Technologies, Inc.Inventors: Yet-Ming Chiang, W. Craig Carter, Bryan Y. Ho, Mihai Duduta, Pimpa Limthongkul
-
Publication number: 20170162863Abstract: Embodiments described herein generally relate to semi-solid suspensions, and more particularly to systems and methods for preparing semi-solid suspensions for use as electrodes in electrochemical devices such as, for example batteries. In some embodiments, a method for preparing a semi-solid electrode includes combining a quantity of an active material with a quantity of an electrolyte to form an intermediate material. The intermediate material is then combined with a conductive additive to form an electrode material. The electrode material is mixed to form a suspension having a mixing index of at least about 0.80 and is then formed into a semi-solid electrode.Type: ApplicationFiled: September 15, 2016Publication date: June 8, 2017Inventors: Tristan DOHERTY, Pimpa LIMTHONGKUL, Asli BUTROS, Mihai DUDUTA, James C. CROSS, III
-
Patent number: 9614231Abstract: Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.Type: GrantFiled: December 16, 2011Date of Patent: April 4, 2017Assignee: 24M Technologies, Inc.Inventors: W. Craig Carter, Yet-Ming Chiang, Mihai Duduta, Pimpa Limthongkul
-
Publication number: 20170033390Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode, a semi-solid cathode that includes a suspension of an active material and a conductive material in a liquid electrolyte, and an ion permeable membrane disposed between the anode and the cathode. The semi-solid cathode has a thickness in the range of about 250 ?m-2,500 ?m, and the electrochemical cell has an area specific capacity of at least 5 mAh/cm2 at a C-rate of C/2.Type: ApplicationFiled: June 6, 2016Publication date: February 2, 2017Inventors: Yet-Ming CHIANG, Mihai DUDUTA, Richard HOLMAN, Pimpa LIMTHONGKUL, Taison TAN
-
Publication number: 20170033389Abstract: Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode and a semi-solid cathode. The semi-solid cathode includes a suspension of an active material of about 35% to about 75% by volume of an active material and about 0.5% to about 8% by volume of a conductive material in a non-aqueous liquid electrolyte. An ion-permeable membrane is disposed between the anode and the semi-solid cathode. The semi-solid cathode has a thickness of about 250 ?m to about 2,000 ?m, and the electrochemical cell has an area specific capacity of at least about 7 mAh/cm2 at a C-rate of C/4. In some embodiments, the semi-solid cathode slurry has a mixing index of at least about 0.9.Type: ApplicationFiled: May 6, 2016Publication date: February 2, 2017Inventors: Yet-Ming CHIANG, Mihai DUDUTA, Richard HOLMAN, Pimpa LIMTHONGKUL, Taison TAN