Abstract: Disclosed is a preparation method of graphene film. The method comprises the following steps: providing a clean substrate, followed by positively charged processing of the substrate surface; preparing suspension of graphene with negative charges on surface and the suspension of graphene with positive charges on surface respectively; immersing the surface-treated substrate into the suspension of graphene with negative charges on surface for 5-20 minutes, then taking the substrate out, washing, drying, and then immersing it into the suspension of graphene with positive charges on surface for 5-20 minutes, then taking the substrate out, washing, drying, so alternately repeated 10 to 50 times to obtain a graphene film precursor, and finally reducing the graphene film precursor at 500-1000° C. to obtain the grapheme film.

Abstract: Provided in the present invention is a metal nanoparticle-coating titanate fluorescent material, which has a molecular formula of A1-x-yByTiO3:xR@SiO2@Mz, where A is one or two elements selected from Ca, Sr, Ba and Mg, where B is one element selected from Li, Na and K, where R is one or two elements selected from Eu, Gd, Tb, Tm, Sm, Ce, Dy and Mn, where M is one selected from Ag, Au, Pt, Pd and Cu nanoparticles, where 0<x?0.40; 0?y?0.40, where z is the molar ratio of M and SiO2, where 0<z?1×10?2, where @ represents a coating, where M is a core where SiO2 is an intermediate layer shell, and where A1-x-yByTiO3:xR is an outer layer shell. The metal nanoparticle-coating titanate fluorescent material forms a core-shell structure by introducing metal nanoparticles, while the metal nanoparticles generate a Plasmon resonance effect, thus increasing the internal quantum efficiency of the metal nanoparticle-coating titanate fluorescent material, which is provided with increased luminescent intensity.

Abstract: Halo-borate luminescent materials and preparation methods thereof are provided. The said luminescent materials are represented by the following general formula: Ca2-xBO3Cl1-yFy:xEu2+, with zM0, wherein M0 is selected from one of Ag, Au, Pt, Pd or Cu metal nano-particles; 0.001?x?0.1, 0?y?0.2, 0<z?0.01. The said luminescent materials have excellent chemical stability and high luminous intensity. The said preparation methods have simple technique, no pollution, manageable process conditions and low equipment requirement, and are beneficial to industry production.

Abstract: Halo-silicate luminescent materials and preparation methods thereof are provided. The said luminescent materials are represented by the following general formula: (Ba1-yAy)2-xSiO4:Eux, Dz@ Mn, wherein A is selected from one or two of Sr, Ca, Mg or Zn, D is selected from one of F or Cl, M is selected from at least one of Ag, Au, Pt, Pd or Cu metal nano-particles; @ is coating; (Ba1-yAy)2-xSiO4:Eux, Dz, is shell; 0.001<x?0.15, 0?y?0.5, 0?z?0.5, 0<n?1×10?2. The said luminescent materials have excellent chemical stability and high luminous intensity. Furthermore, the luminescent materials have controlled spherical shape which is beneficial to the coating screen process and the improved displaying effect. The said preparation methods have simple technique, no pollution, manageable process conditions and low equipment requirement, and are beneficial to industry production.

Abstract: A titanate luminescent material has a formula of A1-x,TiO3:Prx@TiO2@My; wherein A is at least one selected from the group consisting of Ca, Sr, and Ba; M is at least one nanoparticles selected from the group consisting of Ag, Au, Pt, Pd, and Cu; 0<x?0.01; y is the molar ratio between M and Ti in A1-x,TiO3:Prx@TiO2, and 0<y?1×10?2; @ represents coating; M is a core, TiO2 is an intermediate layer shell, and A1-xTiO3:Prx is an outer layer shell. The titanate luminescent material has a high stability and a better luminescent performance. A preparation method of the titanate luminescent material is also provided.

Abstract: A luminescent element includes a luminescent glass and a metal layer with a metal microstructure formed on a surface of the luminescent glass; wherein the luminescent glass has a chemical composition: bY2O3.cAl2O3.dB2O3.yTb2O3, wherein bY2O3.cAl2O3.dB2O3.yTb2O3. A preparation method of a luminescent element and a luminescence method are also provided. The luminescent element has good luminescence homogeneity, high luminescence efficiency, good luminescence stability and simple structure, and can be used in luminescent device with ultrahigh brightness.

Abstract: A manganese-doped magnesium stannate luminescent material, which has a molecular formula of: Mg2-xSnO4:Mnx@SnO2@My, where @ is a coating, where Mg2-xSnO4:Mnx is an outer shell layer, where SnO2 is an intermediate layer shell, where M is an inner core, where M is a metal nanoparticle, where M is at least one selected among Ag, Au, Pt, Pd, and Cu, where the value of x is 0<x?0.05, where y is the molar ratio between M and Sn, and where the value of y is 0<y?1×10?2. The manganese-doped magnesium stannate luminescent material is a core-shell structure luminescent material, has a high internal quantum efficiency, great luminescent intensity, and the advantages of great stability and great luminescent properties. A method for preparing the manganese-doped magnesium stannate luminescent material has simple processes, low equipment requirements, and no pollution, is easy to control and applicable for industrial production, and has a broad application prospect.

Abstract: A core-shell structured silicate luminescent material and a preparation method thereof. The molecular formula of the luminescent material is: MLn1-xSiO4:xRE@SiO2; where @ represents a coating, where M is one or two elements among Li, Na, and K, where Ln is one or two elements among Y, Sc, Lu and La, where the value of x is 0<x?0.6; and where RE is one, two, or three elements among Tb, Gd, Sm, Eu, Dy, Ce and Tm. The compositions of the luminescent material are all chemicals of increased chemical stability, and, when subjected to electron beam bombardment for an extended period, provide a stable matrix and do not decompose easily.

Abstract: Terbium doped phosphate-based green luminescent material and preparation method thereof are provided. The chemical formula of the material is M3RE1-xTbx(PO4)3, wherein, M is alkaline-earth metals, RE is rare-earth elements, x is in a range of 0.001 to 1. The preparation method of the material includes the following steps; providing the compound used as the source of alkaline earth metal, the compound used as the source of phosphate, the compound used as the source of rare-earth, and the compound used as the source of Tb3+ according to the molar ratio of the elements in M3RE1-xTbx(PO4)3, wherein, the compound used as the source of phosphate is added at excess molar ratio in a range of 10% to 30%; mixing and grinding the compound to get mixture; sintering the mixture as pre-treatment, and then cooling the mixture to get a sintered matter; grinding; calcining in reducing atmosphere, and then cooling them.

Abstract: Silicate luminescent material and preparation method thereof are provided. The structural formula of the silicate luminescent material is Zn2-y(Si1-xMx)O4:Mny, wherein M is metal element and its oxide is conductive, x is in a range of 0.001 to 0.15, and y is in a range of 0.001 to 0.05. For integrated with conductive metal oxide component, the silicate luminescent material could take advantage of its conductive properties, and the silicate luminescent material could improve the luminescence properties under cathode ray significantly comparing with that of the luminescent material has not been integrated with conductive component. Accordingly, the luminescence efficiency of the above silicate luminescent material is increased.

Abstract: A fluorographene and preparation method thereof are provided. For the said fluorographene, the fraction of F is 0.5<F %<53.5% in weight and the fraction of C is 46.5%<C %<99.5% in weight. The method comprises the following steps: providing the graphite; preparing the graphene oxide with the graphite; mixing the graphene oxide with the compound containing fluorine by weight ratio of 1:1˜100:1 in anaerobic environment, reacting at 200˜1 000° C. for 1˜10 hours then cooling down to obtain the said fluorographene. The above-mentioned method using graphite to prepare the graphene oxide, then making use of the reaction of graphene oxide with the compound containing fluorine under a certain temperature has simple process and can prepare fluorographene conveniently.

Abstract: Provided are a luminescent material and a preparing method thereof. The borosilicate luminescent material has a chemical formula of aM2O.bLn2O3.cAl2O3.dR2O3.eSiO2.fCeO2.gTb2O3 or aMO.bLn2O3.cAl2O3.dR2O3.eSiO2.fCeO2.gTb2O3, wherein M is alkaline earth metal or alkali metal, Ln is one or two elements selected from the group consisting of elements Y and Gd; R is one or two elements selected from the group consisting of elements B and P; a, b, c, d, e, f, and g are molar fractions, and 6?a?20, 3?b?12, 20?c?30, 32?d?45, 0?e?12, 0.01?f?1, and 0.05?g?1.5. The preparing methods comprises the following steps: 1) selecting source compounds of above elements; 2) mixing and grinding the source compounds to obtain a mixture; 3) presintering the mixture, then grinding the mixture; 4) sintering under reducing atmosphere, and cooling, thereby obtaining the luminescent material.

Abstract: A luminescent material and a preparation method thereof are provided. The said luminescent material is represented by the following chemical formula: Ln2-xEuxSn2O7, wherein Ln is selected from one of Gd, Y and La, 0.1?x?1.5. The said luminescent material has good electrical performance, anti-electron bombardment and stable luminescent property. It is appropriate to be used in field emission light-emitting devices. The said preparation method has simple technique, no pollution, manageable process conditions, low preparation temperature and low equipment requirement, and is beneficial to industry production.

Abstract: Provided is a fluorescent powder of halogen-silicate containing nano-metal particles with the formula of CaX2.y(Ca1-a-bEuaMnbO).SiO2:zM, wherein X is fluorin or/and chlorine, y is 1 or 2, z is molar ratio of nano-metal particles and fluorescent powder CaX2.y(Ca1-a-bEuaMnbO).SiO2, 0<z?1×10?2, 0<a?0.3, 0?b?0.3. The method for preparing the fluorescent powder is also provided. For the surface plasma resonance effect occurring on the surface of the nano-metal particles, the fluorescent powder has stronger luminous intensity. The preparation method is simple to operate, no pollution, easy to control, easy to produce in industry, and can be widely used in the preparation field of fluorescent powder.

Abstract: Disclosed are a double-sided luminescent organic light emitting device and the manufacturing method thereof. The double-sided luminescent organic light emitting device comprises a transparent substrate (21), an anode (22), a transparent cathode (25), and at least two organic light emitting structures (23a, 23b) and at least a charge-generation layer (24) set between the anode (22) and the transparent cathode (25), and the charge-generation layer (24) is set between the two neighboring organic light emitting structures (23a, 23b), the charge-generation layer (24) and the organic light emitting structures (23a, 23b) are alternately arranged. The charge-generation layer (24) includes an n-type semiconductor layer (241) and a p-type semiconductor (242) layer combined with the n-type semiconductor layer. Said double-sided light emitting organic light emitting device requires low driving current, and has high luminescence efficiency, high brightness, and high light extraction efficiency.

Abstract: Provided is a method for preparing graphene paper, comprising the followings steps: placing a clean substrate into a reaction chamber, then introducing protective gas into the reaction chamber to purge out air in the reaction chamber; heating the substrate at a temperature of 800 to 1100° C.; continuously introducing carbonaceous material into the reaction chamber for 100 to 300 min, stopping the introduction of carbonaceous material into the reaction chamber, and at the same time stopping heating of the substrate, then cooling the substrate at a rate of 5 to 30° C./min, finally, stopping the introduction of the protective gas, thereby obtaining graphene paper on the surface of said substrate.

Abstract: A solid electrolyte battery comprises a positive plate (1), a negative plate (2), several composite electrode plates (3) and several solid electrolyte (4), wherein the number of the solid electrolyte (4) is one more than the number of the composite electrode plates (3). The positive plate (1) and the negative plate (2) are spaced oppositely, the composite electrode plates (3) are between the positive plate (1) and the negative plate (2), and both sides of the composite electrode plates (3) are laminated with the positive plate (1) and the negative plate (2) by the solid electrolyte (4), respectively, the structure of the solid electrolyte battery is formed.

Abstract: Disclosed is a doped organic electroluminescent device, comprising the following structures laminated in succession: a conductive anode substrate, a hole injecting layer, a hole transportation layer, an electron barrier layer, a light-emitting layer, an electron transportation layer, an electron injecting layer and a cathode; and the material for the electron barrier layer is a hole transportation material doped with a cerium salt. The material for an electron barrier layer in such a doped organic electroluminescent device is a hole transportation material doped with a cerium salt which has a low work function of approximately ?2.0 eV and can effectively block electrons.

Abstract: A white light emitting glass-ceramic. The chemical formula of the glass-ceramic is aSiO2.bAl2O3.cNaF.dCeF3.nDyF3.mAg, wherein a, b, c, d, n and m are, by mol part, 25-50, 15-30, 10-30, 10-25, 0.01-1 and 0.01-1, respectively, and a+b+c+d-100. A method for producing said glass-ceramic is also provided. Silver ion is doped in the glass-ceramic in the form of silver particles by means of sintering and reduction annealing treatment, and thus the luminescence properties of rare earth ion is improved.

Abstract: Borate luminescent materials, preparation methods and uses thereof are provided. The luminescent material is a blend of metal M nanoparticles and (In1-xRex)BO3, wherein Re is one or two selected from Tm, Tb, Eu, Sm, Gd, Dy and Ce, M is one or two selected from metal nano particles of Au, Ag, Pt or Pd, 0<x?0.5, 0<z?1×10?2. Compared to the luminescent materials in the prior art, the said luminescent materials have higher luminous intensity and luminous efficiency, which can be used in field emission displays or light source.