Patents by Inventor Mitsuru Shibata

Mitsuru Shibata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5849926
    Abstract: A pyrazole compound of the formula ##STR1## wherein R.sup.11 is a C.sub.1 -C.sub.6 alkyl; each of R.sup.12, R.sup.13, R.sup.14 and R.sup.15 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.16 is C.sub.1 -C.sub.4 alkyl; R.sup.17 is hydrogen or C.sub.1 -C.sub.4 alkyl; X.sup.3 is C.sub.1 -C.sub.4 alkyl or hydrogen; p is 0, 1 or 2; A.sup.2 is ##STR2## or --CR.sup.18 R.sup.19 in which each of R.sup.18 and R.sup.19 is C.sub.1 -C.sub.4 alkyl; R is 0 to 3; B is C.sub.1 -C.sub.12 alkyl, cycloalkyl or the formula ##STR3## wherein Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, nitro or halogen; and n is 1 or 2. The pyrazole compounds are used as herbicides.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: December 15, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Mitsuru Shibata, Kazuyoshi Koike, Masashi Sakamoto, Yoriyuki Takashima
  • Patent number: 5756759
    Abstract: Pyrazole compounds of the formula (I) ##STR1## and the formula (XI), ##STR2## and the pyrazole compounds of the formula (I) exhibits selectivity to paddy rice and corn, and can control a wide range of paddy field and upland field weeds at a low dosage.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: May 26, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Mitsuru Shibata, Ichiro Nasuno, Kazuyoshi Koike, Masashi Sakamoto
  • Patent number: 5723408
    Abstract: Provided by the present invention is a herbicide composition containing, as active ingredients, a pyrazole derivative of the general formula (I) ##STR1## and at least one herbicide compound selected from the group consisting of chloroacetamide-containing herbicides, imidazoline-containing herbicides, atrazine, cyanazine, metribuzin, linuron, metobenzuron, bentazone, dicamba, chlopyralid, 2,4-D, bromoxynil, pendimethalin, nicosulfuron, rimsulfuron, primisulfuron and pyridate. The herbicide composition of the present invention can control a broad rage of gramineous weeds and broad-leaved weeds at a very low dosage without damaging corn and other crops.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: March 3, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Mitsuru Shibata, Ichiro Nasuno, Kazufumi Nakamura, Kazuyoshi Koike, Misako Yoshikawa
  • Patent number: 5591868
    Abstract: An aromatic carboxylic acid compound of the following formula: ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl group, each of X.sup.1 and X.sup.2 is independently a C.sub.1 -C.sub.4 alkyl group, m is an integer of 0 or 1, and n is an integer of 0, 1 or 2, or a salt thereof.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: January 7, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Ichiro Nasuno, Mitsuru Shibata, Masashi Sakamoto, Kazuyoshi Koike
  • Patent number: 5587484
    Abstract: Processes for producing a pyrazole compound by reacting a compound ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl, each of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is hydrogen or a C.sub.1 -C.sub.4 alkyl, X.sup.1 is a C.sub.1 -C.sub.4 alkyl or a halogen, n is 1 to 3, and p.sup.1 is 0 to 2, with a compound ##STR2## wherein R.sup.6 is a C.sub.1 -C.sub.4 alkyl and R.sup.7 is hydrogen or a C.sub.1 -C.sub.4 alkyl, to form a pyrazole compound ##STR3## and optionally reacting the pyrazole compound (Ia) with a sulfonic acid halide of the formula Q.sup.2 X.sup.2 (IV)wherein Q.sup.2 is --SO.sub.2 --R.sup.8 or ##STR4## in which R.sup.8 is a C.sub.1 -C.sub.6 alkyl, Y is hydrogen, a C.sub.1 -C.sub.1 alkyl or a halogen, m.sup.1 is 1 to 3, and X.sup.2 is a halogen. Alternatively, the compound of the formula (II) is reacted with a halogenation agent to produce a compound which is reacted with a compound of the formula (III) to produce a compound which is heated to form a compound of the formula (Ia).
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: December 24, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Mitsuru Shibata, Masashi Sakamoto, Ichiro Nasuno
  • Patent number: 5506194
    Abstract: Pyrazole derivatives of the formula, ##STR1## (wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl group, each of R.sup.2, X.sup.1 and X.sup.2 is independently a C1-C4 alkyl group, R.sup.3 is hydrogen or a C.sub.1 -C.sub.4 alkyl group, m is an integer of 0 or 1, and n is an integer of 0, 1 or 2.) or salts thereof have high selectivity to corn, wheat and barley and can control grasses and broad-leaved weeds by any treatment of foliar treatment and soil treatment at a low dosage.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: April 9, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Ichiro Nasuno, Mitsuru Shibata, Masashi Sakamoto, Kazuyoshi Koike
  • Patent number: 5480858
    Abstract: Cyclohexanedione derivatives of the formula (I), ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl group, R.sup.2 is a C.sub.1 -C.sub.4 alkyl group, each of R.sup.3, R.sup.4 and R.sup.5 is independently hydrogen or a C.sub.1 -C.sub.4 alkyl group, and n is an integer of 0 to 2, or salts thereof exhibit high selectivity for corn, wheat and barley, and can control gramineous weeds and broad-leaved weeds at low dosages.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: January 2, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Masashi Sakamoto, Mitsuru Shibata, Ichiro Nasuno, Kazuyoshi Koike
  • Patent number: 5468722
    Abstract: The object of the present invention is to provide a novel pyrazole derivative which shows high selectivity to corn, wheat and barley and which is capable of controlling gramineous weeds and broad-leaved weeds together at a low dosage.The pyrazole derivative of the present invention to achieve the above object is the compound of the general formula (I), ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl group,each of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is independently hydrogen or a C.sub.1 -C.sub.4 alkyl group,R.sup.6 is a C.sub.1 -C.sub.4 alkyl group,R.sup.7 is hydrogen or a C.sub.1 -C.sub.4 alkyl group,X.sup.1 is a C.sub.1 -C.sub.4 alkyl group or a halogen atom,n is an integer of 1 to 3,p.sup.1 is an integer of 0 to 2, andQ.sup.1 is hydrogen, --SO.sub.2 --R.sup.8 or ##STR2## in which R.sup.8 is a C.sub.1 -C.sub.6 alkyl group,Y is hydrogen, a C.sub.1 -C.sub.4 alkyl group or a halogen atom, andm.sup.1 is an integer of 1 to 3.
    Type: Grant
    Filed: August 23, 1994
    Date of Patent: November 21, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Mitsuru Shibata, Masashi Sakamoto, Kazuyoshi Koike, Ichiro Nasuno
  • Patent number: 5468878
    Abstract: Cyclohexanedione derivatives of the general formula (I), ##STR1## wherein: R is a C.sub.1 -C.sub.4 alkyl group,each of R.sup.1 to R.sup.6 is independently hydrogen or a C.sub.1 -C.sub.4 alkyl group,X.sup.1 is a C.sub.1 -C.sub.4 alkyl group,X.sup.2 is hydrogen or a C.sub.1 -C.sub.4 alkyl group, andn is an integer of 0 to 2.or salta thereof exhibit high selectivity for corn, wheat and barley, can control gramineous weeds and broad-leaved weeds at a low dosage, and can be desirably used as an active ingredient of a herbicide.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: November 21, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Ichiro Nasuno, Mitsuru Shibata, Masashi Sakamoto, Kazuyoshi Koike
  • Patent number: 5035739
    Abstract: The present invention relates to a trifluoromethanesulfonamide derivative represented by the general formula given below, a herbicide with the derivative as the active ingredient and a method for the preparation of the derivative. ##STR1## [In the formula, X is a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or a haloalkyl group having 1 to 4 carbon atoms, n is 1, 2 or 3 and A is --O--CR.sup.3 R.sup.4 --, --S--CR.sup.3 R.sup.4 --, --SO--CR.sup.3 R.sup.4 --, --SO.sub.2 --CR.sup.3 R.sup.4 -- or --SO.sub.2 --NR.sup.3 --. And, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.]These compounds are prepared depending on A in the above given general formula by the reaction of an amine derivative and a trifluoromethanesulfonyl halide or trifluoromethanesulfonic anhydride or by the oxidation of a thiochroman ring-containing trifluoromethanesulfonamide derivative.
    Type: Grant
    Filed: January 26, 1990
    Date of Patent: July 30, 1991
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Mitsuru Shibata, Yoshiyuki Hiramatsu, Ryoichi Adachi, Kenichiro Mitsutake
  • Patent number: 4919705
    Abstract: The present invention relates to a trifluoromethanesulfonamide derivative represented by the general formula given below, a herbicide with the derivative as the active ingredient and a method for the preparation of the derivative. ##STR1## [In the formula, X is a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or a haloalkyl group having 1 to 4 carbon atoms, n is 1, 2 or 3 and A is --O--CR.sup.3 R.sup.4 --, --S--CR.sup.3 R.sup.4 --, --SO--CR.sup.3 R.sup.4 --, --SO.sub.2 --CR.sup.3 R.sup.4 -- or --SO.sub.2 --NR.sup.3 --. And, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.]These compounds are prepared depending on A in the above given general formula by the reaction of an amine derivative and a trifluoromethansulfonyl halide or trifluoromethanesulfonic anhydride or by the oxidation of a thiochroman ring-containing trifluoromethanesulfonamide derivative.
    Type: Grant
    Filed: September 6, 1988
    Date of Patent: April 24, 1990
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Mitsuru Shibata, Yoshiyuki Hiramatsu, Ryoichi Adachi, Kenichiro Mitsutake