Abstract: The present invention relates to a self-emulsifying polyisocyanate composition including a reaction mixture of (a) an anionic compound having a specific structure, (b) nonionic hydrophilic group-containing monofunctional alcohol having a specific structure, (c) organic polyisocyanate, and (d) tertiary amine, a two-part coating composition that contains the composition, and a coating film that can be obtained from the coating composition.

Abstract: The present invention relates to a hydrophilizing agent for producing a self-emulsifying polyisocyanate composition, the hydrophilizing agent comprising an anionic compound represented by the following formula (1): wherein X represents a sulfo group or a hydroxysulfonyloxy group, R1 represents a straight-chain or branched alkylene group, and R2 represents a straight-chain or branched alkyl group; the total number of carbon atoms included in R1 and R2 is 6 or more and less than 14, and one or two or more carbon atoms in the groups R1 and R2 are optionally replaced with an oxygen atom(s).

Abstract: A production process of colored resin powder, comprising a coloring step of mixing 0.5 to 40% by mass of a colorant (b1) with 99.5 to 60% by mass of a non-phthalic acid plasticizer (b2) to prepare a colored paste (B) and adding and mixing the colored paste (B) into a powdery thermoplastic polyurethane-urea resin (A), wherein the amounts of the colorant (b1) and the plasticizer (b2) contained in the colored paste (B) added to the powdery thermoplastic polyurethane-urea resin (A) are 0.1 to 5 parts by mass and 1 to 20 parts by mass, respectively, per 100 parts by mass of the thermoplastic polyurethane-urea resin. According to the production process, there can be provided colored resin powder, which is free from color mottling (color unevenness) on its surface and does not cause smearing of a molded product due to separation and falling of the colorant upon a molding process or the like.

Abstract: A process for producing a powdered thermoplastic polyurethane urea resin is disclosed, which includes a step of forming a polyurethane urea resin by reacting a polymer polyol (a), an organic polyisocyanate (b), a monofunctional active hydrogen-containing compound (c), and preferably a bifunctional active hydrogen-containing compound (d) in specific proportions to form an isocyanate-terminated prepolymer, and subjecting the isocyanate-terminated prepolymer and water (e) to chain extension reaction in a non-aqueous dispersion medium. According to this production process, a powdered thermoplastic polyurethane urea resin having excellent melt formability can be obtained, and it is easy to control a molecular weight of the polyurethane urea resin.

Abstract: A production process of colored resin powder, comprising a coloring step of mixing 0.5 to 40% by mass of a colorant (b1) with 99.5 to 60% by mass of a non-phthalic acid plasticizer (b2) to prepare a colored paste (B) and adding and mixing the colored paste (B) into a powdery thermoplastic polyurethane-urea resin (A), wherein the amounts of the colorant (b1) and the plasticizer (b2) contained in the colored paste (B) added to the powdery thermoplastic polyurethane-urea resin (A) are 0.1 to 5 parts by mass and 1 to 20 parts by mass, respectively, per 100 parts by mass of the thermoplastic polyurethane-urea resin. According to the production process, there can be provided colored resin powder, which is free from color mottling (color unevenness) on its surface and does not cause smearing of a molded product due to separation and falling of the colorant upon a molding process or the like.

Abstract: A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa·s (at 25° C.) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same.

Abstract: A self-emulsifiable polyisocyanate with high functionality, having the average number of functional groups in 4.3 or more and a viscosity of 8,000 mPa.s (at 25° C.) or less, which is obtained by subjecting a modified polyisocyanate containing allophanate bonds and a poly(oxyalkylene)glycol monoalkyl ether (e) having oxyethylene bonds in a total amount of 30 mole % or more in its molecule to a urethanization reaction, said modified polyisocyanate being obtained by reacting a polyol (a) having the average number of functional groups in an amount of 2 or more with an organic polyisocyanate (b) in the presence of an allophanate-forming catalyst (c) comprising a zirconium carboxylate; and a process for producing the same.