Abstract: The present specification relates to a battery, comprising an anode, a cathode, an electrolyte disposed between the anode and the cathode, a halogen in contact with the cathode, and a metal in contact with the anode, wherein the halogen is in contact with a polymeric halogen sequestering agent (HSA) which is a polymer comprising a moiety capable of sequestering the halogen.

Abstract: The present specification relates to a battery, comprising an anode, a cathode, an electrolyte disposed between the anode and the cathode, a halogen in contact with the cathode, and a metal in contact with the anode, wherein the halogen is in contact with a polymeric halogen sequestering agent (HSA) which is a polymer comprising a moiety capable of sequestering the halogen.

Abstract: The present invention provides an energy storage system that utilizes batteries of multiple compositions and provides improved load sharing between the different types of batteries is disclosed. The energy storage system includes at least two batteries, where each battery has a different chemical composition for storing energy. One battery is configured for rapid charging/discharging and the other batter is configured for slower charging/discharging. Each battery is connected to a common connection via an energy regulator. The regulators are initially configured such that the energy regulator connected between the common connection and the battery configured for rapid charging/discharging responds initially to changes in power demand at the common connection. If power demand continues, the first regulator decreases the amount of energy transferred between the first battery and the common connection while the second regulator begins transferring energy between the second battery and the common connection.

Abstract: The present invention provides an energy storage system that utilizes batteries of multiple compositions and provides improved load sharing between the different types of batteries is disclosed. The energy storage system includes at least two batteries, where each battery has a different chemical composition for storing energy. One battery is configured for rapid charging/discharging and the other batter is configured for slower charging/discharging. Each battery is connected to a common connection via an energy regulator. The regulators are initially configured such that the energy regulator connected between the common connection and the battery configured for rapid charging/discharging responds initially to changes in power demand at the common connection. If power demand continues, the first regulator decreases the amount of energy transferred between the first battery and the common connection while the second regulator begins transferring energy between the second battery and the common connection.

Abstract: The present disclosure details header flow divider designs and methods of electrolyte distribution. Internal header flow dividers may include multiple flow channels and may be built into flow frames. Flow channels within internal header flow dividers may divide evenly multiple times in order to form multiple flow channel paths and provide a uniform distribution of electrolytes throughout electrode sheets within electrochemical cells. Furthermore, uniform electrolyte distribution across electrode sheets may not only enhance battery performance, but also prevent zinc dendrites that may be formed in electrode sheets. The prevention of zinc dendrite growth in electrode sheets may increase operating lifetime of flow batteries. The disclosed internal header flow dividers may also be included within end caps of electrochemical cells.

Abstract: An improved electrolyte battery is provided that includes a tank assembly adapted to hold an amount of an anolyte and a catholyte, a number of cell stacks operably connected to the tank assembly, each stack formed of a number of flow frames disposed between end caps and a number of power converters operatively connected to the cell stacks. The cell stacks are formed with a number of flow frames each including individual inlets and outlets for anolyte and catholyte fluids and a separator disposed between flow frames defining anodic and cathodic half cells between each pair of flow frames. The power converter is configured to connect the battery with either forward or reverse polarity to a DC power source, such as a DC bus. The anodic and cathodic half cells switch as a function of the polarity by which the battery is connected to the Dc power source.

Abstract: Disclosed is method for enhancing electrolyte flowing mechanism within electrodes in flow battery cells by employing half-cell spacer screens that may be welded to at least one surface of each electrode sheet. Half-cell spacer screens may provide a constant gap thickness between electrode sheet and micro-porous separator membrane. Half-cell spacer screens may be made of a bromine inert thermoplastic such as polypropylene or polyethylene and may include at least one thin layer of strands. Additionally, the disclosed half-cell spacer screens may exhibit diamond pattern netting or any other suitable pattern. The inclusion of half-cell spacer screens may allow an improved distribution of electrolyte throughout the surface of electrode sheet, thereby improving performance flow batteries.

Abstract: An improved chemical composition and manufacturing process for a battery electrode are disclosed. This battery electrode may be later arranged in flowing electrolyte battery cells. Battery electrode material formulation may include a mixture of polypropylene, carbon black, graphite, bonding additives and other substances in different concentrations. The inclusion of graphite may reduce the amount of carbon black in the mixture, thereby reducing the swelling of the battery electrode in the presence of bromine. Moreover, material formulation may reduce warpage caused by the swelling of electrode material, and may additionally improve the performance and properties of flowing electrolyte batteries. An extrusion molding process may be employed in order to fabricate the disclosed battery electrode.

Abstract: Disclosed herein are formulation components for the manufacturing of a flow frame structure that can be integrated in flowing electrolyte batteries. These formulation components for manufacturing flow frames may include, but are not limited to, polypropylene, glass fiber, a coupling agent and an elastomer. A mixing and extrusion process may be employed to formulate the material and produce pre-formulated pellets for the manufacturing of flow frames. As flow frames may be integrated with electrodes (or membranes), the disclosed flow frame formulation may achieve a desired Melt Flow Index (MFI) range and may allow an improved bonding between electrodes (or membranes) and flow frame, therefore, simplifying manufacturing process and achieving higher performance and longer lifetime of flowing electrolyte batteries.

Abstract: The present disclosure details header flow divider designs and methods of electrolyte distribution. Internal header flow dividers may include multiple flow channels and may be built into flow frames. Flow channels within internal header flow dividers may divide evenly multiple times in order to form multiple flow channel paths and provide a uniform distribution of electrolytes throughout electrode sheets within electrochemical cells. Furthermore, uniform electrolyte distribution across electrode sheets may not only enhance battery performance, but also prevent zinc dendrites that may be formed in electrode sheets. The prevention of zinc dendrite growth in electrode sheets may increase operating lifetime of flow batteries. The disclosed internal header flow dividers may also be included within end caps of electrochemical cells.

Abstract: An improved electrolyte battery is provided that includes a tank assembly adapted to hold an amount of an anolyte and a catholyte, a number of cell stacks operably connected to the tank assembly, each stack formed of a number of flow frames disposed between end caps and a number of power converters operatively connected to the cell stacks. The cell stacks are formed with a number of flow frames each including individual inlets and outlets for anolyte and catholyte fluids and a separator disposed between flow frames defining anodic and cathodic half cells between each pair of flow frames. The power converter is configured to connect the battery with either forward or reverse polarity to a DC power source, such as a DC bus. The anodic and cathodic half cells switch as a function of the polarity by which the battery is connected to the Dc power source.