Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.

Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.

Abstract: A method of treating a fiber includes admixing a fiber comprising a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety and having a degree of hydrolysis less than 100% with a hydrolysis agent solution to form a mixture so as to increase the degree of hydrolysis of at least a portion of the fiber.

Abstract: A fiber having a surface region and an interior region includes a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety, the fiber having a transverse cross-section including the interior region comprising the polymer having a first degree of hydrolysis and the surface region comprising the polymer having a second degree of hydrolysis greater than the first degree of hydrolysis.

Abstract: Disclosed herein are unit dose articles comprising one or more compartments, the one or more compartments comprising a nonwoven web and a water soluble film.

Abstract: The disclosure provides a nonwoven web, said nonwoven web including a plurality of fibers including a blend of fiber forming materials, the blend of fiber forming materials including a first polyvinyl alcohol polymer. The blend of fiber forming materials further comprises a second polyvinyl alcohol polymer or does not include carboxymethyl cellulose, hydroxypropyl methylcellulose or starch. The nonwoven web can be water-dispersible, optionally water-soluble, and/or flushable. The disclosure further provides a pouch including a nonwoven web including a plurality of fibers according to the disclosure. In some embodiments, the water dispersible pouch can include a laminate comprising a water-soluble film and a nonwoven web of the disclosure.

Abstract: Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a fiber having a surface region and an interior region, includes a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with a modification agent. The fiber has a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.

Abstract: Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a method of treating fibers includes contacting a surface of a fiber comprising the polymer with a modification agent to chemically modify at least a portion of the polymer with the modification agent in a region of the fiber comprising at least the surface of the fiber to form a modified fiber.

Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.

Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.

Abstract: The disclosure provides a water-soluble film, including polyvinyl alcohol (PVOH) and (PVOH) and an acrylate resin (e.g., methyl acrylate), wherein the water-soluble film remains intact for at least 3 minutes when submerged in water heated to a temperature of about 40° C., as determined by Bleach Compatibility Method A (described herein). The disclosure further provides a packet or pouch comprising water-soluble film of the disclosure. The packet or pouch can optionally include two or more compartments. The disclosure further provides a pouch including a first sealed compartment containing a first composition, the first sealed compartment comprising the water-soluble film according to the disclosure. Optionally, the first composition can include a bleach composition.

Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.

Abstract: Disclosed herein are capsules for delayed release of an active ingredient contained therein, in particular water-soluble capsules for delayed release of water-sensitive, gas-generating compositions into an aqueous liquid medium. The delayed release capsules incorporate one or more gas-relief pinholes for gas-generating water-sensitive compositions contained in the capsules, such as inorganic bleach or other alkaline compositions intended for delayed release into a wash medium during a laundry cycle. The pinholes permit gas generated within the capsule due to exposure to environmental water vapor to escape from the capsule interior, preventing pressure build-up and capsule deformation during storage. The pinholes are sized to prevent or otherwise substantially limit the passage of liquids when submerged in a liquid medium (e.g., liquid water in an aqueous liquid medium). Related articles and methods for delivering the capsules in combination with a detergent or other laundry composition are also disclosed.

Abstract: The disclosure provides a water-soluble film, including polyvinyl alcohol (PVOH) and (PVOH) and an acrylate resin (e.g., methyl acrylate), wherein the water-soluble film remains intact for at least 3 minutes when submerged in water heated to a temperature of about 40° C., as determined by Bleach Compatibility Method A (described herein). The disclosure further provides a packet or pouch comprising water-soluble film of the disclosure. The packet or pouch can optionally include two or more compartments. The disclosure further provides a pouch including a first sealed compartment containing a first composition, the first sealed compartment comprising the water-soluble film according to the disclosure. Optionally, the first composition can include a bleach composition.

Abstract: Disclosed herein are fluorescent tracer compositions and water-soluble polymer compositions containing fluorescent compounds for tracing one or more components in the polymer compositions. More particularly, the disclosure relates to fluorescent tracer compositions including a fluorophore and a bitterant aversive component to be incorporated into a water-soluble polymer composition such as a water-soluble film. An aversive compound such as a bitterant is desirably incorporated into the polymer composition as a deterrent to ingestion of the polymer composition (or an article made therefrom). Qualitative or quantitative detection of the fluorophore in the polymer composition can be correlated to a qualitative or quantitative detection of a corresponding traced material in the polymer composition, for example the bitterant aversive component. Related articles and methods for making and using the polymer compositions are also disclosed.

Abstract: Disclosed herein are fluorescent tracer compositions and water-soluble polymer compositions containing fluorescent compounds for tracing one or more components in the polymer compositions. More particularly, the disclosure relates to fluorescent tracer compositions including a fluorophore and a bitterant aversive component to be incorporated into a water-soluble polymer composition such as a water-soluble film. An aversive compound such as a bitterant is desirably incorporated into the polymer composition as a deterrent to ingestion of the polymer composition (or an article made therefrom). Qualitative or quantitative detection of the fluorophore in the polymer composition can be correlated to a qualitative or quantitative detection of a corresponding traced material in the polymer composition, for example the bitterant aversive component. Related articles and methods for making and using the polymer compositions are also disclosed.

Abstract: Disclosed herein are capsules for delayed release of an active ingredient contained therein, in particular water-soluble capsules for delayed release of water-sensitive, gas-generating compositions into an aqueous liquid medium. The delayed release capsules incorporate one or more gas-relief pinholes for gas-generating water-sensitive compositions contained in the capsules, such as inorganic bleach or other alkaline compositions intended for delayed release into a wash medium during a laundry cycle. The pinholes permit gas generated within the capsule due to exposure to environmental water vapor to escape from the capsule interior, preventing pressure build-up and capsule deformation during storage. The pinholes are sized to prevent or otherwise substantially limit the passage of liquids when submerged in a liquid medium (e.g., liquid water in an aqueous liquid medium). Related articles and methods for delivering the capsules in combination with a detergent or other laundry composition are also disclosed.