Abstract: A multiply fused, conjugated, porphyrin polymer film coated on a substrate, wherein the porphyrin monomer repeating units are di-meso-substituted porphyrins; and including a metal cation selected from the group consisting of Mg(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Ru(II), Pd(II), Ag(II), Pt(II) and Au(III), or mixtures thereof; the porphyrin units are multiply fused, including doubly-fused and/or triply-fused; including a substituent R attached to the meso position of the porphyrin monomer, the substituent R being an aromatic group presenting at least one free ortho position among; at least one of the two free ortho positions of the aromatic substituent is fused to the 13 position of the porphyrin monomer, the porphyrin polymer film being a porous porphyrin polymer film with mean pore diameters within the range of from 2 nm to 100 nm, and exhibiting a density not greater than 2 g/cm3.

Abstract: A conductive coating comprising polymers of meso-meso, ?-? doubly linked fused and/or meso-?, ?-meso doubly linked fused and/or meso-meso, ?-?, ?-? triply linked fused (poly)porphyrins. A method for forming on a substrate a thin conductive coating of polymers of meso-meso, ?-? doubly and/or meso-?, ?-meso doubly and/or meso-meso, ?-?, ?-? triply linked fused (poly)porphyrins, the method comprising the steps of providing a substrate in a vacuum chamber, performing on the substrate an oxidative chemical vapour deposition reaction with an oxidant and at least one porphyrin monomer.

Abstract: A method for forming an electrically conductive multi-layer coating with anti-corrosion properties and with a thickness comprised between 1 ?m and 10 ?m onto a metallic substrate, comprising the following subsequent steps of (a) providing a solvent-free suspension consisting of solid electrically conductive fillers dispersed into a liquid matrix forming material that contains vinyl groups; (b) depositing the suspension on at least a surface portion of a metallic substrate; (c) exposing an atmospheric pressure plasma to the surface portion so as to form one electrically conductive layer with anti-corrosion properties; and (d) repeating the steps (a), (b) and (c). The method is remarkable in that the electrically conductive fillers are electrically conductive carbon-based particles.

Abstract: A solvent-free plasma method for depositing an adherent catechol and/or quinone functionalised layer to an inorganic or organic substrate from a precursor which comprises at least a quinone group; a protected or unprotected catechol group; a molecule substituted by a quinone group and/or a protected or unprotected catechol group; and/or a natural or synthetic derivative of a catechol group and/or a quinone group; wherein the quinone group is a 1,2-benzoquinone group and the catechol group is a 1,-dihydroxybenzene group.

Abstract: The invention provides a method for forming regular polymer thin films on a substrate using atmospheric plasma discharges. In particular, the method allows for the deposition of functional polymer thin films which require a high regularity and a linear polymer structure.

Abstract: A plasma post-discharge deposition device for depositing crystalline metal oxide derivative on a substrate, the device comprising a gas source with a substrate inlet, a post-discharge deposition chamber with a substrate outlet, the substrate inlet and the substrate outlet defining a longitudinal central axis, and a dielectric tube placed between the gas source and the deposition chamber on the longitudinal central axis; configured to confine a plasma discharge and comprising a discharge zone lying on the internal surface of the dielectric tube and a central zone centred on the longitudinal central axis. The deposition device is remarkable in that the central zone is located at a distance comprised between 1 mm and 2.5 mm from the internal surface of the dielectric tube. Also a plasma-enhanced chemical vapour deposition method.

Abstract: A method for forming an electrically conductive multi-layer coating with anti-corrosion properties and with a thickness comprised between 1 ?m and 10 ?m onto a substrate, comprising the following subsequent steps of (a) providing a suspension consisting of electrically conductive fillers into a matrix forming material; (b) depositing the suspension on at least a surface portion of a substrate; (c) exposing an atmospheric pressure plasma to the surface portion so as to form one electrically conductive layer with anti-corrosion properties; and (d) repeating the steps (a), (b) and (c). The method is remarkable in that the electrically conductive fillers are electrically conductive particles.

Abstract: The invention is directed to a method for manufacturing a hydrophobic or superhydrophobic surface comprising the steps of: (a) providing a substrate with a surface roughness Ra between 0.1 and 1.0 ?m and (b) exposing the substrate to a filamentary atmospheric pressure dielectric barrier discharge plasma which is fed by a reaction gas and siloxane-forming material in order to form a superhydrophobic siloxane layer over at least a portion of the surface of the substrate. Step (b) is operated with an electrical excitation frequency of 15,000 Hz to 35,000 Hz and a power density between 0.5 to 10 W·cm?2. The siloxane layer produced in step (b) shows thereby a micro-structure and a nano-structure with droplet “sticking” properties (high water sliding angle).

Abstract: The invention provides a solvent-free plasma method for depositing an adherent catechol and/or quinone functionalised layer to an inorganic or organic substrate from a precursor which comprises at least a quinone group; a protected or unprotected catechol group; a molecule substituted by a quinone group and/or a protected or unprotected catechol group; and/or a natural or synthetic derivative of a catechol group and/or a quinone group; wherein the quinone group is a 1,2-benzoquinone group and the catechol group is a 1,2-dihydroxybenzene group.

Abstract: The invention provides a method for forming regular polymer thin films on a substrate using atmospheric plasma discharges. In particular, the method allows for the deposition of functional polymer thin films which require a high regularity and a linear polymer structure.

Abstract: The invention is directed to a method for manufacturing a hydrophobic or superhydrophobic surface comprising the steps of: (a) providing a substrate with a surface roughness Ra between 0.1 and 1.0 ?m and (b) exposing the substrate to a filamentary atmospheric pressure dielectric barrier discharge plasma which is fed by a reaction gas and siloxane-forming material in order to form a superhydrophobic siloxane layer over at least a portion of the surface of the substrate. Step (b) is operated with an electrical excitation frequency of 15,000 Hz to 35,000 Hz and a power density between 0.5 to 10 W·cm?2. The siloxane layer produced in step (b) shows thereby a micro-structure and a nano-structure with droplet “sticking” properties (high water sliding angle).

Abstract: The present disclosure provides a method for forming a porous colorimetric gas sensing layer. In various embodiments, the method comprises providing a mixture of an organic solvent, a polymer forming material and a gas sensing compound or gas sensing particles. The method additionally comprises depositing the mixture (sprayed or vaporized) on at least a surface portion of a substrate. Thereafter, an atmospheric pressure plasma is applied to the surface portion to form a polymer layer comprising the gas sensing compound or particles. The steps of depositing the mixture and applying the plasma can be repeated multiple times to form a plurality of stacked or superposed polymer layers comprising the gas sensing compound or particles.